File name: Pandora31s1_CharlesCityVA_20240710_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T094024.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240710_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240710T112930.0Z 8957.478820 92 1 30.02 2 73.91 74.15 120.22 47.61 0.00 1 0.00 1 0 17 5.152e-01 1.761e-02 2.968e-01 1.660e-02 4.475714e-01 8.773835e-03 5.133985e-03 -6.000000e+00 2.997106e-01 232.62 -2.00 3.44 -2.00 320.03 0.00e+00 2.279584e-03 2.837055e-03 3.699242e-04 -6.000000e+00 1.394393e-02 291.08 -2.00 20.00 -2.00 319.21 0.00e+00 3.546 0.001 302.00 328.00 3 5.3432e+00 2.6295e-02 4.2581e-02 -6.0000e+00 7.5142e-01 7.6811e-02 3.1740e-02 2.3488e-02 -6.0000e+00 8.1193e-01 4.7484e-02 2.5141e-02 1.1583e-02 -6.0000e+00 4.8409e-01 -3.7758e-02 1.2967e-02 3.7339e-03 -6.0000e+00 2.0727e-01 4.0591e-05 -1.0906e-03 4.9847e-04 4.1195e-05 -6.0000e+00 1.4047e-02 2.1635e-02 12 8 8 10 0 0 99.99 24.12 0.56 0.02163 0.01344 46 46 1 5 0 652.450 26.62 20.00 24.12 34.42 5.7 1014.13 900000 24640 77404 486501 58528 103890 17451 -14831 -99106 145293 129506 900000 -25077 186219 14004 -4393 10304 -12219 21689 -617 24853 -48838 3005 -32554 24941 -12438 56463 19327 11631 13127 3084 41779 -16911 24384 -7301 -5157 -32176 17557 -1604 4228 -4620 4632 1468 8431 11721 -7708 2863 -11320 4865 -4597 10154 2165 870 3210 -2338 3633 -591 -1265 -4684 -704 937 5305 -1666 3306 -2438 -1771 1339 3133 -1456 755 2212 -1815 2945 -1063 2893 -1685 4519 -3715 2763 -4554 1861 2575 -758 -635 -2076 2696 -1552 -175 -2678 2183 -408 94 929 -1301 3150 -3433 2437 2779 -1334 -831 1508 -2044 -1263 -843 976 -365 -1408 -593 -37 -811 -671 942 -198 1041 238 327 665 -866 898 -446 491 -416 878 -694 -102 -476 1535 737 1364 284 343 693 -87 -836 -1695 -156 -87 925 8 -211 -66 -257 314 900000 399 1253 7875 947 1682 282 -297 -4636 2352 2096 900000 -865 3014 486 -203 454 -704 987 -36 1186 -4465 182 -2891 1417 -1028 2569 1174 738 861 248 2693 -2031 2113 -800 -556 -4873 1993 -259 751 -978 952 324 1778 2432 -1931 655 -2975 1120 -1203 2519 629 274 1058 -845 1282 -221 -476 -1785 -258 351 2068 -767 1580 -1249 -858 607 1407 -739 426 1343 -1189 1835 -657 1600 -880 2064 -1805 1365 -2757 1203 1843 -602 -529 -1869 2474 -1555 -178 -2794 2098 -375 80 736 -1050 2632 -3414 2581 3275 -1745 -1074 1794 -2311 -1324 -895 1095 -437 -1783 -786 -52 -1243 -1100 1571 -329 1624 351 456 925 -1269 1377 -727 803 -672 1363 -1055 -148 -664 2020 990 1972 453 584 1228 -161 -1619 -3499 -334 -190 2048 17 -464 -138 -519 614 SS 20240710T132853.2Z 8957.561727 167 1 30.35 2 50.48 90.87 100.90 70.11 0.00 1 0.00 1 0 17 1.270e-02 6.221e-03 8.205e-03 3.542e-03 2.147072e-01 1.823733e-03 2.506917e-03 -6.000000e+00 7.400491e-03 232.62 -2.00 3.44 -2.00 316.63 0.00e+00 3.512836e-04 2.238389e-04 1.041594e-04 -6.000000e+00 3.319070e-04 291.08 -2.00 20.00 -2.00 315.77 0.00e+00 1.568 0.000 302.00 328.00 3 6.0016e+00 4.8111e-03 1.9268e-02 -6.0000e+00 1.8554e-02 6.6778e-02 5.3750e-03 1.1019e-02 -6.0000e+00 2.0025e-02 -2.3743e-03 3.1155e-03 5.3144e-03 -6.0000e+00 1.1942e-02 -3.0717e-03 1.4693e-03 1.4507e-03 -6.0000e+00 5.0828e-03 2.0837e-04 1.1289e-04 1.0226e-04 1.6881e-05 -6.0000e+00 3.4412e-04 7.3634e-03 10 0 0 10 0 0 99.99 24.30 0.22 0.00736 0.00821 17 17 1 5 0 1785.030 26.83 20.00 24.30 36.17 5.8 1015.45 -3181 172 -3371 -433 -6191 2431 -6921 -113 1362 -760 753 -2411 910 -191 2136 -869 1915 311 2877 2158 310 110 1767 2537 -268 -803 -1829 -141 -801 239 590 763 772 1026 -1780 -1655 -1483 -1372 773 248 -738 -520 107 -1081 -353 -1315 -765 -994 -854 -632 -135 342 -328 1698 462 1321 445 1208 84 980 776 985 1601 1262 504 -164 -606 -539 609 -279 936 -94 440 767 11 -162 -1489 -663 -1690 -98 -1187 -970 -1304 -1092 -800 -127 303 -46 298 205 536 -528 34 -613 662 35 602 539 614 129 -303 -349 -1464 -709 -467 -323 -850 -318 -267 621 326 684 10 -312 113 -444 -90 -188 363 115 295 346 89 568 210 903 458 224 26 471 -23 -168 -340 -179 -452 402 53 -324 313 12 195 -248 -802 -543 31 -625 -73 -978 342 -1124 -19 251 -148 142 -477 193 -46 562 -253 559 95 885 688 102 36 580 866 -98 -304 -692 -49 -264 76 196 270 291 392 -653 -597 -580 -616 399 146 -472 -343 72 -736 -238 -890 -505 -639 -535 -395 -88 234 -235 1247 352 1010 347 934 64 745 606 813 1402 1161 462 -141 -488 -422 495 -253 904 -95 441 745 10 -138 -1174 -493 -1304 -82 -1097 -967 -1371 -1187 -915 -153 380 -59 383 257 630 -581 35 -604 670 38 710 687 817 171 -383 -416 -1682 -829 -580 -420 -1147 -442 -384 923 503 1063 15 -450 152 -568 -114 -245 497 166 437 510 130 796 283 1168 571 277 34 636 -33 -241 -494 -265 -702 645 87 -542 527 20 316 -394 -1255 SS 20240710T133839.0Z 8957.568507 170 1 30.02 2 48.54 92.40 99.14 71.67 0.00 1 0.00 1 0 17 7.233e-03 4.737e-03 2.400e-03 1.004e-03 1.999550e-01 5.151105e-04 2.354477e-03 -6.000000e+00 4.215294e-03 232.62 -2.00 3.44 -2.00 316.79 0.00e+00 2.967952e-05 6.534821e-05 6.366700e-05 -6.000000e+00 1.890584e-04 291.08 -2.00 20.00 -2.00 315.91 0.00e+00 1.508 0.000 302.00 328.00 3 3.3877e+00 1.3636e-03 1.8353e-02 -6.0000e+00 1.0568e-02 1.2493e-02 1.5245e-03 1.0331e-02 -6.0000e+00 1.1406e-02 9.3256e-03 8.8460e-04 4.9821e-03 -6.0000e+00 6.8023e-03 -8.8147e-03 4.1850e-04 1.3562e-03 -6.0000e+00 2.8950e-03 3.1738e-03 -2.1211e-05 2.9189e-05 1.6080e-05 -6.0000e+00 1.9603e-04 7.7841e-03 10 0 0 10 0 0 100.00 24.33 0.15 0.00778 0.00762 619 619 1 5 0 48.490 26.83 20.00 24.33 36.81 5.7 1015.58 -958 -1602 -1858 -1985 -1891 172 -564 1338 175 1321 -799 345 -792 -221 -233 -303 -202 -232 916 20 915 -354 1333 266 297 -145 152 -483 596 1202 1189 2044 729 320 -1957 -874 -1503 88 -239 -620 -905 -847 -1043 -1122 -452 -969 -743 -846 -490 100 665 802 809 973 809 876 573 1063 371 1104 876 1196 1193 960 74 -103 -508 -161 650 447 384 -121 135 -107 -47 25 -143 -165 22 -303 -600 -865 -1562 -1177 -992 -546 -336 -88 -10 63 150 49 351 502 559 352 675 318 200 -172 -284 -730 -246 -167 -520 -507 -626 -401 -380 229 159 111 -28 168 6 326 227 193 138 -19 -54 3 79 297 475 466 685 695 497 427 107 118 -242 -29 -179 -76 -5 149 -292 41 -226 -281 -377 -155 -281 -329 -325 -285 24 -86 224 31 244 -147 66 -163 -51 -61 -85 -58 -69 277 6 289 -112 423 90 105 -53 55 -164 185 362 373 677 262 117 -680 -295 -559 37 -122 -354 -561 -545 -690 -746 -297 -636 -474 -522 -292 59 409 524 556 699 597 657 438 804 277 816 669 975 1050 857 66 -87 -397 -121 513 399 361 -119 133 -102 -44 20 -107 -121 16 -246 -545 -831 -1608 -1263 -1138 -644 -417 -113 -13 78 178 54 358 488 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