File name: Pandora40s1_CharlesCityVA_20181019_L2Fit_fwvt1c12d20180910p1-8.txt File generation date: 20250129T150008.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20170420.txt Instrument calibration file used: Pandora40s1_CF_v12d20180910.txt Level 1 file used: Pandora40s1_CharlesCityVA_20181019_L1_smca1c12d20180910p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20181019 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.0114 492.1322 492.2529 492.3736 492.4943 492.6150 492.7357 492.8563 492.9770 493.0976 493.2182 493.3387 493.4593 493.5798 493.7004 493.8209 493.9414 494.0618 494.1823 494.3027 494.4232 494.5436 494.6640 494.7843 494.9047 495.0250 495.1454 495.2657 495.3859 495.5062 495.6265 495.7467 495.8669 495.9871 496.1073 496.2275 496.3476 496.4677 496.5878 496.7079 496.8280 496.9481 497.0681 497.1881 497.3081 497.4281 497.5481 497.6681 497.7880 497.9079 498.0278 498.1477 498.2676 498.3874 498.5073 498.6271 498.7469 498.8667 498.9864 499.1062 499.2259 499.3456 499.4653 499.5850 499.7046 499.8243 499.9439 500.0635 500.1831 500.3027 500.4222 500.5418 500.6613 500.7808 500.9003 501.0197 501.1392 501.2586 501.3780 501.4974 501.6168 501.7362 501.8555 501.9749 502.0942 502.2135 502.3327 502.4520 502.5712 502.6905 502.8097 502.9288 503.0480 503.1672 503.2863 503.4054 503.5245 503.6436 503.7627 503.8817 504.0007 504.1197 504.2387 504.3577 504.4767 504.5956 504.7145 504.8334 504.9523 505.0712 505.1900 505.3089 505.4277 505.5465 505.6653 505.7840 505.9028 506.0215 506.1402 506.2589 506.3776 506.4962 506.6149 506.7335 506.8521 506.9707 507.0893 507.2078 507.3264 507.4449 507.5634 507.6818 507.8003 507.9188 508.0372 508.1556 508.2740 508.3924 508.5107 508.6290 508.7474 508.8657 508.9840 509.1022 509.2205 509.3387 509.4569 509.5751 509.6933 509.8114 509.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181019T112708.0Z 6866.477176 2 1 24.00 2 89.57 103.02 148.28 307.22 0.00 1 0.00 1 0 29 1.071e-01 9.902e-02 9.070e-02 8.765e-02 3.476690e+03 5.423350e+03 2.709920e+01 -6.000000e+00 5.779909e+03 286.43 -2.00 20.00 -2.00 505.15 0.00e+00 1.137343e-03 2.354514e-03 6.663532e-05 -6.000000e+00 2.985648e-03 286.43 -2.00 20.00 -2.00 499.91 0.00e+00 1.550977e+00 1.729788e+00 7.875973e-02 -6.000000e+00 2.081031e+00 226.18 -2.00 3.44 -2.00 501.53 0.00e+00 19.761 0.130 489.00 513.00 1 6.7454e+00 1.3179e-01 3.4412e-02 -6.0000e+00 1.5923e-01 1.4632e-01 3.5061e-02 2.2434e-03 -6.0000e+00 4.2115e-02 1.1827e-04 -7.1686e-03 7.3647e-03 2.1541e-05 -6.0000e+00 9.4103e-03 3.0058e-02 3.3451e-04 12 8 8 10 0 0 12.81 18.98 8.61 0.03006 -0.01967 6 1 1 4 0 4000.000 25.58 19.98 18.98 -13751 8664 4261 1447 -11590 2000 -1192 5551 6846 -11083 4148 2076 2057 593 16634 333 1731 11908 -7304 19257 697 5591 -6955 4966 -1787 3314 12426 -3487 -2507 7885 5261 -4305 2544 3445 -11992 22557 -12 22761 -5573 5918 -12246 -4719 -12234 -9773 5880 10181 670 -581 -11092 17143 -8313 2681 12030 468 -2700 -9108 12748 -15624 8934 1761 8779 -8028 842 -5008 -8828 -12241 -3685 20452 3782 36253 -5876 -13666 15493 -1242 -3780 936 4790 -580 5429 9052 544 16266 598 -5228 -10270 646 8690 -3778 8038 -6624 3485 9820 5236 12617 -518 -2258 -24472 16096 -5176 7736 -5164 -4531 30707 -10487 7031 -13943 -10832 -13577 -4288 -135 189 10656 -1327 10905 4447 23850 -6337 7271 -7064 11894 -5217 -3364 14591 -1799 416 14525 721 909 144 13819 -1759 4758 25428 24790 10977 -8761 16602 -20565 8772 7094 -7778 20626 1198 18978 -14818 1962 -4646 -11678 -97 -2485 900000 -15629 8001 4233 1533 -14302 2205 -1380 6092 7400 -14038 4470 2252 2193 630 15003 353 1828 11652 -8819 18283 791 6056 -8485 5401 -2085 3684 12609 -4089 -2839 7770 5195 -4665 2610 3615 -15160 20713 -14 20313 -6449 6052 -14889 -5356 -15081 -11879 6208 10359 742 -643 -13360 15347 -9196 2586 10439 454 -2759 -10226 11889 -19380 8751 1834 8511 -9186 890 -5584 -10140 -14313 -3895 16870 3613 24939 -5969 -14989 12931 -1231 -3877 915 4435 -553 4814 7685 501 13008 559 -5180 -10782 618 7709 -3759 7119 -6755 3234 8655 4900 11100 -511 -2221 -29201 12652 -4845 6234 -4661 -4096 20325 -10718 6288 -15389 -11493 -14528 -4122 -124 176 9133 -1293 9536 4162 18552 -6627 6710 -7455 10285 -5234 -3255 11715 -1694 387 11808 669 842 133 11232 -1658 4140 17805 17248 8644 -8352 12698 -23027 7505 6237 -7955 16112 1131 15197 -16450 1847 -4593 -12019 -87 -2246 900000 SO 20181019T112836.0Z 6866.478195 4 1 24.01 2 89.29 103.24 148.50 307.72 0.00 1 0.00 1 0 15 8.625e-02 8.297e-02 8.297e-02 8.087e-02 7.236359e+03 5.580420e+03 7.820741e+02 -6.000000e+00 4.653806e+03 286.43 -2.00 20.00 -2.00 505.25 0.00e+00 -1.228979e-03 2.216093e-03 1.630314e-04 -6.000000e+00 2.400306e-03 286.43 -2.00 20.00 -2.00 499.91 0.00e+00 3.170644e-01 1.617568e+00 2.893397e-02 -6.000000e+00 1.661276e+00 226.18 -2.00 3.44 -2.00 501.58 0.00e+00 19.225 0.119 489.00 513.00 1 6.8600e+00 1.2402e-01 3.2689e-02 -6.0000e+00 1.2736e-01 1.5757e-01 3.1936e-02 1.8121e-03 -6.0000e+00 3.3265e-02 1.2867e-04 4.2143e-03 6.7176e-03 9.0459e-05 -6.0000e+00 7.5531e-03 4.9658e-02 -5.3535e-05 12 8 8 10 0 0 23.27 18.98 3.77 0.04966 0.07889 6 1 1 4 0 4000.000 25.68 20.00 18.98 -12848 7931 -2320 -3073 -9933 8963 5989 -417 11764 -8861 2952 3567 -7553 593 11491 8092 6108 -8300 -8453 -1238 9272 -4069 5770 9079 12358 2044 -1611 16975 5245 -1972 -9624 14362 -5437 -2964 5772 -14102 640 -7531 2272 -5777 3233 -1732 6166 11810 -13400 2123 -9308 4044 -685 -848 -6708 -6969 1753 -3227 3304 22404 6001 -5387 -2735 9648 5207 -6102 11110 8569 -5039 17432 -706 -8940 6705 5297 1955 11296 3237 -1709 -5431 -4213 -7583 2303 -3766 2149 334 -4343 -5103 -5264 13594 -4987 14350 -17061 5661 3756 287 14901 20451 -6811 -1868 7614 3051 16607 -4240 16585 2153 -3805 -3849 3057 -5554 -3807 -4635 14748 -4020 1076 6849 3204 -1226 -5795 2281 -6371 1292 -7213 17806 5555 24122 8203 -17482 15614 -19455 -3661 -11541 3130 -7378 -2466 -7155 -2502 10320 -6185 6681 419 -6278 14204 -126 8561 7800 8510 182 -11311 -869 13143 -3741 5660 1679 -7912 8560 -14440 7407 -2479 -3418 -12079 9249 6469 -483 12045 -10892 3202 3792 -8765 627 10905 7981 6226 -9982 -10430 -1438 9744 -4859 6255 9543 12628 2298 -1866 16246 5433 -2113 -10963 13053 -6078 -3361 6199 -18405 715 -8966 2430 -6595 3380 -1910 6351 11621 -16933 2308 -11201 4217 -733 -883 -7139 -7243 1655 -3222 3184 18547 5935 -5986 -2951 9184 5164 -6780 10498 8278 -5494 15066 -713 -9643 6142 4833 1827 9709 3038 -1701 -5654 -4306 -7839 2122 -3626 1943 309 -4238 -5046 -5248 11475 -5088 12165 -19471 5176 3502 278 12671 16714 -7209 -1843 6685 2723 12617 -3827 12040 1792 -3416 -3589 2797 -5722 -3881 -4720 12234 -3929 1003 6131 3004 -1207 -5987 2180 -6627 1261 -7687 14846 5122 18269 7082 -19072 12445 -21845 -3528 -11974 2814 -7299 -2325 -7014 -2294 8230 -5733 5439 366 -6014 11389 -117 7426 6871 7467 174 -12119 -842 11059 -3636 4892 1474 -7556 7037 SO 20181019T113005.0Z 6866.479225 6 1 24.00 2 89.00 103.47 148.72 308.22 0.00 1 0.00 1 0 15 1.171e-01 7.984e-02 7.402e-02 7.137e-02 -1.917187e+03 4.083211e+03 2.696767e+02 -6.000000e+00 6.320348e+03 286.43 -2.00 20.00 -2.00 505.18 0.00e+00 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