File name: Pandora31s1_CharlesCityVA_20250112_L2Fit_fwvt1c7d20240321p1-8.txt File generation date: 20250407T150942.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20250112_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20250112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1679 1829 Nominal wavelengths inside fitting window [nm]: 492.0417 492.1620 492.2824 492.4027 492.5230 492.6432 492.7635 492.8837 493.0039 493.1241 493.2443 493.3645 493.4847 493.6048 493.7249 493.8450 493.9651 494.0852 494.2052 494.3253 494.4453 494.5653 494.6853 494.8052 494.9252 495.0451 495.1651 495.2850 495.4048 495.5247 495.6446 495.7644 495.8842 496.0040 496.1238 496.2436 496.3633 496.4830 496.6028 496.7224 496.8421 496.9618 497.0814 497.2011 497.3207 497.4403 497.5599 497.6794 497.7990 497.9185 498.0380 498.1575 498.2770 498.3964 498.5159 498.6353 498.7547 498.8741 498.9935 499.1129 499.2322 499.3515 499.4708 499.5901 499.7094 499.8286 499.9479 500.0671 500.1863 500.3055 500.4247 500.5438 500.6630 500.7821 500.9012 501.0203 501.1393 501.2584 501.3774 501.4964 501.6154 501.7344 501.8534 501.9723 502.0913 502.2102 502.3291 502.4480 502.5668 502.6857 502.8045 502.9233 503.0421 503.1609 503.2797 503.3984 503.5171 503.6358 503.7545 503.8732 503.9919 504.1105 504.2291 504.3477 504.4663 504.5849 504.7035 504.8220 504.9405 505.0590 505.1775 505.2960 505.4144 505.5329 505.6513 505.7697 505.8881 506.0064 506.1248 506.2431 506.3614 506.4797 506.5980 506.7163 506.8345 506.9528 507.0710 507.1892 507.3073 507.4255 507.5436 507.6618 507.7799 507.8980 508.0160 508.1341 508.2521 508.3702 508.4882 508.6062 508.7241 508.8421 508.9600 509.0779 509.1958 509.3137 509.4316 509.5494 509.6673 509.7851 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250112T123635.6Z 9143.525412 275 1 31.12 2 88.38 118.92 99.62 316.12 0.00 1 0.00 1 0 15 5.444e-03 5.385e-03 1.182e-03 1.179e-03 7.114883e+03 7.639335e+01 4.658359e+02 -6.000000e+00 3.029132e+02 278.68 -2.00 20.00 -2.00 505.40 0.00e+00 2.688692e-03 3.256318e-05 1.472336e-04 -6.000000e+00 1.522151e-04 278.68 -2.00 20.00 -2.00 500.96 0.00e+00 1.101943e+00 2.296366e-02 6.405330e-02 -6.000000e+00 1.087959e-01 224.05 -2.00 3.44 -2.00 502.47 0.00e+00 17.139 0.085 489.00 513.00 1 5.7049e+00 1.7555e-03 2.8118e-02 -6.0000e+00 8.3373e-03 -1.5480e-02 4.4409e-04 2.0429e-03 -6.0000e+00 2.1592e-03 4.9853e-04 -1.3967e-03 1.2260e-04 7.9781e-05 -6.0000e+00 5.9161e-04 -8.1690e-03 12 8 8 10 0 0 68.58 20.31 3.47 -0.00817 -0.01786 10 10 1 4 0 3111.770 23.64 20.00 20.31 3.20 12.7 1021.24 -1591 -1472 -929 -340 -59 114 504 361 434 382 226 -54 -283 -452 -821 -711 -415 -192 254 260 18 363 318 450 513 687 397 544 164 -181 -547 -808 -765 -28 644 259 239 405 358 167 -82 180 103 594 652 793 930 467 308 235 -607 -594 -892 -963 -648 -271 186 -34 512 267 434 792 859 513 727 725 29 28 -110 -417 -696 -523 -482 -416 -199 39 -411 -547 -786 -679 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9143.527793 280 1 29.51 2 87.79 119.45 100.07 316.69 0.00 1 0.00 1 0 15 4.577e-03 4.552e-03 9.656e-04 9.635e-04 6.664068e+03 6.192888e+01 4.506188e+02 -6.000000e+00 2.546572e+02 278.68 -2.00 20.00 -2.00 505.37 0.00e+00 2.517838e-03 2.671202e-05 1.398233e-04 -6.000000e+00 1.279888e-04 278.68 -2.00 20.00 -2.00 500.89 0.00e+00 1.038793e+00 1.886174e-02 5.705998e-02 -6.000000e+00 9.151524e-02 224.05 -2.00 3.44 -2.00 502.42 0.00e+00 15.535 0.063 489.00 513.00 1 5.5236e+00 1.4436e-03 2.4710e-02 -6.0000e+00 7.0122e-03 -1.9785e-02 3.6550e-04 1.8187e-03 -6.0000e+00 1.8174e-03 7.5677e-04 -1.2153e-04 1.0032e-04 7.8546e-05 -6.0000e+00 4.9724e-04 -1.6891e-02 11 8 0 10 0 0 51.94 20.31 2.91 -0.01689 -0.01773 13 13 1 4 0 2269.930 23.64 20.00 20.31 3.64 12.6 1021.44 -908 -1210 -804 -243 -66 233 762 723 604 408 39 22 -132 -366 -479 -580 -387 -141 200 105 23 378 285 225 575 492 380 482 103 -208 -259 -583 -671 -95 404 222 49 211 135 -252 152 41 134 363 571 727 722 520 471 -46 -335 -613 -893 -777 -730 -157 -61 99 157 222 318 693 458 431 447 528 202 -46 -238 -395 -446 -560 -620 -355 66 -56 -288 -467 -502 -507 -686 -486 -498 -425 -278 -137 -324 -240 -263 20 90 -34 421 524 682 299 264 55 -191 -448 -696 -1005 -814 -501 103 -186 -304 -187 -383 -302 -184 -57 173 483 480 521 997 1108 977 543 430 160 194 192 357 251 242 357 -46 305 433 40 -319 -152 -386 -514 -144 165 -99 258 317 275 225 261 188 11 -78 -240 -690 -1031 -841 -819 -1106 -722 -224 -63 227 726 698 585 394 37 21 -128 -352 -459 -557 -362 -134 194 104 23 378 287 227 562 484 373 470 102 -203 -248 -557 -651 -94 397 222 50 211 134 -249 149 41 135 368 585 749 745 534 478 -46 -328 -588 -877 -762 -701 -155 -62 98 157 222 319 695 463 437 453 529 201 -45 -240 -395 -441 -553 -616 -357 64 -54 -281 -466 -495 -497 -671 -477 -493 -424 -270 -134 -321 -238 -261 20 90 -34 427 535 695 302 261 54 -187 -431 -663 -962 -794 -486 103 -185 -305 -187 -381 -299 -184 -57 177 501 502 550 1054 1143 1013 564 442 163 201 198 369 262 254 363 -47 311 440 41 -332 -156 -394 -528 -149 168 -103 273 340 289 238 278 202 11 -83 -254 -718 -1094 -888 SQ 20250112T124256.5Z 9143.529821 284 1 29.46 2 87.28 119.91 100.45 317.18 0.00 1 0.00 1 0 15 4.036e-03 4.007e-03 7.802e-04 7.784e-04 6.398026e+03 4.999626e+01 4.346094e+02 -6.000000e+00 2.245481e+02 278.68 -2.00 20.00 -2.00 505.37 0.00e+00 2.255885e-03 2.147716e-05 1.271605e-04 -6.000000e+00 1.128481e-04 278.68 -2.00 20.00 -2.00 500.86 0.00e+00 9.750084e-01 1.519610e-02 5.417925e-02 -6.000000e+00 8.067876e-02 224.05 -2.00 3.44 -2.00 502.40 0.00e+00 14.243 0.048 489.00 513.00 1 5.3169e+00 1.1614e-03 2.2234e-02 -6.0000e+00 6.1821e-03 -2.3226e-02 2.9533e-04 1.6854e-03 -6.0000e+00 1.6019e-03 1.1284e-03 -6.0655e-04 8.1027e-05 7.3566e-05 -6.0000e+00 4.3848e-04 -1.3980e-02 11 8 0 10 0 0 69.34 20.31 2.47 -0.01398 -0.01819 18 18 1 4 0 1636.460 23.64 20.00 20.31 3.91 12.6 1021.56 -866 -931 -438 -55 -101 236 581 610 629 385 308 172 -96 -246 -528 -433 -502 -220 151 163 178 254 368 183 485 344 326 415 173 -274 -347 -348 -452 -51 404 71 -25 270 110 -84 -74 51 169 267 335 487 571 269 388 -44 -324 -497 -784 -949 -734 -173 -53 49 170 167 265 466 533 293 296 296 120 -94 50 -281 -398 -335 -366 -524 -10 -41 -426 -612 -401 -430 -591 -377 -358 -453 -250 53 -204 -295 -180 -93 -83 21 261 546 454 370 290 96 -223 -450 -904 -774 -712 -492 2 -198 -313 -188 -352 -393 -105 -69 131 355 551 575 814 940 736 645 484 250 24 125 454 211 16 304 139 227 263 205 -153 -101 -249 -506 -144 142 99 205 415 268 329 265 173 -35 -28 -369 -634 -789 -894 -791 -859 -398 -51 -98 226 564 600 620 378 300 165 -91 -232 -495 -407 -478 -213 149 158 175 251 364 182 484 345 326 413 170 -263 -338 -337 -444 -50 404 72 -26 274 111 -85 -74 52 171 266 338 494 580 272 387 -44 -322 -484 -752 -911 -715 -172 -52 50 173 170 270 475 547 302 305 302 121 -94 50 -274 -386 -324 -356 -516 -10 -41 -423 -600 -387 -412 -566 -362 -347 -443 -247 53 -205 -297 -181 -94 -84 21 260 548 456 367 291 94 -214 -425 -846 -725 -679 -485 2 -200 -320 -191 -356 -396 -107 -71 132 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