File name: Pandora31s1_CharlesCityVA_20240706_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T080923.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240706_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240706T105816.4Z 8953.457134 80 1 30.43 2 79.42 69.55 83.22 62.20 0.00 1 0.00 1 0 17 5.220e-01 1.178e-02 3.305e-01 7.690e-03 6.638837e-01 4.276337e-03 7.411180e-03 -6.000000e+00 3.060972e-01 232.66 -2.00 3.44 -2.00 321.33 0.00e+00 3.008611e-03 2.175211e-03 1.277030e-03 -6.000000e+00 1.426097e-02 290.72 -2.00 20.00 -2.00 320.69 0.00e+00 5.231 0.002 302.00 328.00 3 3.0223e+00 1.5534e-02 6.3142e-02 -6.0000e+00 7.6689e-01 1.0440e-01 2.1296e-02 3.5788e-02 -6.0000e+00 8.2787e-01 -1.5406e-01 2.0096e-02 1.8970e-02 -6.0000e+00 4.9243e-01 5.1686e-02 9.4858e-03 6.5578e-03 -6.0000e+00 2.0951e-01 6.9774e-05 -7.6092e-04 2.2068e-04 8.4123e-05 -6.0000e+00 1.4155e-02 5.3679e-03 12 8 8 10 0 0 99.95 24.30 0.46 0.00537 -0.00035 25 25 1 5 0 1216.930 26.83 19.99 24.30 35.35 5.5 1013.03 -243577 -51471 -208418 114688 -88320 900000 -24323 58297 -192963 -128659 -85861 900000 -64365 -81568 80714 -83043 42821 -77180 292495 -1205 191339 12568 -29841 38863 -19324 -38981 -44193 -14257 -1471 73207 3030 5128 -20103 53082 -8087 -31127 24411 -13724 18251 -3363 30417 -2261 8089 -8962 5249 343 2902 5188 -2621 -816 11004 6638 -2005 11654 -3737 9734 4976 2724 -2068 5626 -5833 10124 5341 4343 7085 1449 3196 1254 4025 376 2813 508 1482 -222 298 3228 -1422 2291 -474 286 -5119 -2187 -2727 -163 -3442 1114 273 733 2825 -954 2501 -1393 -311 -1728 -98 -1512 2098 193 667 -785 -1554 -970 -1263 482 -2164 -566 -2331 -486 -73 266 -124 560 545 13 50 -528 41 -544 614 -557 1203 23 312 491 657 66 930 650 -946 520 -26 347 3 328 -114 321 79 -277 -85 -609 627 -694 -100 -4814 -386 -3693 860 -662 900000 -182 437 -3682 -1403 -708 900000 -627 -1112 605 -1755 321 -1946 2193 -18 1434 170 -590 466 -408 -1063 -1295 -301 -30 768 70 140 -822 1234 -303 -1464 732 -720 858 -236 1721 -191 651 -880 454 32 271 491 -282 -93 1245 882 -320 1771 -647 1678 852 477 -369 1001 -1104 1803 1138 1055 1771 376 805 333 1149 129 1042 202 579 -83 102 964 -415 651 -155 110 -2447 -1164 -1608 -100 -2329 771 201 553 2093 -710 1679 -909 -193 -1113 -69 -1257 1951 195 734 -884 -1664 -934 -1204 450 -2056 -563 -2487 -546 -89 363 -189 904 889 20 75 -766 58 -825 976 -939 1991 37 486 738 946 93 1244 895 -1480 908 -51 666 6 704 -263 782 198 -710 -220 -1525 1463 -1549 -213 SS 20240706T110744.7Z 8953.463712 83 1 4.05 2 77.65 70.86 81.61 63.47 0.00 1 0.00 1 0 25 2.886e-01 9.922e-03 3.008e-01 1.010e-02 6.005176e-01 5.426087e-03 6.700845e-03 -6.000000e+00 1.684240e-01 232.66 -2.00 3.44 -2.00 320.59 0.00e+00 -2.108732e-03 2.207034e-03 5.063628e-04 -6.000000e+00 7.850551e-03 290.72 -2.00 20.00 -2.00 319.86 0.00e+00 4.538 0.001 302.00 328.00 3 2.7701e+00 1.7329e-02 5.5298e-02 -6.0000e+00 4.2307e-01 8.9039e-03 2.2409e-02 3.1628e-02 -6.0000e+00 4.5686e-01 -5.1834e-02 2.0425e-02 1.5730e-02 -6.0000e+00 2.7187e-01 1.4601e-02 1.0130e-02 4.5090e-03 -6.0000e+00 1.1640e-01 1.9008e-04 -3.3846e-04 2.8585e-04 5.0105e-05 -6.0000e+00 7.8316e-03 3.7651e-03 12 9 9 12 1 1 77.68 24.31 0.50 0.00377 0.00122 4 37 1 5 0 809.640 26.83 20.00 24.31 35.67 5.5 1013.98 -81609 900000 8841 34890 -55967 13377 -128474 206546 -81037 900000 -46856 2110 -120036 -53490 -16547 -20737 -22060 -4718 43035 -38314 -20156 2232 13264 11211 -39339 30099 -11311 -14537 -15668 37297 -24933 12939 -5333 51427 -16572 26855 -1023 10277 -5429 8281 -6111 -1424 7294 1431 11463 -13474 7661 4277 1239 -6296 -1593 378 -2364 -544 96 7816 1293 6274 -2421 4579 -1292 4876 7238 -454 -2609 1453 2395 507 -874 1430 2999 1158 1338 -3058 -1049 -1952 2584 -504 -672 -295 -704 -2643 -2284 -452 -1346 -659 509 -303 618 1167 -470 575 2017 1498 -973 -281 210 360 1553 -151 -35 -854 -1238 123 -303 -787 -1879 -580 -298 -60 421 299 850 -55 -329 -690 -426 -585 280 339 27 -152 822 -420 746 390 364 884 -398 -201 929 -170 680 -128 -150 -540 -179 640 -90 128 -361 -295 -181 -804 900000 87 344 -551 132 -1945 2035 -1054 900000 -510 21 -3621 -1062 -281 -432 -517 -103 644 -1321 -605 55 314 302 -1877 799 -454 -579 -614 941 -1303 555 -310 1877 -1100 1190 -66 708 -532 857 -811 -194 958 202 1490 -2234 1062 626 194 -1122 -301 78 -544 -134 25 1983 360 1675 -684 1195 -366 1416 2298 -171 -1041 548 880 194 -370 675 1526 625 718 -1637 -514 -878 1044 -210 -305 -153 -420 -1793 -1676 -343 -1090 -563 450 -277 561 1029 -397 456 1519 1147 -823 -265 220 418 1909 -189 -42 -955 -1298 128 -336 -918 -2302 -738 -401 -88 656 486 1380 -87 -505 -1024 -632 -894 444 556 45 -247 1292 -651 1111 567 515 1265 -620 -340 1657 -321 1313 -258 -316 -1190 -401 1446 -205 285 -779 -615 -367 SS 20240706T111617.2Z 8953.469643 86 1 29.90 2 76.04 72.03 80.15 64.60 0.00 1 0.00 1 0 25 1.216e-01 4.327e-03 7.224e-02 1.977e-03 5.338832e-01 1.048142e-03 6.012599e-03 -6.000000e+00 7.092773e-02 232.66 -2.00 3.44 -2.00 320.43 0.00e+00 1.002510e-03 3.973860e-04 4.114487e-04 -6.000000e+00 3.174726e-03 290.72 -2.00 20.00 -2.00 319.67 0.00e+00 4.050 0.001 302.00 328.00 3 2.0758e+00 3.2817e-03 4.9301e-02 -6.0000e+00 1.7786e-01 -1.7038e-02 4.1367e-03 2.8076e-02 -6.0000e+00 1.9193e-01 -8.3921e-03 3.6349e-03 1.3949e-02 -6.0000e+00 1.1443e-01 -7.0166e-03 1.8338e-03 4.1057e-03 -6.0000e+00 4.8715e-02 6.4721e-04 -5.3091e-04 5.7335e-05 4.4912e-05 -6.0000e+00 3.2948e-03 3.1819e-03 10 0 0 10 0 0 97.58 24.31 0.27 0.00318 -0.00081 115 115 1 5 0 259.950 26.83 20.00 24.31 36.06 5.6 1014.98 2641 -30835 -35874 -62394 40425 -48149 -24582 -43297 -38805 -37254 -38311 -27701 -31651 -3282 -20652 -713 -21255 148 -3658 1113 -2928 2538 -9611 -8052 2270 -6131 -1291 -11068 748 -5556 4779 -3554 -186 -2856 -3332 -1604 1125 -649 -2118 -341 -1732 100 -2296 1595 -3090 -1521 -2241 -1586 -155 -948 -802 1224 1692 443 1416 290 517 495 1305 740 675 1277 1485 1831 1137 1193 377 578 736 1411 484 885 447 -354 -69 -623 -516 -1072 -278 -484 -144 -1082 -917 -1292 -539 -305 169 316 368 708 104 804 349 204 244 428 640 328 89 -297 -527 -780 -690 -682 -861 -963 -774 -633 -236 226 90 353 54 465 33 108 -15 207 -218 201 -70 -54 -75 148 329 355 580 503 294 305 151 253 -59 -43 -356 -269 -24 190 -193 116 -94 6 -259 15 -279 -367 -733 171 -492 -218 -534 -476 -490 -530 -384 -560 -55 -503 -17 -682 4 -117 36 -102 84 -379 -343 95 -296 -60 -551 32 -269 241 -227 -13 -221 -249 -117 89 -57 -233 -44 -256 16 -384 263 -540 -267 -401 -287 -29 -186 -173 287 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