File name: Pandora31s1_CharlesCityVA_20250716_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20250717T052718.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora31_OF_v2d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20250716_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20250716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250716T115925.8Z 9328.499604 262 1 29.98 2 68.73 78.89 47.03 230.20 0.00 1 0.00 1 0 25 1.300e-02 4.380e-03 2.784e-03 4.799e-04 3.701594e-01 2.464092e-04 4.276122e-03 -6.000000e+00 7.562490e-03 232.57 -2.00 3.44 -2.00 318.25 0.00e+00 1.854938e-04 4.726960e-05 1.531214e-04 -6.000000e+00 3.400416e-04 291.49 -2.00 20.00 -2.00 317.36 0.00e+00 2.731 0.000 302.00 328.00 3 1.2011e+00 6.7139e-04 3.3505e-02 -6.0000e+00 1.8955e-02 8.7138e-03 7.6403e-04 1.9184e-02 -6.0000e+00 2.0467e-02 -4.7904e-03 4.9319e-04 9.2332e-03 -6.0000e+00 1.2209e-02 -5.0876e-03 2.5504e-04 2.4945e-03 -6.0000e+00 5.1911e-03 6.5751e-03 -2.1470e-04 1.3703e-05 2.7230e-05 -6.0000e+00 3.5231e-04 1.6675e-02 10 0 0 10 0 0 99.95 24.11 0.21 0.01668 0.01506 530 530 1 5 0 56.560 26.62 20.00 24.11 34.86 1.3 1013.16 -3663 -3304 -1641 -4916 -5716 -5789 -4357 -4279 -2707 -1954 -2562 -2591 -1321 -745 174 -832 -453 -229 -426 509 518 274 623 106 27 -114 -405 -929 -490 92 507 777 481 -943 -1869 -2226 -1494 -1037 -423 -654 -686 -663 -724 -708 -321 -628 -511 -690 -678 327 516 621 875 1107 781 878 672 656 389 964 958 1200 1551 1124 417 227 42 159 596 584 535 246 -1 -114 -76 -182 -292 -294 -250 -419 -714 -1038 -1486 -1228 -868 -630 -251 -59 152 52 263 199 492 546 522 443 636 340 -157 -280 -276 -535 -349 -134 -724 -709 -579 -397 -217 173 116 15 99 80 126 374 353 277 154 -185 -176 87 -11 150 442 407 728 787 377 275 176 187 -164 29 -172 -154 -52 103 -232 -159 -185 -238 -195 -192 -175 -88 -280 -296 -296 -239 -267 -171 -130 -173 -187 -110 -73 20 -107 -62 -33 -65 81 84 45 105 19 5 -22 -76 -180 -90 17 95 162 111 -228 -430 -513 -379 -311 -142 -258 -298 -303 -319 -316 -143 -282 -228 -306 -300 148 251 327 492 662 457 528 414 403 234 574 591 800 1068 838 315 161 30 113 429 480 455 219 -1 -97 -63 -136 -212 -207 -189 -341 -625 -1017 -1489 -1292 -927 -719 -287 -69 178 62 288 211 484 528 543 490 751 430 -213 -376 -348 -648 -416 -163 -916 -906 -774 -558 -310 254 182 23 156 119 181 528 495 389 231 -283 -275 133 -16 224 625 576 979 1067 530 420 275 304 -264 49 -295 -278 -92 188 -430 -286 -331 -409 -338 SS 20250716T120950.1Z 9328.506830 265 1 4.35 2 66.70 80.32 48.58 232.93 0.00 1 0.00 1 0 17 1.574e-02 5.301e-03 1.128e-02 2.648e-03 3.429752e-01 1.364829e-03 3.982434e-03 -6.000000e+00 9.160721e-03 232.57 -2.00 3.44 -2.00 317.70 0.00e+00 1.697923e-04 2.232026e-04 1.619601e-04 -6.000000e+00 4.118833e-04 291.49 -2.00 20.00 -2.00 316.81 0.00e+00 2.508 0.000 302.00 328.00 3 2.8866e+00 3.6686e-03 3.0855e-02 -6.0000e+00 2.2960e-02 3.4617e-02 4.1358e-03 1.7729e-02 -6.0000e+00 2.4791e-02 -1.1296e-02 2.5544e-03 8.5380e-03 -6.0000e+00 1.4788e-02 -1.1997e-03 1.2925e-03 2.3105e-03 -6.0000e+00 6.2890e-03 1.5480e-03 -2.1784e-04 7.5470e-05 2.5210e-05 -6.0000e+00 4.2668e-04 1.5562e-02 12 1 1 12 1 1 99.92 24.15 0.30 0.01556 0.01392 11 83 1 5 0 362.410 26.73 20.00 24.15 35.77 1.3 1016.93 -6974 -4702 -8198 -7512 -2233 -1307 -2931 -1620 -4831 -2545 2821 -2588 331 447 -736 -115 483 -1222 350 -501 2379 330 -936 1185 -165 1513 -1350 -577 -1410 1845 291 1369 229 -112 -2384 -2812 -1160 -705 328 -1659 -248 -536 -641 259 -87 -1029 56 -85 -1171 12 61 709 1143 1463 978 1235 843 -15 649 893 728 1844 1852 1138 600 -194 697 -455 269 214 426 270 -237 -89 -717 -211 130 -34 -715 -337 -514 -876 -1617 -1594 -1021 -1062 -165 -125 121 178 91 -127 381 857 421 483 497 124 -7 -196 -294 -400 -593 298 -1004 -522 -552 -584 50 122 101 -192 -80 511 92 338 449 355 256 252 36 303 -270 224 333 317 784 767 265 311 297 70 -119 118 -104 -463 7 -104 -119 -127 -213 -260 -255 -524 -380 -706 -600 -152 -86 -213 -132 -455 -247 260 -267 38 61 -118 -19 83 -225 67 -100 471 66 -198 263 -39 371 -339 -135 -315 404 71 363 67 -34 -695 -818 -368 -244 136 -767 -124 -281 -348 141 -47 -533 30 -45 -628 6 33 416 711 963 632 817 572 -10 429 586 495 1340 1393 926 491 -149 530 -347 207 178 387 256 -225 -81 -606 -168 99 -26 -567 -286 -469 -847 -1691 -1668 -1139 -1212 -196 -154 148 210 104 -133 387 849 447 545 600 160 -9 -256 -377 -492 -686 350 -1239 -679 -752 -801 72 181 154 -301 -123 756 131 453 598 493 365 383 56 461 -402 319 469 427 1043 1025 367 447 453 107 -186 193 -173 -791 13 -187 -214 -222 -373 -436 -416 SS 20250716T122034.1Z 9328.514284 269 1 29.99 2 64.59 81.80 50.24 235.61 0.00 1 0.00 1 0 17 7.759e-03 4.569e-03 1.509e-03 3.915e-04 3.151327e-01 2.013797e-04 3.670602e-03 -6.000000e+00 4.515990e-03 232.57 -2.00 3.44 -2.00 317.58 0.00e+00 1.905933e-04 3.177111e-05 1.093257e-04 -6.000000e+00 2.030460e-04 291.49 -2.00 20.00 -2.00 316.68 0.00e+00 2.316 0.000 302.00 328.00 3 1.2775e+00 5.4010e-04 2.8443e-02 -6.0000e+00 1.1319e-02 7.3724e-03 6.0873e-04 1.6295e-02 -6.0000e+00 1.2221e-02 -2.2572e-03 3.7075e-04 7.8596e-03 -6.0000e+00 7.2901e-03 -4.7508e-03 1.8572e-04 2.1341e-03 -6.0000e+00 3.1004e-03 9.8408e-03 -1.6232e-04 1.1228e-05 2.3434e-05 -6.0000e+00 2.1034e-04 1.5404e-02 10 0 0 10 0 0 100.00 24.18 0.23 0.01540 0.01418 762 762 1 5 0 39.350 26.73 20.00 24.18 36.34 1.3 1018.11 -1798 -1537 -2124 -3326 -2229 -2362 -1766 -337 298 -581 -813 -1219 -605 -478 -133 -568 -443 -179 176 209 432 532 492 326 -147 -26 -369 -705 -232 446 684 1110 740 -691 -1219 -1865 -1334 -790 -167 -699 -670 -776 -730 -624 -385 -546 -759 -562 -636 167 573 819 855 1101 706 892 571 607 575 868 1061 1161 1569 1007 249 53 -37 -6 686 614 403 135 -29 -42 -147 -43 -368 -180 -289 -458 -779 -1083 -1551 -1262 -790 -671 -281 -64 93 -32 191 255 409 487 540 449 630 326 -136 -220 -371 -486 -272 -112 -668 -672 -611 -411 -245 145 125 -14 99 81 141 382 371 301 156 -178 -171 115 11 217 356 504 728 888 426 332 182 181 -171 45 -111 -202 -19 63 -268 -169 -174 -255 -296 -149 -140 -199 -293 -174 -181 -145 -31 30 -63 -88 -139 -79 -73 -21 -102 -84 -35 36 45 94 115 111 79 -38 -7 -98 -177 -55 105 174 308 225 -218 -363 -555 -437 -282 -72 -328 -344 -417 -405 -349 -215 -306 -419 -305 -342 91 332 479 531 722 482 623 384 431 401 600 757 842 1239 809 201 42 -28 -4 540 519 374 124 -26 -39 -126 -35 -275 -129 -220 -395 -721 -1056 -1627 -1317 -879 -762 -335 -79 114 -38 219 268 416 484 571 501 748 412 -184 -293 -467 -588 -324 -131 -850 -863 -821 -554 -349 211 194 -22 152 122 195 517 500 422 225 -263 -258 171 16 314 511 690 946 1155 595 481 280 276 -268 73 -184 -340 -33 111 -478 -294 -304 -428 -483 SS 20250716T123104.8Z 9328.521584 272 1 12.45 2 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