File name: Pandora40s1_CharlesCityVA_20181203_L2Fit_fwvt1c12d20180910p1-8.txt File generation date: 20250129T154100.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20170420.txt Instrument calibration file used: Pandora40s1_CF_v12d20180910.txt Level 1 file used: Pandora40s1_CharlesCityVA_20181203_L1_smca1c12d20180910p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20181203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.0114 492.1322 492.2529 492.3736 492.4943 492.6150 492.7357 492.8563 492.9770 493.0976 493.2182 493.3387 493.4593 493.5798 493.7004 493.8209 493.9414 494.0618 494.1823 494.3027 494.4232 494.5436 494.6640 494.7843 494.9047 495.0250 495.1454 495.2657 495.3859 495.5062 495.6265 495.7467 495.8669 495.9871 496.1073 496.2275 496.3476 496.4677 496.5878 496.7079 496.8280 496.9481 497.0681 497.1881 497.3081 497.4281 497.5481 497.6681 497.7880 497.9079 498.0278 498.1477 498.2676 498.3874 498.5073 498.6271 498.7469 498.8667 498.9864 499.1062 499.2259 499.3456 499.4653 499.5850 499.7046 499.8243 499.9439 500.0635 500.1831 500.3027 500.4222 500.5418 500.6613 500.7808 500.9003 501.0197 501.1392 501.2586 501.3780 501.4974 501.6168 501.7362 501.8555 501.9749 502.0942 502.2135 502.3327 502.4520 502.5712 502.6905 502.8097 502.9288 503.0480 503.1672 503.2863 503.4054 503.5245 503.6436 503.7627 503.8817 504.0007 504.1197 504.2387 504.3577 504.4767 504.5956 504.7145 504.8334 504.9523 505.0712 505.1900 505.3089 505.4277 505.5465 505.6653 505.7840 505.9028 506.0215 506.1402 506.2589 506.3776 506.4962 506.6149 506.7335 506.8521 506.9707 507.0893 507.2078 507.3264 507.4449 507.5634 507.6818 507.8003 507.9188 508.0372 508.1556 508.2740 508.3924 508.5107 508.6290 508.7474 508.8657 508.9840 509.1022 509.2205 509.3387 509.4569 509.5751 509.6933 509.8114 509.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181203T121311.0Z 6911.509155 2 1 32.01 2 89.60 118.62 50.24 143.05 0.00 1 0.00 1 0 29 1.166e-02 1.149e-02 1.999e-03 1.989e-03 1.399500e+04 1.331073e+02 9.412054e+02 -6.000000e+00 6.168670e+02 281.46 -2.00 20.00 -2.00 505.46 0.00e+00 3.416316e-03 5.403645e-05 1.821283e-04 -6.000000e+00 3.208681e-04 281.46 -2.00 20.00 -2.00 501.10 0.00e+00 1.219745e+00 3.741620e-02 9.803380e-02 -6.000000e+00 2.260262e-01 223.68 -2.00 3.44 -2.00 502.59 0.00e+00 19.945 0.133 489.00 513.00 1 2.8443e+00 2.8559e-03 3.5684e-02 -6.0000e+00 1.7273e-02 -2.9378e-02 7.2502e-04 3.0247e-03 -6.0000e+00 4.5642e-03 5.6555e-03 4.7928e-03 1.6152e-04 1.2861e-04 -6.0000e+00 1.0239e-03 -5.8335e-03 -4.3799e-05 12 8 8 10 0 0 -303.58 19.55 5.74 -0.00583 0.02741 8 2 1 4 0 4000.000 26.11 19.99 19.55 900000 -3003 -2267 -1243 418 218 938 850 1139 871 78 -315 -923 -1989 -1615 -1326 -538 -448 437 732 733 336 1003 923 1070 1277 1101 625 -506 -1135 -1942 -1449 -1015 -386 980 1410 1069 636 -220 -274 54 938 756 1299 1825 2023 1594 1090 574 -209 -1207 -2077 -2739 -1745 -1621 -431 692 1033 1101 1003 817 1209 1366 1093 1111 740 107 302 49 -797 -943 -1222 -905 -383 -436 178 -1174 -899 -1710 -1874 -1793 -1055 -990 -723 -1071 -440 -384 -397 -941 -434 27 257 972 1345 2571 652 1365 -69 -948 -2080 -2166 -2197 -1366 -465 -41 231 584 -480 -1496 -946 -136 209 771 1091 1851 1623 1922 2778 1736 1327 435 119 -369 340 831 692 774 295 549 246 344 -213 -732 -964 -1452 -1304 -561 -119 499 167 521 1030 214 577 853 475 213 -694 -1863 -1903 -2035 900000 -2661 -1971 -1118 382 204 893 822 1102 836 74 -299 -868 -1861 -1498 -1234 -504 -429 410 697 702 324 963 891 1042 1250 1081 614 -492 -1071 -1807 -1347 -954 -373 977 1427 1079 638 -221 -272 54 934 735 1276 1813 2024 1602 1093 571 -205 -1163 -1965 -2683 -1699 -1550 -423 694 1050 1123 1023 835 1241 1413 1139 1153 762 109 303 48 -791 -927 -1207 -902 -384 -445 181 -1193 -893 -1688 -1836 -1754 -1034 -980 -718 -1039 -431 -378 -389 -920 -421 27 252 965 1342 2492 624 1308 -65 -875 -1904 -1968 -2020 -1290 -441 -40 236 598 -492 -1530 -962 -141 219 781 1110 1881 1659 1984 2903 1854 1413 459 124 -377 345 851 716 805 311 576 259 363 -223 -755 -992 -1500 -1355 -595 -129 527 179 568 1128 238 644 954 532 237 -763 -2029 -2055 -2217 SO 20181203T121454.9Z 6911.510358 4 1 23.83 2 89.30 118.89 50.05 143.54 0.00 1 0.00 1 0 22 1.096e-02 1.077e-02 1.193e-03 1.187e-03 1.511140e+04 8.046054e+01 9.939710e+02 -6.000000e+00 5.797476e+02 281.46 -2.00 20.00 -2.00 505.46 0.00e+00 3.450979e-03 3.231001e-05 1.922720e-04 -6.000000e+00 3.012751e-04 281.46 -2.00 20.00 -2.00 501.06 0.00e+00 1.048942e+00 2.240940e-02 1.086061e-01 -6.000000e+00 2.114311e-01 223.68 -2.00 3.44 -2.00 502.56 0.00e+00 19.372 0.122 489.00 513.00 1 1.8389e+00 1.7126e-03 3.4416e-02 -6.0000e+00 1.6176e-02 -3.5335e-02 4.3208e-04 3.1452e-03 -6.0000e+00 4.2397e-03 1.6923e-02 6.1137e-04 9.5378e-05 1.3534e-04 -6.0000e+00 9.5911e-04 2.5000e-02 -5.6788e-05 12 9 9 12 1 1 38.34 19.55 5.47 0.02500 0.02924 13 4 1 4 0 1701.620 26.21 20.00 19.55 -3120 -2719 -1533 -755 204 832 1454 1353 1088 939 242 -139 -888 -1148 -1359 -1479 -865 -491 437 620 696 626 912 907 990 1351 1185 786 -190 -1019 -2125 -1499 -725 -404 846 1283 896 625 200 -250 -107 360 377 883 1337 1460 1480 1155 641 115 -1053 -1956 -2154 -1672 -1311 -156 326 1073 1162 853 991 916 1215 1336 1042 713 249 10 -287 -979 -1423 -963 -345 -628 -378 -476 -737 -1159 -1380 -1852 -1435 -1316 -352 -908 -773 209 -492 -229 -837 -506 -34 242 1147 1506 1583 953 999 214 -918 -2136 -2609 -1884 -1182 -483 315 72 -100 -236 -944 -869 -321 176 357 960 1452 1487 1987 2045 1539 994 618 289 29 523 562 746 582 603 596 683 189 209 -794 -956 -1268 -1444 -843 55 484 302 530 578 330 642 868 667 160 -822 -1626 -2138 -2010 -2752 -2418 -1343 -687 189 788 1399 1276 1031 882 225 -129 -817 -1082 -1277 -1400 -796 -460 419 605 682 616 897 896 955 1307 1150 763 -182 -984 -2030 -1429 -696 -387 836 1286 896 621 198 -246 -106 357 380 900 1333 1468 1488 1156 637 113 -1048 -1911 -2080 -1612 -1294 -153 328 1090 1186 872 1012 943 1260 1390 1083 735 254 11 -288 -975 -1407 -951 -342 -634 -387 -473 -747 -1156 -1361 -1818 -1401 -1296 -347 -905 -755 206 -490 -226 -826 -496 -34 240 1148 1513 1562 916 958 200 -845 -1950 -2373 -1722 -1112 -461 316 72 -101 -236 -941 -867 -324 181 370 997 1507 1549 2086 2126 1628 1051 644 306 30 540 587 785 599 624 617 707 197 215 -809 -971 -1292 -1486 -886 59 523 324 575 634 366 714 967 743 178 -903 -1763 -2310 -2185 SO 20181203T121640.4Z 6911.511578 6 1 32.76 2 88.99 119.16 49.85 144.04 0.00 1 0.00 1 0 29 9.820e-03 9.643e-03 6.211e-04 6.184e-04 1.487873e+04 4.154786e+01 9.868102e+02 -6.000000e+00 5.195469e+02 281.46 -2.00 20.00 -2.00 505.44 0.00e+00 3.313041e-03 1.684304e-05 1.843027e-04 -6.000000e+00 2.700735e-04 281.46 -2.00 20.00 -2.00 501.03 0.00e+00 1.037525e+00 1.162554e-02 1.043315e-01 -6.000000e+00 1.895998e-01 223.68 -2.00 3.44 -2.00 502.54 0.00e+00 18.683 0.110 489.00 513.00 1 1.0404e+00 8.8667e-04 3.2600e-02 -6.0000e+00 1.4505e-02 -3.6348e-02 2.2550e-04 3.0215e-03 -6.0000e+00 3.8039e-03 4.1615e-02 1.5691e-03 4.9605e-05 1.3357e-04 -6.0000e+00 8.5984e-04 1.1195e-02 -1.1207e-05 12 8 8 10 0 0 37.95 19.55 4.83 0.01120 0.02208 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