File name: Pandora31s1_CharlesCityVA_20240811_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T102104.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240811_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240811T111011.6Z 8989.465412 70 1 30.33 2 81.69 77.39 153.90 40.86 0.00 1 0.00 1 0 17 4.483e-01 3.454e-02 3.652e-01 2.221e-02 7.448159e-01 1.282825e-02 9.292119e-03 -6.000000e+00 2.649469e-01 231.68 -2.00 3.44 -2.00 321.67 0.00e+00 9.843766e-03 6.593913e-03 7.633213e-03 -6.000000e+00 1.332211e-02 292.07 -2.00 20.00 -2.00 321.04 0.00e+00 6.489 0.004 302.00 328.00 3 3.0932e+00 4.7899e-02 8.3250e-02 -6.0000e+00 6.6546e-01 7.9900e-01 6.1696e-02 5.7439e-02 -6.0000e+00 7.2270e-01 -9.3519e-01 4.8092e-02 2.6138e-02 -6.0000e+00 4.3032e-01 3.6402e-01 2.3185e-02 6.4322e-03 -6.0000e+00 1.8528e-01 1.5217e-05 5.9825e-06 6.4435e-04 1.8117e-04 -6.0000e+00 1.2792e-02 6.3083e-03 12 8 8 10 0 0 -89.57 23.80 1.31 0.00631 0.00635 10 10 1 5 0 3032.780 26.41 20.00 23.80 32.77 8.0 1019.18 900000 900000 -143289 118123 -58042 2804 -44728 -41272 -118996 -24313 900000 -161976 900000 51512 900000 -45338 900000 -24215 900000 -53635 -46400 900000 -59575 900000 -25617 53289 24762 900000 -47268 900000 -5507 16365 900000 15245 219659 -61349 900000 37433 54179 59799 25174 6041 94929 19609 29683 120240 49490 162416 -9553 23483 -18089 118989 45132 35948 12648 57519 13725 4019 7937 -5136 30927 3374 46373 18275 32390 -9702 16116 669 13446 10680 12901 15964 12156 5547 -11091 18738 3575 11235 -8306 13068 5681 2297 -2945 -253 -2095 -6635 11474 -4853 6380 -4636 364 -6169 -7382 -6139 -3590 -2030 -3536 1799 -1586 1090 -4735 288 -9878 -1748 -3450 -1933 -1213 -5458 1658 -5303 540 1239 4345 -5008 2080 1449 83 -1610 901 521 -76 3285 88 6362 -2208 4860 5255 2621 440 -575 2420 -55 -214 -1101 1156 -1378 1344 -391 1261 -1013 -555 -698 -1867 900000 900000 -7740 2552 -1254 61 -966 -892 -3856 -525 900000 -9041 900000 1113 900000 -1878 900000 -959 900000 -2994 -2339 900000 -3218 900000 -1107 1151 632 900000 -2321 900000 -238 675 900000 749 4746 -5784 900000 1618 2341 2819 1830 558 3729 1656 2274 3779 3208 3509 -1201 2260 -2913 5375 4610 4307 1987 5875 2184 687 1247 -898 3888 616 6285 3697 5980 -2446 3387 169 3301 2827 3647 4513 3480 1578 -3355 4085 850 2538 -2594 3953 1994 955 -1416 -125 -1124 -3954 5970 -3049 3573 -2788 194 -3287 -3855 -3294 -2127 -1389 -2878 1607 -1610 1085 -4698 244 -8395 -1360 -2926 -1713 -1129 -5719 1788 -6951 750 1834 6329 -7817 2883 1946 114 -2356 1365 825 -120 4808 127 8397 -3054 6055 6320 3369 656 -989 4492 -114 -466 -2572 2611 -3371 3274 -985 3118 -2464 -1361 -1603 -4152 SS 20240811T112430.9Z 8989.475358 75 1 30.26 2 78.90 79.47 152.04 46.87 0.00 1 0.00 1 0 25 3.082e-01 7.225e-03 2.904e-01 5.832e-03 6.177744e-01 3.202378e-03 6.986576e-03 -6.000000e+00 1.790970e-01 231.68 -2.00 3.44 -2.00 321.12 0.00e+00 2.472779e-03 1.533883e-03 1.383234e-03 -6.000000e+00 8.710555e-03 292.07 -2.00 20.00 -2.00 320.43 0.00e+00 5.007 0.002 302.00 328.00 3 2.8871e+00 1.1186e-02 5.9831e-02 -6.0000e+00 4.4871e-01 1.5042e-02 1.5188e-02 3.3428e-02 -6.0000e+00 4.8503e-01 -4.0707e-02 1.4460e-02 1.7534e-02 -6.0000e+00 2.8879e-01 4.0141e-03 6.9551e-03 5.6227e-03 -6.0000e+00 1.2373e-01 1.0668e-04 -2.3447e-04 1.6989e-04 7.1886e-05 -6.0000e+00 8.3644e-03 8.2559e-03 11 8 0 10 0 0 86.77 23.79 0.59 0.00826 0.00649 33 33 1 5 0 916.910 26.41 20.00 23.79 33.56 8.0 1019.18 -53172 -37138 -29290 -109320 139437 -99946 -190379 -30579 -106025 900000 -16458 900000 -79686 75455 -68877 -13303 44238 14423 1736 -51208 27895 -38079 -22309 -31311 -11721 -52245 11992 -23616 -26510 -5237 -22565 -12503 2380 21308 -9640 19589 -16103 9796 8948 4097 -2718 -1593 4946 1838 524 -2749 -1315 9586 285 -2003 -2476 -1703 2614 5292 1688 1988 2724 1720 -1894 3636 -4438 1070 221 4931 2041 1296 -1046 2267 2952 582 1686 -238 3037 207 -1269 -1875 -2415 1092 -1445 -25 295 -881 -2192 -462 -1721 -440 -319 689 1725 395 1529 -347 428 80 529 -376 708 -774 520 -186 -1141 -1189 -502 -664 -1138 -1347 -394 -310 -432 343 189 711 131 406 520 176 9 208 4 602 -480 -226 -126 -397 171 565 1009 501 -340 482 269 231 -434 42 -451 219 187 -176 -468 -256 156 305 -2 -302 -211 -167 -808 793 -625 -2952 -174 -1025 900000 -94 900000 -997 429 -1139 -166 352 172 26 -1244 349 -846 -495 -761 -280 -1809 245 -671 -769 -134 -746 -446 85 739 -399 668 -799 451 513 296 -237 -148 455 180 53 -294 -142 961 33 -254 -352 -269 435 935 329 404 567 362 -403 725 -998 252 60 1425 636 397 -323 698 999 214 677 -102 1251 83 -475 -692 -836 369 -558 -10 142 -490 -1356 -299 -1207 -326 -249 549 1362 305 1090 -235 275 53 387 -321 689 -876 585 -212 -1232 -1261 -485 -645 -1196 -1506 -460 -357 -543 477 291 1154 214 639 772 251 14 311 6 997 -804 -365 -197 -602 247 784 1345 690 -526 832 511 469 -862 88 -1017 519 457 -438 -1178 -623 358 660 -4 SS 20240811T112946.6Z 8989.479011 78 1 29.94 2 77.87 80.23 151.32 48.91 0.00 1 0.00 1 0 25 2.499e-01 5.947e-03 1.822e-01 3.469e-03 5.742932e-01 1.865357e-03 6.458794e-03 -6.000000e+00 1.454519e-01 231.68 -2.00 3.44 -2.00 320.83 0.00e+00 2.104194e-03 8.253034e-04 6.096976e-04 -6.000000e+00 6.730599e-03 292.07 -2.00 20.00 -2.00 320.10 0.00e+00 4.615 0.002 302.00 328.00 3 2.4799e+00 6.2507e-03 5.5041e-02 -6.0000e+00 3.6336e-01 -1.4729e-02 8.2385e-03 3.0277e-02 -6.0000e+00 3.9254e-01 -1.9429e-02 7.5987e-03 1.5477e-02 -6.0000e+00 2.3420e-01 -3.7029e-03 3.7202e-03 5.2331e-03 -6.0000e+00 1.0064e-01 2.4568e-04 -9.4260e-05 1.0098e-04 5.9516e-05 -6.0000e+00 6.8631e-03 7.2205e-03 10 0 0 10 0 0 -28.39 23.79 0.39 0.00722 0.00651 58 58 1 5 0 516.180 26.41 20.00 23.79 33.76 8.0 1019.46 900000 -101351 -14540 -114799 900000 -125372 109486 -111439 -42297 -52890 68981 37462 -37022 53570 -28899 -4036 -26183 6184 -28447 -1772 -15650 925 -17043 -5434 2718 -5033 17723 -12941 1490 -11474 23472 -17471 1004 -2890 -547 -7201 -954 2297 -11380 -4657 -7526 2429 -5212 2870 -2003 -924 -3346 3783 -402 2215 1549 -1090 3438 1620 4604 -130 1159 -1118 516 695 1260 602 247 3906 -278 2735 -440 1513 394 2849 754 1733 311 -204 478 -1833 342 -2862 1322 -1361 216 -1576 -1750 -1719 -280 374 -98 716 792 615 455 227 -553 1507 332 372 243 -165 -95 -110 -716 -950 -12 -649 -1134 -924 -497 -601 262 -18 -301 123 -142 342 155 582 5 608 236 -259 -436 -134 -197 395 624 44 798 160 602 102 606 135 133 -39 -419 -331 -181 86 -143 143 63 24 -306 900000 -966 -69 -1306 900000 -1465 370 -1439 -343 -519 233 177 -421 344 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