File name: Pandora31s1_CharlesCityVA_20240711_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T094012.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240711_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240711T114633.1Z 8958.490661 99 1 30.01 2 70.73 76.56 127.89 46.19 0.00 1 0.00 1 0 25 2.239e-02 4.392e-03 3.548e-03 4.075e-04 3.957378e-01 2.103872e-04 4.545380e-03 -6.000000e+00 1.304431e-02 232.62 -2.00 3.44 -2.00 318.90 0.00e+00 3.536526e-04 4.852340e-05 2.154782e-04 -6.000000e+00 5.853756e-04 291.17 -2.00 20.00 -2.00 318.02 0.00e+00 2.995 0.000 302.00 328.00 3 4.3089e-01 5.8676e-04 3.6447e-02 -6.0000e+00 3.2702e-02 5.1833e-03 6.7685e-04 2.0581e-02 -6.0000e+00 3.5299e-02 -9.5141e-03 4.7134e-04 9.9481e-03 -6.0000e+00 2.1052e-02 -3.6422e-03 2.4714e-04 2.7222e-03 -6.0000e+00 8.9571e-03 1.0699e-02 -2.2969e-04 1.1790e-05 2.9128e-05 -6.0000e+00 6.0691e-04 1.0171e-02 10 0 0 10 0 0 99.23 24.30 0.21 0.01017 0.00845 800 800 1 5 0 37.500 26.83 20.01 24.30 38.19 5.8 1019.98 -6843 -6176 -6827 -8137 -9289 -10605 -7414 -5785 -4054 -6002 -5081 -5740 -3852 -2610 -1592 -1535 -556 -484 -454 197 -356 123 -417 -185 -351 -267 -912 -1118 -1202 -357 16 607 174 -1186 -1886 -2617 -1997 -1526 -659 -940 -711 -884 -752 -667 -302 -459 -724 -421 -735 22 525 934 891 1034 898 943 571 728 439 718 973 1226 1823 1398 678 314 27 181 685 710 609 315 18 80 -142 -245 -535 -405 -373 -463 -717 -1072 -1462 -1248 -893 -542 -162 80 170 146 419 307 430 486 553 388 575 323 -101 -240 -471 -636 -383 -299 -782 -682 -739 -510 -265 136 101 68 125 109 142 348 325 329 124 -110 -142 16 -63 272 342 443 606 731 446 447 166 162 -130 33 -234 -182 -37 23 -205 -53 -179 -221 -189 -219 -220 -255 -291 -303 -345 -254 -223 -173 -278 -236 -288 -223 -179 -127 -139 -54 -50 -49 20 -41 14 -51 -22 -45 -36 -124 -144 -161 -49 2 93 30 -214 -324 -451 -379 -341 -178 -300 -231 -304 -268 -241 -109 -167 -263 -152 -268 8 211 407 417 516 469 508 316 401 237 384 537 681 1111 928 459 201 17 110 447 530 466 253 14 62 -108 -168 -337 -248 -244 -347 -574 -963 -1423 -1198 -915 -594 -186 89 190 167 444 300 416 464 566 419 658 415 -132 -312 -612 -758 -451 -359 -960 -887 -1008 -692 -382 211 160 110 200 165 210 485 450 476 192 -171 -225 24 -96 417 500 619 854 1037 648 709 268 272 -227 56 -430 -336 -71 46 -401 -101 -343 -407 -338 SS 20240711T115536.0Z 8958.496945 102 1 30.01 2 68.98 77.79 126.64 48.43 0.00 1 0.00 1 0 17 1.492e-02 4.467e-03 2.197e-03 3.320e-04 3.664976e-01 1.707757e-04 4.224316e-03 -6.000000e+00 8.693663e-03 232.62 -2.00 3.44 -2.00 318.52 0.00e+00 2.703217e-04 3.530206e-05 2.031133e-04 -6.000000e+00 3.900783e-04 291.17 -2.00 20.00 -2.00 317.63 0.00e+00 2.761 0.000 302.00 328.00 3 3.3321e-01 4.6894e-04 3.3643e-02 -6.0000e+00 2.1795e-02 5.1787e-03 5.3592e-04 1.9047e-02 -6.0000e+00 2.3524e-02 -9.9736e-03 3.5671e-04 9.1753e-03 -6.0000e+00 1.4030e-02 -2.7395e-03 1.8548e-04 2.4863e-03 -6.0000e+00 5.9709e-03 1.5371e-02 -1.3525e-04 9.5877e-06 2.6744e-05 -6.0000e+00 4.0435e-04 8.3951e-03 10 0 0 10 0 0 54.45 24.31 0.23 0.00840 0.00738 971 971 1 5 0 30.900 26.83 20.00 24.31 39.42 5.8 1021.20 -5374 -3674 -4961 -4343 -6392 -6337 -5241 -2882 -2554 -2788 -2740 -3357 -2147 -1725 -994 -830 -344 -679 6 99 17 -224 -313 -346 -585 -416 -1009 -1210 -1455 -92 -96 1092 296 -770 -2308 -2499 -2097 -1210 -355 -547 -428 -647 -483 -476 -204 -479 -611 -439 -805 51 540 921 849 1008 654 983 654 725 443 755 956 1183 1708 1281 670 195 -75 98 682 761 642 231 98 85 -81 -193 -533 -428 -478 -423 -729 -1074 -1464 -1345 -936 -575 -185 -20 187 173 331 197 441 456 469 267 579 349 -31 -216 -455 -642 -437 -298 -705 -673 -706 -476 -258 132 134 50 99 58 159 347 346 306 174 -60 -84 32 -45 265 369 470 639 777 482 450 169 144 -140 31 -231 -142 -29 16 -188 -100 -200 -264 -246 -239 -179 -253 -208 -281 -272 -241 -148 -146 -170 -168 -221 -162 -154 -103 -97 -42 -82 1 13 2 -30 -44 -52 -94 -70 -171 -195 -222 -15 -16 202 61 -166 -476 -512 -473 -319 -113 -189 -163 -260 -201 -200 -86 -203 -257 -183 -337 22 246 455 449 566 357 550 376 415 249 420 548 733 1159 943 501 137 -50 65 483 572 532 201 85 71 -63 -143 -364 -281 -334 -316 -620 -1023 -1414 -1366 -1015 -626 -212 -23 221 197 372 204 422 427 470 299 684 437 -42 -289 -575 -789 -501 -348 -896 -857 -942 -667 -363 200 205 79 153 89 227 490 484 447 257 -94 -136 51 -69 392 548 667 863 1051 703 677 273 230 -231 52 -401 -259 -54 30 -349 -189 -365 -461 -440 SS 20240711T120543.3Z 8958.503973 105 1 30.00 2 67.01 79.16 125.19 50.85 0.00 1 0.00 1 0 17 1.095e-02 4.579e-03 1.447e-03 2.845e-04 3.383163e-01 1.463433e-04 3.924555e-03 -6.000000e+00 6.382796e-03 232.62 -2.00 3.44 -2.00 318.11 0.00e+00 2.997484e-04 2.666938e-05 1.486933e-04 -6.000000e+00 2.863796e-04 291.17 -2.00 20.00 -2.00 317.22 0.00e+00 2.540 0.000 302.00 328.00 3 3.0598e-01 3.9715e-04 3.0987e-02 -6.0000e+00 1.6002e-02 2.7830e-03 4.5035e-04 1.7555e-02 -6.0000e+00 1.7270e-02 -8.0997e-03 2.8702e-04 8.4654e-03 -6.0000e+00 1.0300e-02 -2.6480e-03 1.4726e-04 2.3057e-03 -6.0000e+00 4.3841e-03 2.0341e-02 -8.4793e-05 8.2011e-06 2.5365e-05 -6.0000e+00 2.9682e-04 7.6565e-03 10 0 0 10 0 0 13.92 24.33 0.23 0.00766 0.00702 1115 1115 1 5 0 26.900 26.83 20.00 24.33 40.51 5.7 1019.64 -2495 -2205 -1955 -3752 -4033 -5546 -3233 -3000 -1381 -1859 -1942 -2526 -1515 -807 -714 -287 -865 -363 -311 237 25 21 -27 2 -116 -109 -404 -974 -579 -340 251 742 672 -790 -1913 -2202 -1812 -949 -286 -446 -587 -458 -600 -442 -298 -459 -511 -428 -548 227 559 810 929 945 812 867 652 631 411 711 1043 1181 1640 1364 565 226 -178 72 540 713 589 192 105 17 -47 -242 -433 -512 -393 -459 -716 -1110 -1501 -1344 -960 -629 -187 -17 163 140 293 209 359 470 466 345 535 372 1 -206 -419 -601 -394 -279 -669 -649 -703 -548 -283 143 170 87 97 100 109 329 290 316 146 -13 -133 0 -27 266 403 447 709 845 502 475 225 134 -138 27 -186 -121 -27 9 -224 -109 -243 -281 -299 -149 -145 -133 -243 -235 -320 -197 -207 -105 -150 -157 -217 -149 -92 -95 -39 -125 -55 -50 39 4 4 -5 0 -23 -23 -84 -192 -107 -63 51 165 164 -202 -466 -532 -481 -294 -98 -180 -261 -214 -291 -216 -145 -226 -249 -205 -262 110 289 420 513 554 495 543 418 403 258 442 668 816 1155 1036 436 163 -130 52 387 581 495 169 93 15 -39 -183 -320 -364 -295 -365 -649 -1053 -1538 -1360 -1037 -727 -214 -20 193 160 329 215 362 462 487 379 620 482 2 -271 -548 -722 -468 -338 -833 -858 -923 -755 -411 212 268 140 154 149 158 446 390 443 219 -19 -207 1 -40 402 578 612 973 1159 702 720 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