File name: Pandora40s1_CharlesCityVA_20180216_L2Fit_fwvt1c10d20180129p1-8.txt File generation date: 20250118T052420.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v1d20170420.txt Instrument calibration file used: Pandora40s1_CF_v10d20180129.txt Level 1 file used: Pandora40s1_CharlesCityVA_20180216_L1_smca1c10d20180129p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20180216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1830 Nominal wavelengths inside fitting window [nm]: 492.0953 492.2160 492.3368 492.4575 492.5782 492.6989 492.8195 492.9402 493.0608 493.1814 493.3020 493.4226 493.5432 493.6637 493.7842 493.9047 494.0252 494.1457 494.2662 494.3866 494.5070 494.6274 494.7478 494.8682 494.9886 495.1089 495.2292 495.3495 495.4698 495.5901 495.7103 495.8306 495.9508 496.0710 496.1912 496.3113 496.4315 496.5516 496.6717 496.7918 496.9119 497.0319 497.1520 497.2720 497.3920 497.5120 497.6320 497.7519 497.8719 497.9918 498.1117 498.2316 498.3515 498.4713 498.5912 498.7110 498.8308 498.9506 499.0703 499.1901 499.3098 499.4295 499.5492 499.6689 499.7885 499.9082 500.0278 500.1474 500.2670 500.3866 500.5061 500.6257 500.7452 500.8647 500.9842 501.1037 501.2231 501.3425 501.4620 501.5814 501.7007 501.8201 501.9395 502.0588 502.1781 502.2974 502.4167 502.5359 502.6552 502.7744 502.8936 503.0128 503.1319 503.2511 503.3702 503.4894 503.6085 503.7275 503.8466 503.9656 504.0847 504.2037 504.3227 504.4417 504.5606 504.6796 504.7985 504.9174 505.0363 505.1552 505.2740 505.3928 505.5117 505.6305 505.7492 505.8680 505.9868 506.1055 506.2242 506.3429 506.4616 506.5802 506.6989 506.8175 506.9361 507.0547 507.1733 507.2918 507.4104 507.5289 507.6474 507.7659 507.8843 508.0028 508.1212 508.2396 508.3580 508.4764 508.5947 508.7131 508.8314 508.9497 509.0680 509.1863 509.3045 509.4227 509.5410 509.6592 509.7773 509.8955 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180216T120333.0Z 6621.502465 2 1 32.00 2 89.52 105.86 95.64 100.77 0.00 1 0.00 1 0 22 1.774e-02 1.777e-02 1.730e-02 1.719e-02 1.733808e+04 1.249496e+03 1.142738e+03 -6.000000e+00 9.277058e+02 278.38 -2.00 20.00 -2.00 505.42 0.00e+00 1.686141e-03 4.627335e-04 1.052666e-04 -6.000000e+00 4.843989e-04 278.38 -2.00 20.00 -2.00 500.51 0.00e+00 2.185572e+00 3.363133e-01 1.124127e-01 -6.000000e+00 3.454187e-01 225.19 -2.00 3.44 -2.00 502.10 0.00e+00 19.849 0.131 489.00 513.00 1 5.4739e+00 2.5647e-02 3.5493e-02 -6.0000e+00 2.6357e-02 2.9818e-02 6.5283e-03 3.3786e-03 -6.0000e+00 6.9805e-03 3.9132e-04 -3.9982e-04 1.3397e-03 1.1812e-04 -6.0000e+00 1.5576e-03 4.6488e-02 -2.1979e-04 12 8 8 10 0 0 -128.22 19.81 2.77 0.04649 0.04371 8 2 1 4 0 4000.000 26.21 20.00 19.81 -1624 -2349 -776 -2403 370 942 827 -502 -503 -161 -719 -1294 -1477 977 860 -1789 511 2069 -22 -658 -1949 4090 1167 1713 -544 2597 752 -3621 -1664 -1140 -2431 -772 -3515 485 547 4554 2092 1252 -1248 1312 -804 -1199 1726 2630 -1 1176 544 482 -1371 -382 -3289 -71 -1586 -1569 1203 2950 1306 2151 2049 2088 -63 209 -336 2565 -398 3188 568 -396 1146 -2947 -1723 -904 -1018 -1909 -2392 -175 -1149 331 1099 -1046 -4198 2114 22 -1132 2610 -955 -1304 621 -517 -1016 3769 1836 3830 454 3038 -1512 -764 1702 -1393 -1190 -716 -316 -1657 -1323 -1280 858 -152 204 -651 943 -3938 -671 1711 293 1574 2673 542 3244 -193 -722 108 331 2072 -653 2531 750 -427 -1135 38 -383 -2404 -1157 -4174 1676 255 -2658 1277 756 -12 41 -1338 431 701 3723 -2752 -72 1487 -316 1 -3203 -1473 -2198 -743 -2418 371 958 856 -530 -527 -165 -735 -1312 -1474 942 831 -1789 509 2085 -23 -701 -2104 4173 1226 1797 -588 2720 798 -3950 -1722 -1138 -2442 -771 -3684 509 590 4720 2193 1307 -1319 1345 -845 -1278 1808 2770 -2 1266 585 511 -1452 -389 -3345 -69 -1542 -1545 1192 2965 1360 2234 2122 2153 -67 221 -359 2654 -419 3192 573 -398 1121 -2949 -1695 -889 -1012 -1938 -2456 -174 -1128 314 1021 -984 -4082 1955 20 -1094 2474 -943 -1286 596 -498 -980 3498 1759 3634 438 2769 -1384 -668 1408 -1161 -975 -586 -264 -1473 -1244 -1255 836 -149 196 -624 900 -4009 -668 1668 290 1540 2600 548 3254 -200 -741 108 321 1954 -636 2412 730 -423 -1134 37 -378 -2403 -1119 -4114 1563 241 -2640 1255 760 -13 43 -1430 456 746 3862 -3026 -76 1534 -325 1 -3335 SO 20180216T120525.0Z 6621.503762 4 1 32.01 2 89.16 106.14 95.28 101.03 0.00 1 0.00 1 0 29 1.335e-02 1.309e-02 8.421e-03 8.378e-03 1.807641e+04 6.057818e+02 1.284714e+03 -6.000000e+00 6.980891e+02 278.38 -2.00 20.00 -2.00 505.44 0.00e+00 1.802826e-03 2.252940e-04 1.125296e-04 -6.000000e+00 3.645854e-04 278.38 -2.00 20.00 -2.00 500.64 0.00e+00 1.808819e+00 1.626804e-01 9.956094e-02 -6.000000e+00 2.602233e-01 225.19 -2.00 3.44 -2.00 502.21 0.00e+00 19.114 0.117 489.00 513.00 1 4.8335e+00 1.2398e-02 3.3391e-02 -6.0000e+00 1.9851e-02 1.3075e-02 3.1535e-03 3.2620e-03 -6.0000e+00 5.2659e-03 8.4593e-04 2.8915e-03 6.5352e-04 1.3866e-04 -6.0000e+00 1.1721e-03 7.3084e-02 -4.7065e-04 12 8 8 10 0 0 72.80 19.81 3.49 0.07308 0.09314 8 2 1 4 0 4000.000 26.32 20.00 19.81 -1884 -2069 1785 593 -475 1663 758 2028 -672 49 117 -794 -1298 -1084 -1371 -633 -490 -36 1715 -305 172 119 -1124 110 -36 660 792 -224 -695 -3409 -1713 -253 -518 1933 1508 1200 830 -559 1216 -828 -445 2005 1008 1949 1124 164 1133 -876 641 -293 -852 -1005 -2069 -1458 -493 1500 -139 2523 179 -649 1139 543 1324 9 -18 -1059 420 549 -1096 -2361 -1967 409 -3387 1182 404 1287 739 -1790 -1090 -2155 1340 819 -1459 -1083 -408 1610 -1923 266 -921 1650 824 -1101 3207 1691 4856 -235 1089 -1315 -1002 -2317 -724 -1574 -2737 1614 -863 1141 -991 -790 -840 -282 -195 -619 150 110 59 966 2096 1059 1117 1985 -6 615 -1305 320 596 -1203 811 426 19 -166 307 -580 -2157 -243 -3210 196 714 -92 929 -150 1921 185 15 1193 1164 768 -290 -1122 -1931 -1341 -1689 -1904 1647 571 -472 1653 772 2046 -690 49 116 -786 -1269 -1048 -1331 -616 -485 -37 1745 -318 179 124 -1183 116 -38 692 827 -232 -700 -3421 -1686 -248 -522 1980 1587 1262 867 -584 1238 -854 -460 2049 1052 2040 1196 176 1196 -929 659 -296 -838 -972 -2010 -1431 -495 1523 -145 2596 188 -682 1181 570 1386 10 -19 -1098 423 547 -1092 -2348 -1942 398 -3449 1168 404 1262 713 -1740 -1039 -2059 1245 771 -1411 -1054 -400 1563 -1920 258 -896 1567 793 -1095 3085 1625 4373 -214 943 -1128 -840 -1940 -601 -1355 -2500 1500 -853 1121 -989 -775 -818 -277 -195 -624 150 110 59 970 2122 1100 1159 2014 -6 604 -1290 314 588 -1212 806 426 19 -166 303 -566 -2120 -234 -3198 193 719 -95 959 -160 2023 200 17 1286 1251 823 -309 -1180 -2020 -1396 SO 20180216T120718.0Z 6621.505070 6 1 32.01 2 88.80 106.43 94.92 101.30 0.00 1 0.00 1 0 22 8.926e-03 8.784e-03 3.586e-03 3.570e-03 1.951386e+04 2.579945e+02 1.336761e+03 -6.000000e+00 4.669384e+02 278.39 -2.00 20.00 -2.00 505.44 0.00e+00 2.041820e-03 9.623503e-05 1.272999e-04 -6.000000e+00 2.438443e-04 278.39 -2.00 20.00 -2.00 500.73 0.00e+00 1.524906e+00 6.899372e-02 1.164927e-01 -6.000000e+00 1.740029e-01 225.19 -2.00 3.44 -2.00 502.29 0.00e+00 18.241 0.102 489.00 513.00 1 3.9972e+00 5.2562e-03 3.1716e-02 -6.0000e+00 1.3275e-02 -2.2528e-03 1.3379e-03 3.4770e-03 -6.0000e+00 3.5196e-03 2.2456e-03 1.5137e-03 2.7532e-04 1.4941e-04 -6.0000e+00 7.8386e-04 2.5331e-02 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