File name: Pandora31s1_CharlesCityVA_20250614_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20250615T052043.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20250614_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20250614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250614T105412.1Z 9296.454307 231 1 30.21 2 78.94 69.06 76.16 223.05 0.00 1 0.00 1 0 25 3.875e-01 1.358e-02 2.808e-01 9.229e-03 6.525395e-01 5.153411e-03 7.230653e-03 -6.000000e+00 2.281334e-01 232.79 -2.00 3.44 -2.00 321.16 0.00e+00 -6.924068e-04 2.445901e-03 1.195247e-03 -6.000000e+00 1.105359e-02 288.66 -2.00 20.00 -2.00 320.52 0.00e+00 5.023 0.002 302.00 328.00 3 3.3539e+00 1.7868e-02 6.1287e-02 -6.0000e+00 5.7453e-01 1.5551e-01 2.4106e-02 3.5852e-02 -6.0000e+00 6.2193e-01 -1.3825e-01 2.2684e-02 1.7407e-02 -6.0000e+00 3.6725e-01 5.0709e-02 1.0826e-02 4.9650e-03 -6.0000e+00 1.5653e-01 5.9096e-05 -9.0536e-04 2.6931e-04 6.1467e-05 -6.0000e+00 1.0926e-02 2.1908e-02 12 8 8 10 0 0 99.97 23.88 0.70 0.02191 0.01510 29 29 1 5 0 1041.710 26.51 19.99 23.88 32.48 0.7 1017.48 -167631 900000 -147279 900000 -105124 -94280 900000 -120875 900000 -148456 900000 -95231 19250 -118171 900000 -111613 -4003 -33015 -66864 83889 -23568 900000 29658 136938 -70968 34151 17649 39077 -43918 5039 14498 12785 48289 -14220 34739 -33655 25158 -15740 17504 -9560 7945 -3165 11291 10925 -1656 16406 1391 14014 -17182 11547 -3299 11602 2884 9002 -996 -555 3853 115 9495 -2854 2008 -720 9876 4976 11548 -4192 5569 4130 8519 2639 1536 3480 -2625 1967 -1867 -802 -509 -1002 -5153 -1048 -2086 -1515 770 -4980 969 -2781 2344 98 2319 -625 2339 319 1176 -316 -1045 598 -557 529 -1668 1068 -1964 1381 -1499 -637 -3073 -1679 -19 -122 635 -57 463 -778 782 -642 882 -1091 315 -178 -272 -653 -4 945 -554 999 -228 1831 747 1913 133 -796 117 661 338 -410 901 42 166 31 -19 -272 -236 -606 -617 -2202 900000 -1935 900000 -945 -847 900000 -1421 900000 -2874 900000 -1317 173 -3035 900000 -3941 -58 -708 -2018 754 -538 900000 431 1231 -3190 614 378 648 -1640 125 391 415 1269 -685 1057 -1902 957 -1011 1000 -859 673 -321 1037 1024 -178 1496 150 1377 -2416 1312 -487 1654 460 1473 -192 -111 764 24 1718 -575 398 -162 2267 1342 3038 -1256 1498 1171 2573 976 632 1464 -1158 781 -703 -268 -159 -319 -1918 -443 -1041 -858 467 -3393 667 -1987 1671 73 1694 -452 1629 212 746 -210 -781 476 -518 556 -1943 1209 -2148 1319 -1351 -573 -3049 -1737 -20 -141 791 -80 714 -1283 1272 -1023 1308 -1578 452 -267 -435 -1090 -6 1489 -853 1462 -324 2452 975 2555 202 -1376 207 1241 668 -865 2007 100 402 78 -48 -646 -528 -1283 -1260 SS 20250614T125012.5Z 9296.534867 319 1 29.78 2 56.55 84.72 93.65 241.88 0.00 1 0.00 1 0 17 1.140e-02 5.809e-03 1.020e-02 3.411e-03 2.543137e-01 1.751463e-03 2.971693e-03 -6.000000e+00 6.635371e-03 232.79 -2.00 3.44 -2.00 317.21 0.00e+00 2.918589e-04 2.463984e-04 1.876298e-04 -6.000000e+00 2.946149e-04 288.66 -2.00 20.00 -2.00 316.36 0.00e+00 1.808 0.000 302.00 328.00 3 5.7668e+00 4.6652e-03 2.2455e-02 -6.0000e+00 1.6657e-02 5.1505e-02 5.2325e-03 1.3117e-02 -6.0000e+00 1.7993e-02 2.3716e-03 3.1012e-03 6.3244e-03 -6.0000e+00 1.0712e-02 -6.5744e-03 1.5086e-03 1.7164e-03 -6.0000e+00 4.5380e-03 1.9503e-04 1.4024e-04 9.8815e-05 1.9331e-05 -6.0000e+00 3.0902e-04 1.8714e-02 11 1 0 11 8 0 99.99 24.00 0.29 0.01871 0.01977 10 10 1 5 0 2977.490 26.62 20.00 24.00 32.88 0.6 1018.91 -2037 -2125 -5348 -3319 -1030 -2061 -3896 1199 1837 386 -705 712 1446 1856 -97 -618 -1406 431 44 -2657 1075 174 1477 313 952 -142 -735 217 2642 1373 1422 1409 2079 1117 -2443 -2235 -1533 -627 471 -438 -1821 -967 -95 -1480 -159 76 -116 -329 -1935 -100 840 -3 1565 1152 433 463 279 796 -160 1109 228 1814 1931 878 -179 489 -134 -692 463 1444 221 381 202 457 -377 -1123 -1021 -862 -1088 -1651 -739 -1039 -1296 -901 -846 212 83 578 460 321 123 29 -583 -343 129 91 452 276 -324 181 -207 -629 -558 -784 -610 -930 -779 117 -124 421 650 844 240 289 26 -298 78 82 242 -279 304 210 -6 131 398 375 364 618 453 19 34 -364 -478 38 -40 -131 -99 575 -63 -189 -8 -245 -472 -242 -272 -715 -404 -110 -218 -449 148 248 55 -100 103 234 340 -20 -141 -336 105 11 -714 283 46 396 89 283 -44 -227 62 699 367 402 428 673 369 -782 -711 -531 -249 218 -232 -1046 -570 -57 -901 -96 45 -68 -190 -1114 -57 502 -2 1031 794 307 334 204 578 -115 790 168 1404 1595 767 -156 395 -103 -524 368 1260 209 370 195 428 -336 -923 -774 -629 -828 -1391 -676 -1029 -1349 -970 -959 251 102 726 580 392 142 32 -591 -339 133 101 541 356 -437 240 -263 -754 -643 -927 -767 -1219 -1055 163 -178 632 1009 1321 368 421 36 -391 102 110 342 -413 459 314 -10 188 546 496 466 786 605 27 49 -544 -722 59 -65 -219 -168 990 -109 -325 -14 -400 -759 SS 20250614T134740.4Z 9296.574773 373 1 28.84 2 45.14 93.29 103.60 249.82 0.00 1 0.00 1 0 17 1.244e-02 8.162e-03 9.378e-03 4.352e-03 2.080242e-01 2.240671e-03 2.429359e-03 -6.000000e+00 7.241132e-03 232.79 -2.00 3.44 -2.00 316.39 0.00e+00 5.682929e-04 2.595190e-04 1.016153e-04 -6.000000e+00 3.214781e-04 288.67 -2.00 20.00 -2.00 315.59 0.00e+00 1.416 0.000 302.00 328.00 3 6.5348e+00 5.8935e-03 1.7840e-02 -6.0000e+00 1.8177e-02 7.8566e-02 6.5745e-03 1.0655e-02 -6.0000e+00 1.9635e-02 -1.1001e-03 3.7942e-03 5.1458e-03 -6.0000e+00 1.1690e-02 -4.2335e-03 1.7656e-03 1.4230e-03 -6.0000e+00 4.9531e-03 1.4283e-04 -2.6679e-05 1.2478e-04 1.6479e-05 -6.0000e+00 3.3714e-04 1.7410e-02 11 8 0 10 0 0 99.91 24.05 0.34 0.01741 0.01721 8 8 1 5 0 3603.730 26.62 20.00 24.05 33.34 0.6 1021.10 -1349 -469 2754 -1035 1366 -5425 1354 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