File name: Pandora31s1_CharlesCityVA_20240930_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T192459.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240930_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240930 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240930T120258.1Z 9039.502061 134 1 29.95 2 79.22 102.39 55.68 107.81 0.00 1 0.00 1 0 25 2.952e-01 6.339e-03 1.696e-01 3.462e-03 6.077424e-01 1.848399e-03 6.870164e-03 -6.000000e+00 1.689912e-01 227.85 -2.00 3.44 -2.00 320.95 0.00e+00 2.107581e-03 8.430916e-04 1.068511e-03 -6.000000e+00 7.701215e-03 288.42 -2.00 20.00 -2.00 320.29 0.00e+00 5.145 0.002 302.00 328.00 3 1.9528e+00 6.1633e-03 6.0154e-02 -6.0000e+00 4.1917e-01 3.5661e-02 8.2810e-03 3.2018e-02 -6.0000e+00 4.5431e-01 -4.2361e-02 7.9436e-03 1.6685e-02 -6.0000e+00 2.7176e-01 6.5009e-03 3.8546e-03 5.3453e-03 -6.0000e+00 1.1707e-01 2.4071e-04 -4.4287e-04 9.9227e-05 6.6457e-05 -6.0000e+00 7.9948e-03 1.0206e-02 10 0 0 10 0 0 99.82 23.38 0.29 0.01021 0.00688 59 59 1 5 0 507.570 26.11 20.00 23.38 29.63 9.4 1015.64 -158348 900000 -150633 27577 -98274 -20709 -91979 -100795 -44025 -111385 -30085 -85807 -36304 -79290 17346 -43131 -5142 -35266 -13715 12498 -16703 46263 -24927 7600 -29853 1407 -31511 18417 -16050 -2815 -5815 -13391 -589 -10106 -2371 -12692 -5703 -6926 7712 -1694 3306 -2894 5855 1518 -761 1997 -2966 550 1298 2145 -1996 6232 39 2799 445 3644 1778 987 -308 -73 3017 54 4227 1238 3783 1473 2056 1281 1572 203 680 189 -268 1072 -922 -76 -2507 -872 -1517 290 -946 320 -972 -1186 -831 -490 108 17 725 63 1086 -430 762 374 540 -284 470 515 -501 -9 -774 -631 -1059 -311 -1639 -693 -703 -784 -235 -86 451 -212 517 6 686 386 257 486 7 6 -53 6 -360 485 51 525 313 1025 285 420 -90 169 -129 -55 -165 -375 57 -197 -218 -92 209 -109 117 -1871 900000 -2076 93 -719 -76 -699 -964 -297 -1473 -203 -1062 -347 -1494 170 -849 -78 -804 -274 204 -376 610 -652 158 -983 36 -1143 394 -479 -80 -203 -599 -27 -540 -113 -671 -314 -428 509 -147 308 -309 604 168 -87 229 -366 68 166 291 -315 1015 7 564 97 808 415 232 -71 -17 695 14 1207 379 1183 459 627 406 549 83 305 89 -126 471 -379 -28 -878 -303 -591 131 -506 193 -651 -845 -632 -371 85 14 589 50 848 -318 533 268 430 -245 465 582 -623 -11 -911 -671 -1037 -304 -1746 -776 -830 -991 -302 -123 708 -355 858 9 1036 558 372 734 11 9 -90 9 -572 738 74 739 425 1421 443 734 -162 326 -261 -117 -358 -860 134 -472 -524 -215 460 -240 248 SS 20240930T121400.3Z 9039.509726 137 1 29.88 2 77.09 104.17 53.67 109.98 0.00 1 0.00 1 0 25 1.231e-01 4.796e-03 7.251e-02 2.328e-03 5.260712e-01 1.218157e-03 5.938596e-03 -6.000000e+00 7.048011e-02 227.85 -2.00 3.44 -2.00 320.44 0.00e+00 9.240672e-04 4.707303e-04 7.580661e-04 -6.000000e+00 3.181176e-03 288.42 -2.00 20.00 -2.00 319.73 0.00e+00 4.356 0.001 302.00 328.00 3 2.0431e+00 3.7927e-03 5.1150e-02 -6.0000e+00 1.7482e-01 6.2233e-03 4.8040e-03 2.7384e-02 -6.0000e+00 1.8947e-01 2.0068e-03 4.3036e-03 1.3824e-02 -6.0000e+00 1.1326e-01 -1.2420e-02 2.1676e-03 4.0602e-03 -6.0000e+00 4.8548e-02 5.0664e-04 -1.8930e-04 6.7930e-05 4.7003e-05 -6.0000e+00 3.3329e-03 9.3776e-03 10 0 0 10 0 0 99.97 23.38 0.27 0.00938 0.00796 114 114 1 5 0 262.030 26.11 20.00 23.38 30.11 9.5 1015.85 -27571 -40086 -12478 -74486 -54218 -41735 -46374 -30021 -31357 -19831 -33322 6766 -2566 -11310 -26279 -8171 -15961 -4319 -17897 -4549 -6138 -14214 -12487 -4585 5492 -3822 -4773 -8617 -2395 -4384 -768 -2693 1176 -322 -8640 -1983 -5189 286 -1435 474 -1302 -181 -207 -1670 -1259 -340 250 -1066 974 415 2556 1404 1627 319 951 326 573 682 -20 1042 886 3217 1840 3175 900 1041 8 154 951 693 478 213 -434 -499 -310 -606 -365 -1011 34 -492 -662 -603 -1576 -737 -1387 -293 10 891 452 497 261 447 -225 262 692 336 692 361 151 -414 -428 -1054 -445 -564 -992 -849 -1070 -574 -441 216 115 223 151 389 434 601 282 255 105 -16 -53 -352 -66 158 321 205 821 349 462 178 227 -89 -176 -142 -239 -167 -238 157 -257 -49 -51 66 169 -205 -389 -98 -1045 -571 -388 -498 -316 -382 -233 -468 71 -37 -219 -727 -221 -517 -136 -640 -151 -212 -538 -491 -183 215 -174 -223 -403 -102 -203 -40 -166 79 -23 -650 -140 -422 26 -166 64 -201 -27 -33 -274 -208 -57 42 -185 170 77 514 317 399 86 268 97 174 207 -6 305 269 1046 682 1286 385 428 3 63 425 357 272 118 -241 -284 -162 -285 -159 -440 16 -274 -396 -408 -1174 -577 -1170 -262 10 855 436 462 226 360 -172 201 582 323 708 421 190 -525 -511 -1151 -478 -612 -1090 -987 -1312 -745 -617 332 181 367 247 607 635 890 418 395 163 -26 -86 -564 -103 252 488 300 1146 500 727 293 407 -168 -349 -278 -500 -369 -542 364 -600 -112 -110 134 333 SS 20240930T124410.7Z 9039.530680 153 1 9.86 2 71.35 109.24 48.33 116.46 0.00 1 0.00 1 0 25 2.462e-02 5.163e-03 1.316e-02 1.924e-03 3.779063e-01 9.746742e-04 4.387325e-03 -6.000000e+00 1.409666e-02 227.85 -2.00 3.44 -2.00 318.47 0.00e+00 4.042301e-04 2.002960e-04 2.419296e-04 -6.000000e+00 6.362654e-04 288.42 -2.00 20.00 -2.00 317.63 0.00e+00 3.087 0.000 302.00 328.00 3 2.4901e+00 2.6558e-03 3.6289e-02 -6.0000e+00 3.4965e-02 6.2050e-03 3.0438e-03 1.9239e-02 -6.0000e+00 3.7895e-02 3.2535e-04 2.0612e-03 9.4269e-03 -6.0000e+00 2.2653e-02 -6.5903e-03 1.0809e-03 2.6507e-03 -6.0000e+00 9.7099e-03 1.2938e-03 -1.0263e-04 5.5296e-05 2.8392e-05 -6.0000e+00 6.6661e-04 9.4324e-03 12 1 1 12 1 1 99.86 23.40 0.28 0.00943 0.00866 26 82 1 5 0 365.000 26.11 20.00 23.40 31.01 9.4 1015.93 -11068 -6494 -3472 -13240 -6993 -10076 -680 -10233 625 -7729 1 -5052 -3534 -2568 -3571 -1031 -5196 431 -297 22 -439 1564 -203 174 -1065 69 160 -1462 -319 -1383 524 626 1319 -1271 -1787 -3087 -2187 -190 -40 -253 -712 -59 -1403 -203 -174 -125 -644 212 -611 315 947 1022 1332 1117 810 331 327 720 604 989 1088 1352 2330 1339 391 714 -16 -14 157 606 181 305 -109 -254 -191 -325 -201 -710 -389 -527 -641 -1545 -1564 -1436 -890 -615 -289 -90 315 274 364 410 498 557 408 517 601 428 9 -253 -657 -797 -414 -581 -864 -701 -547 -609 -286 225 202 110 -196 270 341 776 500 429 155 -5 -208 183 -194 315 296 280 685 600 572 433 301 72 -137 -168 -135 -191 -31 -1 -292 -221 -223 -76 -136 -487 -305 -164 -650 -291 -425 -28 -534 33 -471 0 -324 -262 -224 -340 -108 -608 51 -37 3 -59 205 -28 26 -172 12 27 -236 -48 -216 89 118 275 -282 -375 -653 -507 -51 -12 -90 -280 -24 -609 -88 -76 -55 -282 92 -267 141 421 494 687 616 467 198 186 437 359 581 661 829 1562 982 293 500 -11 -10 113 463 153 268 -96 -215 -149 -244 -138 -473 -276 -402 -558 -1427 -1557 -1420 -938 -693 -324 -104 363 305 396 410 491 539 425 568 704 535 12 -339 -829 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