File name: Pandora31s1_CharlesCityVA_20241003_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T192604.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20241003_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20241003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241003T120506.4Z 9042.503547 72 1 30.26 2 79.36 103.80 88.01 102.68 0.00 1 0.00 1 0 17 4.138e-01 1.261e-02 3.093e-01 9.012e-03 6.403625e-01 4.861993e-03 7.211655e-03 -6.000000e+00 2.386427e-01 227.56 -2.00 3.44 -2.00 321.08 0.00e+00 5.759356e-03 2.293247e-03 5.573155e-04 -6.000000e+00 1.132038e-02 288.09 -2.00 20.00 -2.00 320.44 0.00e+00 5.204 0.002 302.00 328.00 3 3.3938e+00 1.6521e-02 6.1585e-02 -6.0000e+00 5.9015e-01 1.8432e-01 2.2155e-02 3.3982e-02 -6.0000e+00 6.4010e-01 -1.6124e-01 2.1104e-02 1.8496e-02 -6.0000e+00 3.8128e-01 6.1301e-02 1.0196e-02 9.2231e-03 -6.0000e+00 1.6341e-01 4.8018e-05 -7.1211e-04 2.5700e-04 9.5114e-05 -6.0000e+00 1.1526e-02 1.2483e-02 12 9 8 11 8 0 98.66 22.84 0.43 0.01248 0.00713 13 13 1 5 0 2327.210 25.58 20.00 22.84 29.68 9.7 1022.10 -123792 -42196 -216777 900000 900000 900000 -127962 -104966 -127773 -118724 86929 -82731 -45324 -51326 -36181 42860 76917 -14768 191508 -38640 -23937 -53640 -35989 -25836 -55659 117577 -37433 62614 -6565 32472 23884 58810 -14751 10870 -14308 7128 47842 -31637 31730 4854 3316 2611 -3264 18875 13099 -2035 -5970 10132 -1954 8776 -10693 13530 4698 3977 2492 1672 7920 -2 -187 256 7532 3062 9112 3816 4435 -2653 4556 2797 3282 2970 -1347 2269 45 2988 -2691 3715 -7569 -1996 -1871 -312 -1115 -2419 -2317 -1875 -692 546 2209 -540 2001 -343 1353 -2261 -609 -342 413 -573 1015 391 -566 584 -852 -776 -835 -1222 -1143 -849 -1714 216 -1185 -67 332 -378 245 210 754 -296 -663 -69 -271 43 748 651 392 -270 -187 1862 -321 1422 56 530 1492 293 264 -1036 -761 305 748 -343 -110 -539 630 -514 -549 -1208 -371 -6346 900000 900000 900000 -1527 -1123 -1883 -1715 764 -1016 -498 -770 -590 393 676 -291 1682 -1084 -597 -1760 -1044 -732 -2213 1033 -1334 852 -172 647 615 1299 -744 459 -731 298 1503 -2455 1646 381 294 249 -347 1676 1254 -230 -720 1089 -246 1070 -1738 1945 799 738 494 346 1581 0 -39 53 1508 704 2245 1106 1338 -837 1328 854 1096 1136 -588 994 20 1217 -1064 1248 -2661 -674 -705 -136 -567 -1411 -1469 -1252 -486 402 1681 -432 1566 -265 967 -1568 -401 -230 305 -489 976 427 -674 691 -965 -802 -797 -1170 -1166 -910 -1943 256 -1535 -95 512 -617 399 333 1133 -432 -971 -104 -433 72 1227 1037 606 -407 -272 2576 -440 1969 86 903 2729 572 536 -2230 -1725 717 1787 -839 -268 -1285 1418 -1112 -1153 SS 20241003T130942.1Z 9042.548403 95 1 30.11 2 67.26 114.93 76.26 113.03 0.00 1 0.00 1 0 25 1.487e-02 4.814e-03 1.215e-02 2.259e-03 3.358093e-01 1.142163e-03 3.933724e-03 -6.000000e+00 8.502057e-03 227.56 -2.00 3.44 -2.00 318.17 0.00e+00 1.066516e-04 2.143070e-04 1.064486e-04 -6.000000e+00 3.836654e-04 288.09 -2.00 20.00 -2.00 317.34 0.00e+00 2.566 0.000 302.00 328.00 3 4.3169e+00 3.0771e-03 3.0779e-02 -6.0000e+00 2.1077e-02 3.7122e-02 3.5062e-03 1.7063e-02 -6.0000e+00 2.2851e-02 5.7085e-03 2.2723e-03 8.3609e-03 -6.0000e+00 1.3660e-02 -9.4826e-03 1.1782e-03 2.3366e-03 -6.0000e+00 5.8555e-03 3.5605e-04 -8.6470e-05 6.5344e-05 2.5767e-05 -6.0000e+00 4.0255e-04 1.0775e-02 11 1 0 11 8 0 98.58 23.01 0.14 0.01077 0.01012 17 17 1 5 0 1770.690 25.79 20.00 23.01 31.11 9.8 1022.10 2014 -1367 -1697 -5273 -7593 -6970 -3441 1592 -1447 1061 -6101 -2527 -162 -3763 -1151 -3686 -963 876 -993 664 371 431 -1226 -222 1528 474 -103 -2104 -40 -1021 498 634 62 -432 -1850 -1680 -2946 -1021 29 26 -711 -1021 -762 -277 27 -341 -910 -814 50 288 1483 631 602 1307 983 1065 450 1005 333 1256 876 1144 1821 1057 267 436 -880 -23 711 686 160 326 -9 -416 -109 -227 -151 -954 -528 -305 -925 -1114 -1091 -1266 -1062 -599 -364 -382 416 392 411 128 662 359 645 -170 588 314 293 121 -525 -613 -299 -530 -579 -729 -623 -351 -166 270 218 111 278 -3 67 171 -119 145 180 -16 -227 -58 -108 311 323 501 559 801 543 550 303 152 -80 -2 -116 -118 25 -30 -181 -177 -93 -216 -453 108 -83 -107 -323 -430 -385 -198 99 -103 78 -482 -204 -15 -409 -141 -512 -138 130 -157 108 62 71 -213 -41 293 96 -21 -412 -7 -190 99 138 15 -106 -435 -392 -763 -302 10 10 -309 -464 -355 -130 13 -161 -427 -378 23 135 729 333 335 763 593 657 283 627 206 768 551 764 1305 805 205 318 -617 -16 517 551 139 292 -8 -361 -89 -171 -106 -655 -379 -241 -809 -1058 -1090 -1312 -1157 -682 -430 -461 501 460 458 134 654 349 657 -188 702 405 394 162 -679 -745 -347 -626 -723 -951 -837 -488 -239 408 343 178 437 -4 97 235 -164 203 265 -24 -355 -90 -164 458 460 691 747 1071 763 816 470 241 -129 -3 -199 -210 45 -54 -335 -323 -166 -375 -774 SS 20241003T131149.4Z 9042.549878 97 1 29.87 2 66.88 115.33 75.89 113.40 0.00 1 0.00 1 0 17 1.737e-02 5.129e-03 1.074e-02 2.139e-03 3.334032e-01 1.081362e-03 3.909180e-03 -6.000000e+00 9.931079e-03 227.56 -2.00 3.44 -2.00 318.12 0.00e+00 2.929609e-04 2.002859e-04 1.488420e-04 -6.000000e+00 4.481569e-04 288.09 -2.00 20.00 -2.00 317.29 0.00e+00 2.526 0.000 302.00 328.00 3 4.2454e+00 2.9103e-03 3.0388e-02 -6.0000e+00 2.4619e-02 4.2379e-02 3.3148e-03 1.6931e-02 -6.0000e+00 2.6691e-02 6.3333e-04 2.1341e-03 8.3076e-03 -6.0000e+00 1.5956e-02 -6.5461e-03 1.1015e-03 2.3309e-03 -6.0000e+00 6.8396e-03 3.9756e-04 -1.4860e-04 6.1912e-05 2.5149e-05 -6.0000e+00 4.7023e-04 1.0924e-02 10 0 0 10 0 0 98.24 23.01 0.28 0.01092 0.00981 19 19 1 5 0 1571.670 25.79 20.00 23.01 31.14 9.8 1022.24 -11458 -6607 -3787 -7129 -364 -5456 -1060 -4206 -1687 -4166 -3415 874 -742 -3407 -1339 -1590 -111 -123 -951 1448 -233 -1138 -1213 -1371 747 -805 1269 -156 -1016 -1157 1138 1256 1101 359 -2686 -2675 -202 -818 129 -968 -277 -77 -876 -686 -967 525 -561 395 -467 -102 490 889 1120 1452 1052 735 401 717 842 469 844 969 1964 1503 264 465 -282 224 214 825 -7 205 14 168 205 -369 -942 -1084 -391 -345 -917 -1446 -1134 -1579 -1322 -845 -87 138 0 -75 135 296 407 770 568 196 656 382 -23 248 -428 -673 -587 -449 -623 -645 -494 -516 -60 338 177 -13 224 -34 265 288 106 323 176 -200 -109 142 -61 437 327 498 419 968 677 324 290 -25 134 -229 -193 -126 168 -43 -239 -189 -283 -163 -336 -763 -462 -265 -483 -21 -318 -64 -296 -130 -346 -282 73 -73 -402 -165 -219 -16 -19 -152 235 -39 -192 -212 -257 146 -166 256 -30 -186 -214 224 272 263 89 -643 -634 -52 -247 47 -383 -119 -35 -412 -325 -459 247 -263 181 -214 -48 243 475 636 872 658 473 264 468 537 298 552 635 1397 1154 206 338 -194 152 155 675 -6 180 12 151 171 -278 -648 -774 -273 -273 -827 -1360 -1141 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