File name: Pandora31s1_CharlesCityVA_20250111_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20250407T145907.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20250111_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20250111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250111T131204.8Z 9142.550055 267 1 29.91 2 82.44 124.78 110.45 334.05 0.00 1 0.00 1 0 25 8.254e-01 1.346e-02 4.147e-01 7.921e-03 1.056660e+00 4.703827e-03 1.100050e-02 -6.000000e+00 4.690271e-01 224.03 -2.00 3.44 -2.00 322.34 0.00e+00 5.368122e-03 2.918528e-03 5.345112e-03 -6.000000e+00 2.395642e-02 278.73 -2.00 20.00 -2.00 321.93 0.00e+00 7.055 0.006 302.00 328.00 3 7.6594e-01 1.9045e-02 9.8471e-02 -6.0000e+00 1.1555e+00 6.2153e-01 3.3013e-02 8.2945e-02 -6.0000e+00 1.2596e+00 -7.5895e-01 3.7929e-02 3.9575e-02 -6.0000e+00 7.5285e-01 2.8547e-01 1.6603e-02 1.3605e-02 -6.0000e+00 3.3011e-01 7.4629e-05 -8.7823e-04 2.0681e-04 1.5558e-04 -6.0000e+00 2.3069e-02 -2.8827e-03 12 8 8 10 0 0 84.17 20.90 0.47 -0.00288 -0.00948 61 61 1 5 0 490.230 24.14 20.00 20.90 7.78 12.7 1021.21 900000 900000 -282698 900000 -343691 -347189 -225257 -372503 -44713 -146750 900000 -249170 900000 -190733 900000 -118087 19244 73067 -79313 900000 -109445 900000 -100339 900000 -116437 900000 -92397 -43763 -99517 32822 -42163 -116365 2799 -42016 271995 -96824 58037 5387 120601 8452 -26211 22558 5762 86450 -20255 73443 14581 25467 -2232 47051 16426 38370 19775 14298 28244 24277 21244 14208 38840 10125 31851 10717 28473 15042 18364 13925 11497 12754 6209 8370 4686 6436 3557 5248 -1017 3382 1344 -4405 1694 3384 930 -467 -870 -2304 1141 -908 2191 808 3254 3057 1980 1425 -3072 -300 -1990 -908 -1589 906 -573 291 -912 -468 -2439 -1751 -1849 -3890 -496 -2466 -1465 -678 -14 179 102 -493 -581 517 -341 281 -522 265 -322 912 385 1504 1051 770 792 945 954 -251 845 -296 437 -248 -170 -339 636 26 -38 258 -337 -119 -955 900000 900000 -2180 900000 -3854 -3894 -1737 -6266 -345 -1131 900000 -1921 900000 -1604 900000 -910 148 563 -612 900000 -1181 900000 -1006 900000 -1616 900000 -1069 -337 -1228 253 -455 -3099 30 -777 2097 -2647 447 75 930 169 -772 487 155 1066 -734 1076 405 687 -80 1270 633 1509 956 812 1505 1412 1310 926 1878 625 1607 744 1956 1402 1841 1503 1322 1564 918 1408 907 1272 705 942 -172 486 187 -695 298 728 250 -138 -291 -837 425 -364 887 339 1323 1198 734 505 -1141 -118 -933 -511 -1084 715 -517 267 -801 -363 -1688 -1149 -1278 -2904 -379 -2099 -1401 -755 -17 238 142 -699 -803 687 -459 393 -772 398 -471 1233 535 2004 1363 975 981 1236 1355 -429 1647 -649 1030 -636 -437 -922 1746 74 -106 678 -883 -283 -2162 SS 20250111T132142.7Z 9142.556745 270 1 30.08 2 80.88 126.41 111.21 336.05 0.00 1 0.00 1 0 25 7.737e-01 8.432e-03 2.832e-01 3.445e-03 9.053949e-01 1.929989e-03 9.673591e-03 -6.000000e+00 4.372976e-01 224.03 -2.00 3.44 -2.00 321.87 0.00e+00 3.852077e-03 1.084549e-03 1.294166e-03 -6.000000e+00 2.045868e-02 278.73 -2.00 20.00 -2.00 321.42 0.00e+00 5.988 0.004 302.00 328.00 3 6.7276e-01 7.1897e-03 7.7168e-02 -6.0000e+00 1.0790e+00 1.6960e-01 1.1816e-02 5.2475e-02 -6.0000e+00 1.1741e+00 -2.0460e-01 1.3673e-02 2.9365e-02 -6.0000e+00 6.9995e-01 7.1539e-02 6.1645e-03 1.1378e-02 -6.0000e+00 3.0191e-01 2.7982e-04 -6.8241e-04 8.9395e-05 1.3452e-04 -6.0000e+00 2.1413e-02 -3.7462e-03 11 8 0 10 0 0 59.20 20.91 0.26 -0.00375 -0.00887 134 134 1 5 0 224.470 24.14 20.00 20.91 8.56 12.9 1026.04 -293946 -71654 -312918 900000 -275102 -311114 -57161 -181748 -236992 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-209 1470 396 1263 867 697 1195 583 1332 608 1040 624 869 -20 57 -504 224 180 218 247 -248 -152 -1032 70 -612 119 -42 455 -115 42 -172 -409 -123 -653 -89 -507 568 -281 322 -792 -316 -1038 -767 -1388 -1262 -1003 -1427 119 -579 538 369 0 320 271 240 -70 256 -116 505 -443 745 -78 1190 538 698 658 868 257 47 1186 233 -219 -84 -794 -386 -20 -110 -26 223 -250 -316 -327 SS 20250111T133256.1Z 9142.564538 276 1 29.97 2 79.11 128.34 112.03 338.43 0.00 1 0.00 1 0 25 5.788e-01 6.281e-03 1.335e-01 1.727e-03 7.818410e-01 9.305262e-04 8.501319e-03 -6.000000e+00 3.271041e-01 224.03 -2.00 3.44 -2.00 321.33 0.00e+00 2.234963e-03 4.619824e-04 9.537426e-04 -6.000000e+00 1.436683e-02 278.73 -2.00 20.00 -2.00 320.85 0.00e+00 5.099 0.002 302.00 328.00 3 4.9865e-01 3.1565e-03 6.5157e-02 -6.0000e+00 8.0700e-01 7.3500e-02 4.6826e-03 4.2427e-02 -6.0000e+00 8.7792e-01 -7.5253e-02 5.2286e-03 2.2891e-02 -6.0000e+00 5.2328e-01 1.8914e-02 2.4566e-03 8.2747e-03 -6.0000e+00 2.2452e-01 8.7231e-04 -5.9219e-04 4.5642e-05 9.1646e-05 -6.0000e+00 1.5635e-02 -4.3311e-03 10 0 0 10 0 0 21.81 20.92 0.28 -0.00433 -0.00878 255 255 1 5 0 117.500 24.14 19.99 20.92 8.53 12.9 1024.06 -95700 -231047 -172314 -227153 -164764 -164407 -221482 -191169 -203441 -152829 -174681 -130404 -151007 -17643 -83764 -35135 -52674 -49076 -50411 -48969 -49224 -65154 -21107 -59866 -21424 -42519 -3055 -39752 -22259 -35202 -16637 -10319 -12443 3021 -17547 -10407 -24647 -496 -6098 2088 -1133 1780 3168 2819 2033 -4177 2971 -1281 2022 -79 4913 3712 5482 2925 3768 3064 2719 2879 579 1800 482 4305 3037 3436 2015 3839 2358 2479 2269 1816 2056 532 417 2 212 -1560 78 -865 -588 -792 -1107 -833 -1544 -1097 -1213 -575 -439 335 -34 297 565 462 170 -159 331 -172 537 256 62 -172 -76 -515 -589 -549 -1159 -993 -1226 -490 -369 120 165 306 149 291 191 449 196 50 -159 -231 -73 -15 124 108 340 213 572 556 254 376 238 260 -255 25 -470 -137 -138 119 3 -83 44 -166 42 -161 -1663 -842 -1913 -694 -692 -1828 -1353 -1885 -953 -1471 -835 -1577 -65 -790 -254 -532 -546 -628 -643 -672 -1054 -235 -999 -296 -781 -39 -723 -341 -688 -336 -221 -326 74 -519 -285 -864 -16 -266 103 -66 110 206 190 141 -318 219 -104 171 -8 503 402 651 394 543 468 433 458 91 274 76 726 600 780 502 940 589 649 662 617 776 214 166 1 72 -485 22 -257 -197 -321 -494 -430 -893 -674 -796 -399 -319 249 -25 212 377 290 104 -101 238 -145 491 272 73 -206 -86 -527 -540 -529 -1108 -1005 -1311 -559 -464 171 248 495 247 474 297 665 291 76 -258 -391 -122 -25 189 158 481 311 807 808 392 666 442 524 -547 58 -1086 -333 -345 300 8 -203 100 -374 91 SS 20250111T133806.9Z 9142.568136 279 1 30.05 2 78.30 129.26 112.37 339.55 0.00 1 0.00 1 0 25 4.469e-01 5.334e-03 9.256e-02 1.361e-03 7.402171e-01 7.244726e-04 8.120926e-03 -6.000000e+00 2.525821e-01 224.03 -2.00 3.44 -2.00 321.13 0.00e+00 2.136001e-03 3.406220e-04 7.786125e-04 -6.000000e+00 1.109414e-02 278.73 -2.00 20.00 -2.00 320.63 0.00e+00 4.777 0.002 302.00 328.00 3 4.6513e-01 2.3812e-03 6.1113e-02 -6.0000e+00 6.2315e-01 5.0707e-02 3.4111e-03 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