File name: Pandora31s1_CharlesCityVA_20250126_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20250407T151900.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20250126_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20250126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250126T131553.2Z 9157.552699 121 1 30.56 2 80.33 122.41 69.87 159.49 0.00 1 0.00 1 0 25 4.446e-01 1.281e-02 3.604e-01 1.087e-02 6.982173e-01 5.966738e-03 7.681491e-03 -6.000000e+00 2.519484e-01 224.46 -2.00 3.44 -2.00 321.38 0.00e+00 -2.456936e-03 2.913325e-03 9.300682e-04 -6.000000e+00 1.157543e-02 278.41 -2.00 20.00 -2.00 320.89 0.00e+00 5.682 0.003 302.00 328.00 3 3.1598e+00 2.0381e-02 6.7133e-02 -6.0000e+00 6.2204e-01 1.5486e-01 2.8461e-02 3.7261e-02 -6.0000e+00 6.7715e-01 -1.6972e-01 2.9968e-02 2.0068e-02 -6.0000e+00 4.0406e-01 6.0525e-02 1.4258e-02 6.5692e-03 -6.0000e+00 1.7428e-01 3.8934e-05 -5.1558e-04 3.1537e-04 8.4719e-05 -6.0000e+00 1.2291e-02 -1.7667e-03 12 8 8 10 0 0 77.35 21.16 0.29 -0.00177 -0.00564 18 18 1 5 0 1697.680 24.35 20.00 21.16 12.30 12.8 1027.80 6900 900000 -224534 -80147 -223566 78018 -124003 -82992 -30397 113694 -141011 -34469 900000 900000 900000 187711 -68347 -41196 62481 -53019 900000 -81143 -72737 -35993 -24817 -9061 52757 900000 -36225 82464 -6310 -24466 13624 70410 36143 48557 9641 -23018 15384 -9566 28514 5477 391 8457 8044 -17397 -14261 3606 6676 14249 -6003 18969 -663 13715 1006 22265 3144 7045 -3639 1265 5815 -8069 4998 2956 11411 -3035 3885 -1592 5830 2707 -762 -1405 2417 1171 -3114 -1557 -6251 -2354 330 1298 -2839 650 -2101 -2448 -941 -344 2841 972 1786 -1036 1237 1185 2492 -840 1403 -2872 805 1513 886 313 -2045 323 -1831 -824 -1576 -1076 -2620 -2452 -8 -809 1395 946 -5 -480 854 -630 572 -732 -701 -525 236 579 544 1511 76 438 -429 1371 -168 1278 813 173 -128 -256 -440 -90 325 -619 36 165 292 -35 -740 73 900000 -4067 -849 -3632 826 -1313 -879 -322 1204 -1879 -365 900000 900000 900000 1988 -1345 -696 662 -1139 900000 -2343 -2075 -821 -565 -191 638 900000 -944 873 -157 -853 386 1272 869 1036 325 -1244 717 -673 1603 409 32 655 628 -1747 -1421 316 596 1277 -725 2037 -94 1856 164 3134 550 1190 -660 214 962 -1652 1027 697 2637 -794 948 -424 1595 876 -282 -547 902 420 -1069 -474 -1864 -685 104 477 -1266 321 -1172 -1456 -587 -227 1911 684 1246 -720 790 714 1434 -513 934 -2279 710 1507 968 348 -2205 311 -1645 -726 -1490 -1068 -2775 -2763 -9 -1086 2030 1473 -8 -753 1266 -909 815 -1092 -1099 -853 381 900 818 2189 108 600 -574 1851 -254 2146 1503 342 -266 -562 -1024 -219 807 -1573 92 407 682 -77 -1592 SS 20250126T133158.1Z 9157.563867 132 1 31.09 2 77.67 125.19 68.87 162.98 0.00 1 0.00 1 0 25 2.556e-01 7.488e-03 2.118e-01 5.299e-03 5.738771e-01 2.763754e-03 6.465433e-03 -6.000000e+00 1.446983e-01 224.46 -2.00 3.44 -2.00 320.57 0.00e+00 2.108091e-03 1.073257e-03 3.811289e-04 -6.000000e+00 6.368919e-03 278.41 -2.00 20.00 -2.00 320.03 0.00e+00 4.549 0.002 302.00 328.00 3 3.4859e+00 8.4310e-03 5.3827e-02 -6.0000e+00 3.5736e-01 8.1247e-02 1.0826e-02 2.9654e-02 -6.0000e+00 3.8883e-01 -4.7712e-02 1.0632e-02 1.5482e-02 -6.0000e+00 2.3162e-01 5.9486e-03 5.3372e-03 5.4284e-03 -6.0000e+00 9.9931e-02 9.1750e-05 -4.8228e-04 1.5127e-04 5.8755e-05 -6.0000e+00 6.9533e-03 -2.3388e-03 11 8 0 10 0 0 99.74 21.18 0.36 -0.00234 -0.00596 14 14 1 5 0 2220.150 24.35 19.99 21.18 13.29 12.9 1027.94 900000 -100635 22428 -82041 -12360 -119373 -113375 151821 -35614 24380 -96905 21712 -41463 15889 -28269 -23627 -20763 26124 24888 -14457 12185 -31359 6426 -2104 13214 -26409 5159 -16475 -904 1476 1487 15363 -11940 -1373 -13664 5910 -2558 2646 -13246 5218 -7720 1716 7877 -2183 3919 -3986 6138 -154 5275 -1504 1673 2018 2602 1532 989 2191 -968 4160 -1670 1866 -1805 6332 -846 3354 -218 -157 2008 -809 1680 -677 2479 325 1488 -380 -164 -1478 1318 -2881 -66 -554 -1215 -295 -2006 -448 -2092 57 -335 1390 -488 -11 342 0 2052 77 357 -1004 1115 -142 -133 895 -236 -1189 -781 -973 -945 -429 -834 239 -481 171 -316 651 755 -175 146 189 9 -73 783 -409 -155 -584 -94 221 612 656 -5 130 267 717 156 541 -247 4 -423 -297 8 -5 -61 -297 171 -48 14 900000 -1336 116 -960 -68 -1816 -1766 784 -341 143 -1884 152 -659 184 -614 -579 -553 491 511 -454 307 -1193 180 -69 407 -1252 185 -705 -33 56 65 692 -794 -89 -954 340 -175 203 -1436 566 -1061 231 1052 -328 564 -631 898 -25 826 -266 316 422 588 378 260 591 -276 1135 -469 501 -516 1825 -292 1239 -87 -61 749 -316 695 -325 1271 177 800 -199 -79 -656 531 -1202 -29 -285 -722 -196 -1465 -340 -1704 49 -298 1254 -449 -10 286 0 1520 58 293 -939 1153 -166 -167 1122 -285 -1335 -810 -1008 -1037 -494 -1005 301 -649 249 -500 1070 1244 -282 224 278 13 -111 1235 -677 -258 -952 -148 339 906 942 -7 184 408 1197 280 1018 -482 8 -904 -662 19 -11 -142 -676 373 -101 28 SS 20250126T133727.6Z 9157.567681 135 1 32.00 2 76.78 126.17 68.57 164.19 0.00 1 0.00 1 0 17 2.591e-01 1.168e-02 2.142e-01 9.370e-03 5.369623e-01 4.847586e-03 6.212609e-03 -6.000000e+00 1.466266e-01 224.46 -2.00 3.44 -2.00 320.43 0.00e+00 5.406255e-05 1.763675e-03 1.856537e-03 -6.000000e+00 6.422298e-03 278.41 -2.00 20.00 -2.00 319.87 0.00e+00 4.265 0.001 302.00 328.00 3 4.6122e+00 1.4533e-02 5.1085e-02 -6.0000e+00 3.6214e-01 1.1424e-01 1.8192e-02 2.9866e-02 -6.0000e+00 3.9389e-01 -7.9002e-02 1.6822e-02 1.4696e-02 -6.0000e+00 2.3465e-01 2.6395e-02 8.5377e-03 4.2292e-03 -6.0000e+00 1.0054e-01 4.0107e-05 -8.8039e-04 2.7026e-04 5.3736e-05 -6.0000e+00 7.0000e-03 -2.8538e-03 12 8 8 10 0 0 89.01 21.18 0.19 -0.00285 -0.00947 8 8 1 5 0 3999.250 24.35 20.00 21.18 13.47 12.8 1027.24 -95332 -65671 -65221 -50485 -45489 -77710 -49115 -83667 -93422 -103832 69482 -73346 16799 19966 -58997 -41772 5756 18318 -32058 21898 25615 107238 12834 31142 -13171 16330 -8234 -4790 4967 -14173 24381 5874 -3355 -5011 25279 11644 -4934 -7325 5126 -5122 1690 -943 -618 -2158 1621 8483 -2276 -5620 5722 4619 -1444 2709 2281 -2166 1004 3150 2254 4054 -1973 -531 1740 3240 2427 2513 2243 2093 -2293 -5041 2726 1858 4205 1806 2071 2614 -2354 -260 -2359 975 -2240 -2354 236 -2745 59 -3277 501 878 1181 1986 979 -547 618 -1178 -1477 -1314 -308 473 635 493 27 -350 -801 -1650 -1183 -1334 -2624 -1970 -1427 -756 335 756 561 574 177 -518 37 1 -635 -724 302 -232 1859 1390 376 500 1326 979 -249 25 -1328 -133 930 467 948 86 -614 -115 121 54 -195 -676 90 -466 -108 -1749 -1047 -1100 -723 -571 -1288 -677 -1798 -2481 -3282 635 -1978 238 335 -2458 -1721 168 516 -1538 670 778 1543 458 1023 -704 702 -452 -246 224 -797 1087 359 -253 -409 1489 769 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