File name: Pandora31s1_CharlesCityVA_20250123_L2Fit_fwvt1c7d20240321p1-8.txt File generation date: 20250407T151608.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20250123_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20250123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1679 1829 Nominal wavelengths inside fitting window [nm]: 492.0417 492.1620 492.2824 492.4027 492.5230 492.6432 492.7635 492.8837 493.0039 493.1241 493.2443 493.3645 493.4847 493.6048 493.7249 493.8450 493.9651 494.0852 494.2052 494.3253 494.4453 494.5653 494.6853 494.8052 494.9252 495.0451 495.1651 495.2850 495.4048 495.5247 495.6446 495.7644 495.8842 496.0040 496.1238 496.2436 496.3633 496.4830 496.6028 496.7224 496.8421 496.9618 497.0814 497.2011 497.3207 497.4403 497.5599 497.6794 497.7990 497.9185 498.0380 498.1575 498.2770 498.3964 498.5159 498.6353 498.7547 498.8741 498.9935 499.1129 499.2322 499.3515 499.4708 499.5901 499.7094 499.8286 499.9479 500.0671 500.1863 500.3055 500.4247 500.5438 500.6630 500.7821 500.9012 501.0203 501.1393 501.2584 501.3774 501.4964 501.6154 501.7344 501.8534 501.9723 502.0913 502.2102 502.3291 502.4480 502.5668 502.6857 502.8045 502.9233 503.0421 503.1609 503.2797 503.3984 503.5171 503.6358 503.7545 503.8732 503.9919 504.1105 504.2291 504.3477 504.4663 504.5849 504.7035 504.8220 504.9405 505.0590 505.1775 505.2960 505.4144 505.5329 505.6513 505.7697 505.8881 506.0064 506.1248 506.2431 506.3614 506.4797 506.5980 506.7163 506.8345 506.9528 507.0710 507.1892 507.3073 507.4255 507.5436 507.6618 507.7799 507.8980 508.0160 508.1341 508.2521 508.3702 508.4882 508.6062 508.7241 508.8421 508.9600 509.0779 509.1958 509.3137 509.4316 509.5494 509.6673 509.7851 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250123T132748.8Z 9154.560981 254 1 30.32 2 78.77 125.11 63.07 199.92 0.00 1 0.00 1 0 22 2.046e-03 2.034e-03 9.307e-04 9.296e-04 1.167479e+03 5.327960e+01 9.507750e+01 -6.000000e+00 1.137351e+02 278.44 -2.00 20.00 -2.00 505.27 0.00e+00 1.405131e-03 2.543766e-05 8.007575e-05 -6.000000e+00 5.715541e-05 278.44 -2.00 20.00 -2.00 500.53 0.00e+00 4.705697e-01 1.840188e-02 1.409341e-02 -6.000000e+00 4.088867e-02 224.37 -2.00 3.44 -2.00 502.11 0.00e+00 4.961 0.002 489.00 513.00 1 7.0618e+00 1.4085e-03 7.4486e-03 -6.0000e+00 3.1333e-03 1.9917e-04 3.6465e-04 4.5229e-04 -6.0000e+00 8.1104e-04 7.8407e-04 -3.3381e-03 9.9014e-05 3.3567e-05 -6.0000e+00 2.2235e-04 -1.3895e-03 10 0 0 10 0 0 98.55 19.60 1.45 -0.00139 -0.02454 13 13 1 4 0 2331.850 23.11 20.01 19.60 0.63 12.0 1031.26 -348 -210 21 134 -208 -70 509 317 335 218 178 253 121 -121 -45 -179 -204 -53 36 -123 70 -39 90 49 270 155 139 357 -13 -183 -64 -182 -389 -43 303 55 -55 83 125 -96 8 -100 14 -24 140 272 169 -84 224 89 -181 -237 -294 -524 -429 -112 -135 -152 -170 -193 182 97 71 -47 141 27 -74 -154 133 -60 -149 -265 -222 -296 87 152 -199 -304 50 30 70 69 -147 -228 -70 310 -42 -149 1 65 -29 -61 196 132 102 234 196 83 -165 -218 -264 -285 -523 -130 -8 -155 -363 -119 -191 -354 68 -115 57 -17 59 11 113 309 426 234 110 229 -20 138 303 172 -43 -122 113 83 271 62 -128 209 212 -238 220 318 -11 91 307 209 170 239 3 118 -87 -85 -412 -421 -421 -328 -199 20 133 -207 -71 525 332 351 227 184 257 121 -120 -44 -176 -202 -54 37 -129 72 -40 93 50 279 161 144 365 -13 -186 -63 -179 -389 -44 307 56 -57 86 127 -97 8 -101 15 -24 145 284 177 -87 229 89 -184 -234 -286 -508 -421 -113 -135 -155 -175 -198 186 100 73 -49 145 28 -75 -153 129 -60 -147 -262 -220 -287 85 149 -194 -293 49 29 68 68 -144 -219 -67 301 -41 -147 1 65 -29 -61 199 131 102 231 197 82 -160 -207 -254 -275 -494 -126 -8 -153 -359 -116 -191 -352 67 -112 56 -18 60 11 116 319 440 240 112 229 -20 136 298 170 -43 -121 112 83 267 61 -124 199 207 -233 209 308 -11 92 311 207 169 239 3 118 -87 -83 -411 -412 -410 SQ 20250123T133202.9Z 9154.563923 257 1 29.44 2 78.09 125.85 63.37 200.94 0.00 1 0.00 1 0 15 2.036e-03 2.021e-03 6.744e-04 6.737e-04 1.124788e+03 3.850088e+01 9.485060e+01 -6.000000e+00 1.131982e+02 278.44 -2.00 20.00 -2.00 505.27 0.00e+00 1.241567e-03 1.843970e-05 7.100369e-05 -6.000000e+00 5.688332e-05 278.44 -2.00 20.00 -2.00 500.53 0.00e+00 3.865654e-01 1.331545e-02 1.242424e-02 -6.000000e+00 4.068746e-02 224.37 -2.00 3.44 -2.00 502.11 0.00e+00 4.697 0.002 489.00 513.00 1 6.4788e+00 1.0193e-03 7.0130e-03 -6.0000e+00 3.1180e-03 -1.7409e-03 2.6373e-04 4.2371e-04 -6.0000e+00 8.0689e-04 1.4711e-03 -3.6115e-03 7.1730e-05 3.0656e-05 -6.0000e+00 2.2131e-04 1.0951e-03 10 0 0 10 0 0 99.21 19.62 1.44 0.00110 -0.02396 20 20 1 4 0 1471.860 23.11 20.01 19.62 0.91 12.0 1031.10 -146 -230 -66 180 -28 154 318 298 263 197 120 208 51 -112 13 -164 -174 -153 172 -48 -178 82 -33 56 304 184 1 338 151 -177 -81 -92 -249 -91 310 -55 -42 -33 161 -141 -24 109 32 -115 99 80 147 196 201 36 -261 -179 -325 -547 -381 -191 -137 -127 -143 -55 -4 104 220 0 194 180 52 -104 11 -88 -323 -262 -352 -297 -7 29 -172 -117 -92 2 -91 -47 15 -200 49 139 -195 -108 -57 -27 108 -25 234 339 79 266 234 -30 -146 -98 -217 -518 -515 -233 73 -212 -194 -163 -275 -227 99 -28 -64 -39 35 20 125 383 378 232 336 152 -126 -2 272 123 20 154 -27 86 384 65 -27 106 -21 -225 181 366 26 233 242 306 123 178 57 144 11 -71 -549 -447 -425 -140 -222 -64 177 -29 156 326 310 274 204 123 210 51 -113 14 -165 -172 -154 176 -50 -183 84 -34 58 314 190 1 345 156 -179 -80 -90 -247 -93 314 -56 -44 -34 163 -142 -24 110 33 -119 103 83 154 203 205 36 -263 -176 -314 -527 -372 -191 -137 -129 -146 -56 -4 106 225 0 199 183 53 -103 11 -88 -319 -257 -348 -296 -7 28 -168 -116 -89 2 -88 -46 15 -198 47 135 -192 -106 -56 -27 107 -25 237 338 79 264 235 -30 -141 -93 -208 -498 -488 -226 73 -210 -193 -161 -276 -226 99 -28 -64 -39 36 20 126 387 381 233 342 153 -125 -2 269 123 20 153 -27 86 380 64 -27 102 -21 -214 174 356 25 234 240 305 123 180 58 146 11 -70 -536 -440 -416 SQ 20250123T133620.4Z 9154.566903 260 1 30.10 2 77.40 126.61 63.69 201.96 0.00 1 0.00 1 0 15 1.938e-03 1.928e-03 3.397e-04 3.393e-04 9.871666e+02 1.925561e+01 8.177464e+01 -6.000000e+00 1.077145e+02 278.44 -2.00 20.00 -2.00 505.27 0.00e+00 1.176399e-03 9.289843e-06 6.730561e-05 -6.000000e+00 5.412862e-05 278.44 -2.00 20.00 -2.00 500.53 0.00e+00 3.971750e-01 6.710818e-03 1.181528e-02 -6.000000e+00 3.872014e-02 224.37 -2.00 3.44 -2.00 502.11 0.00e+00 4.458 0.001 489.00 513.00 1 5.2022e+00 5.1380e-04 6.6554e-03 -6.0000e+00 2.9671e-03 -4.5390e-03 1.3302e-04 3.9948e-04 -6.0000e+00 7.6795e-04 5.4575e-03 -3.3812e-03 3.6186e-05 2.8659e-05 -6.0000e+00 2.1058e-04 -1.1953e-04 10 0 0 10 0 0 98.51 19.63 1.43 -0.00012 -0.02357 71 71 1 4 0 423.910 23.11 20.00 19.63 1.25 12.0 1031.21 -208 -202 -17 64 -79 92 319 402 281 213 159 178 8 -62 -79 -181 -275 -133 146 -45 -110 47 167 102 288 160 14 301 18 -161 -164 -77 -358 42 299 -56 -152 101 103 -74 71 21 -87 35 198 169 227 112 117 83 -217 -218 -365 -487 -367 -163 -205 -205 -130 -49 24 137 144 64 137 94 11 -49 88 -79 -283 -255 -228 -301 26 132 -149 -187 -32 -93 -118 -75 -120 -265 -11 88 -17 -71 -7 -7 41 -23 257 239 105 136 207 126 -206 -118 -259 -379 -483 -287 -62 -211 -237 -130 -224 -172 -78 12 -53 69 186 135 266 347 367 243 203 114 -91 66 263 8 -27 121 -71 54 225 202 -52 147 29 -106 228 314 88 78 318 221 125 109 171 32 -24 -187 -402 -458 -405 -198 -194 -16 63 -80 93 328 418 293 221 163 180 8 -61 -79 -182 -272 -134 150 -46 -113 48 172 106 299 167 15 310 18 -163 -163 -76 -357 43 304 -58 -158 105 106 -75 72 21 -89 36 206 173 233 117 120 83 -213 -215 -353 -470 -359 -163 -205 -210 -134 -51 25 141 145 65 138 96 11 -49 86 -77 -280 -251 -226 -293 26 130 -146 -181 -31 -90 -115 -73 -118 -255 -10 87 -16 -70 -7 -7 41 -22 256 241 107 137 205 125 -201 -113 -250 -366 -461 -281 -61 -211 -238 -130 -221 -168 -76 12 -53 69 187 137 272 356 376 248 204 113 -90 66 264 8 -27 119 -70 53 220 202 -51 143 27 -102 220 309 86 78 319 224 124 109 172 33 -24 -188 -398 -445 -390 SQ 20250123T134544.0Z 9154.573426 263 1 30.22 2 75.92 128.30 64.42 204.17 0.00 1 0.00 1 0 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