File name: Pandora31s1_CharlesCityVA_20240717_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T094814.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240717_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240717T105021.4Z 8964.451637 100 1 29.44 2 82.07 69.51 143.71 277.18 0.00 1 0.00 1 0 25 5.869e-01 2.544e-02 4.408e-01 1.846e-02 8.058818e-01 1.079115e-02 8.928393e-03 -6.000000e+00 3.468466e-01 232.51 -2.00 3.44 -2.00 321.97 0.00e+00 3.301112e-03 6.204798e-03 1.161997e-03 -6.000000e+00 1.626221e-02 291.53 -2.00 20.00 -2.00 321.41 0.00e+00 6.757 0.005 302.00 328.00 3 2.5381e+00 4.3494e-02 8.0084e-02 -6.0000e+00 8.7227e-01 6.7706e-01 5.8473e-02 4.3519e-02 -6.0000e+00 9.4365e-01 -9.4012e-01 4.7835e-02 2.2340e-02 -6.0000e+00 5.5926e-01 3.9061e-01 2.2016e-02 7.5311e-03 -6.0000e+00 2.3724e-01 2.1203e-05 -1.1186e-03 5.2901e-04 1.0612e-04 -6.0000e+00 1.6179e-02 9.9262e-03 12 8 8 10 0 0 48.65 24.27 0.89 0.00993 0.00152 15 15 1 5 0 1962.180 26.73 20.00 24.27 34.50 6.1 1014.07 -129053 -69678 140350 -47752 -172011 -50227 900000 11461 -111599 900000 -210475 -155169 900000 -122688 51000 -28728 900000 -80795 -21247 42870 900000 -32611 -24419 142496 -14108 258691 -26415 89855 27910 900000 275133 9531 66701 -60280 9972 106657 45198 116618 -41695 6955 65289 31750 148054 29148 2100 90056 30945 10261 12920 3249 4890 49655 16275 17963 26480 28283 30141 43462 11851 20199 53111 15714 34612 -2606 12325 13905 2098 -5532 18751 17637 17261 11949 12397 17486 13711 6046 -7218 14423 8203 8741 2297 1872 -10352 5396 -1183 -3305 -2926 2074 456 -3214 4489 -1827 -1591 -148 -5051 -3562 -951 -3892 -3761 1684 -1122 -2177 -4590 -4946 -3119 -968 -2772 -1025 1039 -1810 -888 -201 997 -7 332 846 3 -2115 845 1448 -915 1129 2083 70 607 3900 958 3220 333 902 1468 182 -194 837 -119 371 -238 -177 115 -1140 241 254 -2038 -2743 -1253 2524 -859 -5062 -903 900000 206 -2007 900000 -10666 -5073 900000 -4613 917 -611 900000 -3434 -521 771 900000 -853 -599 2562 -346 4652 -734 1616 502 900000 4948 265 1319 -4040 310 1918 1138 2097 -3204 387 2241 1609 2662 1572 148 2915 1669 705 908 271 448 3247 1623 1909 2727 2959 3153 3908 1395 2113 4081 1927 4017 -498 2156 2364 401 -1194 3525 3864 4176 3164 3202 4002 2936 1245 -1593 2641 1824 2329 773 732 -5060 2399 -599 -1821 -1684 1166 260 -1834 2216 -905 -767 -74 -3014 -2469 -693 -3394 -3624 1557 -1007 -1778 -3782 -4043 -2458 -793 -2451 -963 1062 -2173 -1196 -292 1464 -10 463 1134 4 -3080 1267 2244 -1435 1661 2916 97 805 4850 1191 4083 496 1536 2782 380 -431 1969 -304 996 -658 -496 321 -3097 601 591 -4620 SS 20240717T110513.9Z 8964.461966 107 1 30.15 2 79.28 71.60 146.51 279.90 0.00 1 0.00 1 0 17 4.469e-01 7.915e-03 2.445e-01 4.459e-03 6.722799e-01 2.440572e-03 7.545354e-03 -6.000000e+00 2.626036e-01 232.51 -2.00 3.44 -2.00 321.27 0.00e+00 1.929456e-03 1.251299e-03 2.354240e-03 -6.000000e+00 1.194835e-02 291.53 -2.00 20.00 -2.00 320.62 0.00e+00 5.169 0.002 302.00 328.00 3 2.1837e+00 8.8636e-03 6.3609e-02 -6.0000e+00 6.5769e-01 3.3687e-02 1.2389e-02 3.8472e-02 -6.0000e+00 7.1029e-01 -5.5589e-02 1.2043e-02 1.9438e-02 -6.0000e+00 4.2186e-01 8.9495e-03 5.6736e-03 5.4396e-03 -6.0000e+00 1.7890e-01 1.7196e-04 -4.0157e-04 1.2676e-04 7.7917e-05 -6.0000e+00 1.2332e-02 1.0321e-02 11 8 0 10 0 0 34.64 24.26 0.35 0.01032 0.00730 55 55 1 5 0 548.070 26.73 20.00 24.26 35.06 6.1 1015.58 -217372 -138235 71644 -204755 900000 -180973 900000 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936 -290 1550 406 711 819 462 815 -105 1023 -113 1049 -595 732 -311 -176 -421 69 95 -861 -553 -1177 -294 -869 465 -1019 323 -6 417 -76 696 107 -149 346 -141 942 588 1010 -688 -579 -1099 -875 -1088 -591 -1710 -1421 -692 -1467 436 -167 595 31 243 463 124 49 904 1059 -188 1356 -551 228 -313 795 500 474 543 1052 561 27 -408 -246 687 -824 -871 -640 -89 457 -220 287 27 287 -660 SS 20240717T111523.0Z 8964.469016 110 1 29.51 2 77.36 73.02 148.41 281.92 0.00 1 0.00 1 0 25 3.119e-01 7.880e-03 1.991e-01 5.639e-03 5.845985e-01 3.037770e-03 6.571286e-03 -6.000000e+00 1.827118e-01 232.51 -2.00 3.44 -2.00 320.72 0.00e+00 1.745498e-03 1.282739e-03 8.183034e-04 -6.000000e+00 8.251664e-03 291.53 -2.00 20.00 -2.00 319.99 0.00e+00 4.442 0.001 302.00 328.00 3 3.5332e+00 9.8990e-03 5.4052e-02 -6.0000e+00 4.5866e-01 5.4805e-02 1.2866e-02 3.0851e-02 -6.0000e+00 4.9548e-01 -5.7473e-02 1.1673e-02 1.5618e-02 -6.0000e+00 2.9441e-01 1.5273e-02 5.7697e-03 4.8224e-03 -6.0000e+00 1.2549e-01 9.4955e-05 -1.7891e-04 1.6254e-04 5.6422e-05 -6.0000e+00 8.5806e-03 9.4223e-03 11 8 0 10 0 0 99.93 24.26 0.30 0.00942 0.00808 15 15 1 5 0 1966.750 26.83 20.00 24.26 35.39 6.1 1015.35 -130504 900000 -71271 -96451 -112018 173085 -58900 900000 -55942 -53976 -112573 -48780 128678 -28838 32763 -39990 20353 -47446 11468 -379 -31552 -14431 -10397 5425 -35553 26107 -17939 51786 -35118 18600 -11574 14906 -3126 -207 -6674 -14503 -2533 -5209 6147 959 309 -2494 10397 -3697 -4036 -5916 4143 4863 -2588 -2845 47 6701 1621 3284 1894 3725 115 561 1269 467 2101 1878 3601 1319 3727 -66 1408 1054 2300 1998 3067 -1038 -2488 177 457 -881 -1284 -2627 -1791 1267 -2017 -1494 -987 -28 -61 -964 -595 1332 1372 42 135 773 779 117 -13 -1495 714 383 -474 -364 -915 -219 -870 -273 -525 -1117 -1286 -82 -753 40 175 862 71 -118 719 711 256 7 214 -751 192 -381 31 271 286 549 193 1009 424 449 -164 568 -254 21 -319 117 138 -353 -187 -583 281 94 -47 -1743 900000 -671 -1116 -1389 952 -487 900000 -582 -596 -2259 -606 707 -459 359 -1017 327 -1581 238 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