File name: Pandora31s1_CharlesCityVA_20240720_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T101826.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240720_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240720T143723.7Z 8967.609303 318 1 17.48 2 38.07 105.06 154.31 284.35 0.00 1 0.00 1 0 17 6.442e-03 5.283e-03 1.397e-03 9.062e-04 1.777008e-01 4.718260e-04 2.104565e-03 -6.000000e+00 3.750484e-03 232.40 -2.00 3.44 -2.00 315.18 0.00e+00 1.810190e-04 4.272062e-05 2.441512e-05 -6.000000e+00 1.687387e-04 291.60 -2.00 20.00 -2.00 314.44 0.00e+00 1.269 0.000 302.00 328.00 3 3.6920e+00 1.2222e-03 1.5715e-02 -6.0000e+00 9.3959e-03 1.6418e-02 1.3536e-03 9.1063e-03 -6.0000e+00 1.0143e-02 2.6400e-04 7.7330e-04 4.4079e-03 -6.0000e+00 6.0519e-03 -3.6559e-03 3.4414e-04 1.2068e-03 -6.0000e+00 2.5775e-03 3.0890e-03 -9.6493e-05 2.5649e-05 1.5794e-05 -6.0000e+00 1.7460e-04 9.5333e-03 12 1 1 12 1 1 99.97 24.08 0.20 0.00953 0.00881 49 86 1 5 0 349.380 26.62 20.00 24.08 37.59 6.2 1025.46 -1110 -436 -1171 -1164 -1707 -537 -30 1228 -286 359 -392 -429 -679 -301 254 -385 -141 -112 917 595 844 447 728 406 135 307 -100 78 -35 847 568 1762 828 -55 -1624 -1103 -1649 -328 219 -522 -565 -638 -715 -790 -465 -839 -332 -851 -414 151 509 952 828 928 552 957 540 1015 533 891 637 1170 1392 1018 253 -345 -396 -347 511 289 485 27 -77 -50 57 -258 -413 -309 -447 -441 -945 -1060 -1447 -1403 -1067 -637 -246 -101 -5 24 197 -51 442 226 643 228 577 356 58 0 -326 -441 -71 16 -586 -522 -733 -428 -387 236 118 112 53 14 165 229 299 173 413 -73 125 111 102 321 551 470 672 933 581 616 141 277 -143 107 -414 -152 -61 17 -298 -176 -244 -439 -480 -339 -141 -383 -349 -453 -146 -8 358 -93 121 -129 -142 -247 -114 106 -174 -65 -53 440 295 423 222 366 200 70 163 -52 41 -17 392 273 887 448 -30 -841 -557 -915 -195 145 -378 -442 -518 -594 -660 -384 -691 -264 -654 -306 110 386 763 696 769 470 823 473 879 456 756 559 1092 1321 1019 251 -330 -348 -310 452 273 500 27 -79 -52 55 -240 -366 -256 -381 -394 -897 -1104 -1527 -1547 -1255 -763 -309 -125 -6 30 228 -56 465 227 666 246 685 443 73 -1 -401 -527 -80 19 -710 -671 -941 -572 -515 329 172 164 74 19 214 278 357 216 524 -101 170 151 140 425 722 586 830 1135 709 797 183 367 -192 148 -582 -225 -88 26 -452 -262 -368 -642 -686 SS 20240720T144623.8Z 8967.615553 325 1 11.20 2 36.36 107.07 155.93 286.65 0.00 1 0.00 1 0 17 6.139e-03 5.121e-03 4.216e-04 2.900e-04 1.731274e-01 1.512886e-04 2.051437e-03 -6.000000e+00 3.574179e-03 232.40 -2.00 3.44 -2.00 314.93 0.00e+00 2.091177e-04 1.296518e-05 2.139681e-05 -6.000000e+00 1.608038e-04 291.60 -2.00 20.00 -2.00 314.20 0.00e+00 1.241 0.000 302.00 328.00 3 1.0978e+00 3.9135e-04 1.5339e-02 -6.0000e+00 8.9542e-03 9.5342e-03 4.3315e-04 8.8652e-03 -6.0000e+00 9.6659e-03 -1.2619e-03 2.4741e-04 4.2929e-03 -6.0000e+00 5.7673e-03 -2.5200e-03 1.0894e-04 1.1772e-03 -6.0000e+00 2.4564e-03 4.3056e-02 -1.1674e-04 8.1847e-06 1.5340e-05 -6.0000e+00 1.6639e-04 9.3159e-03 12 1 1 12 1 1 99.95 24.11 0.25 0.00932 0.00844 409 1098 1 5 0 27.310 26.62 20.00 24.11 38.44 6.5 1027.59 -1027 -723 -1008 -1318 -1346 -1038 -308 602 603 76 -205 -389 -332 -76 90 -98 109 170 611 713 781 751 799 488 363 286 46 -246 13 765 859 1510 793 -259 -1350 -1363 -1170 -544 -183 -608 -661 -795 -734 -773 -540 -675 -672 -586 -536 172 601 770 924 956 726 885 618 697 457 848 923 1083 1259 891 141 -213 -461 -155 463 398 307 39 -45 -15 -17 -132 -282 -330 -235 -443 -708 -1104 -1494 -1313 -1040 -735 -359 -187 -99 -73 87 18 295 409 475 334 632 348 21 -123 -272 -384 -162 2 -481 -512 -624 -465 -260 146 147 68 81 77 116 413 315 311 206 36 -56 125 57 350 556 564 805 876 617 514 207 104 -142 11 -238 -199 -119 -55 -286 -149 -331 -391 -403 -350 -262 -367 -442 -397 -316 -91 196 217 28 -74 -143 -134 -32 42 -46 52 82 302 362 401 380 411 264 205 166 27 -132 7 388 451 776 437 -146 -709 -702 -657 -331 -124 -452 -532 -663 -593 -627 -458 -569 -550 -461 -407 136 466 632 793 811 632 780 554 621 400 738 827 984 1229 917 143 -198 -413 -133 417 384 309 41 -48 -15 -17 -125 -254 -278 -203 -404 -686 -1120 -1616 -1414 -1195 -865 -444 -229 -122 -91 103 20 303 418 504 369 732 425 26 -158 -328 -448 -179 2 -572 -646 -789 -612 -356 201 211 94 112 103 147 511 385 379 269 49 -76 167 78 457 716 690 971 1042 772 653 276 136 -188 15 -330 -291 -172 -82 -430 -220 -475 -565 -569 SS 20240720T145613.3Z 8967.622376 328 1 30.01 2 34.50 109.43 157.68 289.44 0.00 1 0.00 1 0 17 6.285e-03 4.978e-03 7.037e-04 4.169e-04 1.702403e-01 2.166284e-04 2.020768e-03 -6.000000e+00 3.659873e-03 232.40 -2.00 3.44 -2.00 315.57 0.00e+00 1.932967e-04 2.123389e-05 3.901754e-05 -6.000000e+00 1.646496e-04 291.60 -2.00 20.00 -2.00 314.79 0.00e+00 1.213 0.000 302.00 328.00 3 2.5268e+00 5.6324e-04 1.5046e-02 -6.0000e+00 9.1689e-03 1.5097e-02 6.2472e-04 8.7561e-03 -6.0000e+00 9.8973e-03 -1.1533e-03 3.5729e-04 4.2441e-03 -6.0000e+00 5.9054e-03 -3.4014e-03 1.6120e-04 1.1642e-03 -6.0000e+00 2.5155e-03 1.0646e-02 -9.4847e-05 1.1929e-05 1.4742e-05 -6.0000e+00 1.7036e-04 8.6456e-03 10 0 0 10 0 0 99.98 24.16 0.24 0.00865 0.00793 652 652 1 5 0 46.020 26.73 20.01 24.16 40.89 6.3 1029.05 -1237 -919 -744 -1561 -1555 -1311 -346 563 723 104 -310 -608 -394 -14 256 -59 37 156 411 712 624 674 757 324 355 284 37 -323 70 680 909 1474 926 -291 -1294 -1442 -1150 -449 -195 -506 -692 -752 -815 -709 -509 -714 -650 -585 -631 57 542 783 895 890 779 936 643 755 539 819 1010 1111 1387 992 267 -222 -557 -132 450 492 292 50 -21 8 29 -143 -432 -434 -383 -497 -756 -1104 -1441 -1316 -996 -650 -301 -119 21 7 144 -66 138 344 391 331 588 405 90 -92 -217 -514 -201 -75 -492 -561 -596 -507 -205 178 213 122 83 103 65 267 250 366 204 48 -57 120 71 385 532 545 724 762 516 475 192 156 -142 58 -232 -158 -103 -5 -236 -110 -291 -339 -445 -336 -265 -215 -417 -365 -293 -81 145 206 31 -89 -177 -125 -5 101 -25 16 68 170 303 269 286 326 147 168 138 18 -145 31 291 402 683 459 -147 -612 -669 -581 -242 -125 -348 -515 -580 -643 -561 -399 -556 -491 -424 -442 43 387 591 707 734 658 800 558 651 458 691 877 1030 1286 970 258 -210 -484 -110 392 450 293 52 -22 8 27 -131 -356 -334 -303 -437 -742 -1111 -1546 -1472 -1114 -779 -380 -154 27 9 168 -74 140 332 392 361 705 502 119 -119 -265 -622 -230 -88 -594 -719 -797 -665 -279 255 317 183 120 137 84 321 296 450 269 64 -79 166 97 531 692 674 901 935 624 609 258 214 -198 83 -331 -238 -160 -7 -380 -175 -447 -506 -649 SS 20240720T150450.3Z 8967.628360 331 1 18.86 2 32.90 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