File name: Pandora40s1_CharlesCityVA_20190402_L2Fit_fwvt1c12d20180910p1-8.txt File generation date: 20250129T160456.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20170420.txt Instrument calibration file used: Pandora40s1_CF_v12d20180910.txt Level 1 file used: Pandora40s1_CharlesCityVA_20190402_L1_smca1c12d20180910p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20190402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.0114 492.1322 492.2529 492.3736 492.4943 492.6150 492.7357 492.8563 492.9770 493.0976 493.2182 493.3387 493.4593 493.5798 493.7004 493.8209 493.9414 494.0618 494.1823 494.3027 494.4232 494.5436 494.6640 494.7843 494.9047 495.0250 495.1454 495.2657 495.3859 495.5062 495.6265 495.7467 495.8669 495.9871 496.1073 496.2275 496.3476 496.4677 496.5878 496.7079 496.8280 496.9481 497.0681 497.1881 497.3081 497.4281 497.5481 497.6681 497.7880 497.9079 498.0278 498.1477 498.2676 498.3874 498.5073 498.6271 498.7469 498.8667 498.9864 499.1062 499.2259 499.3456 499.4653 499.5850 499.7046 499.8243 499.9439 500.0635 500.1831 500.3027 500.4222 500.5418 500.6613 500.7808 500.9003 501.0197 501.1392 501.2586 501.3780 501.4974 501.6168 501.7362 501.8555 501.9749 502.0942 502.2135 502.3327 502.4520 502.5712 502.6905 502.8097 502.9288 503.0480 503.1672 503.2863 503.4054 503.5245 503.6436 503.7627 503.8817 504.0007 504.1197 504.2387 504.3577 504.4767 504.5956 504.7145 504.8334 504.9523 505.0712 505.1900 505.3089 505.4277 505.5465 505.6653 505.7840 505.9028 506.0215 506.1402 506.2589 506.3776 506.4962 506.6149 506.7335 506.8521 506.9707 507.0893 507.2078 507.3264 507.4449 507.5634 507.6818 507.8003 507.9188 508.0372 508.1556 508.2740 508.3924 508.5107 508.6290 508.7474 508.8657 508.9840 509.1022 509.2205 509.3387 509.4569 509.5751 509.6933 509.8114 509.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190402T110137.0Z 7031.459456 3 1 32.00 2 89.19 84.45 78.07 115.05 0.00 1 0.00 1 0 26 1.237e-01 1.148e-01 1.202e-01 1.166e-01 2.477940e+03 6.827454e+03 2.882802e+02 -6.000000e+00 6.555078e+03 281.53 -2.00 20.00 -2.00 505.32 0.00e+00 4.247817e-04 3.179626e-03 2.225488e-04 -6.000000e+00 3.400783e-03 281.53 -2.00 20.00 -2.00 500.35 0.00e+00 1.748497e+00 2.263273e+00 2.940438e-02 -6.000000e+00 2.393903e+00 227.98 -2.00 3.44 -2.00 501.97 0.00e+00 19.117 0.117 489.00 513.00 1 7.4444e+00 1.7355e-01 3.2607e-02 -6.0000e+00 1.8310e-01 9.4250e-02 4.4775e-02 1.7802e-03 -6.0000e+00 4.7978e-02 6.3837e-05 -6.7821e-03 9.9869e-03 6.9459e-05 -6.0000e+00 1.0821e-02 -8.0398e-02 1.6392e-03 12 8 8 10 0 0 -334.09 18.76 7.23 -0.08040 -0.12744 8 2 1 4 0 4000.000 25.58 20.20 18.76 -27178 20699 -16717 -8765 -9807 -8330 10227 -11050 1332 2954 10422 -736 -6325 5728 -4364 45630 -5462 3696 -4443 -3545 2214 1978 12072 10613 4350 -2802 2575 9559 28224 5901 5626 13949 2101 13793 -6477 5626 2332 7366 -9844 -2829 -17097 -9847 13073 -6315 7816 -11016 4312 -3088 6932 11325 1666 3419 4777 -2901 -7709 7296 24999 -24138 3139 -4860 9940 37387 4011 21531 -338 23357 -1308 7078 -5618 1597 17161 -11127 8763 -1911 -3264 -20618 -3605 490 9358 -3528 5011 27005 -9147 13800 10943 19944 1015 1879 476 895 18975 5499 5440 3851 -10986 10235 1368 4068 -5639 -9689 2072 -2212 3017 -12628 41820 -8915 8727 -18326 13845 10827 -17682 10186 -3073 13634 209 9503 9075 -15861 5793 -14270 -1442 3618 -2707 -4363 14493 14939 -12340 16955 4109 17407 -12888 4339 -8196 4872 -886 20899 13795 -2649 -747 -1804 -8164 10449 2359 4773 -9902 -5237 -18133 9711 13989 -18837 900000 -33471 16599 -19815 -9953 -11469 -9788 10238 -13605 1444 3104 10094 -781 -6944 5543 -4652 30684 -6037 3853 -5109 -4060 2405 2152 11934 10672 4658 -3203 2784 9497 22672 5687 5410 12511 2161 13200 -7682 5926 2498 7420 -11526 -3080 -21399 -11593 12517 -7340 7995 -13435 4501 -3404 6811 10349 1616 3197 4388 -2913 -8354 7061 20793 -32073 3205 -5319 9487 27729 4076 18452 -351 19109 -1330 6559 -5789 1512 14009 -11953 7878 -1923 -3343 -24526 -3570 461 7999 -3401 4492 19874 -9489 11635 9596 16156 980 1795 461 867 15608 5223 5228 3740 -12065 9036 1283 3613 -5343 -9423 1810 -2056 2771 -13975 28147 -9597 7828 -20825 11556 9399 -20446 9173 -3173 12116 211 8854 8545 -18843 5539 -16226 -1429 3370 -2675 -4422 12332 12660 -13520 14054 3841 14371 -13952 3913 -8220 4287 -823 16134 11684 -2661 -746 -1838 -8857 9548 2343 4653 -11084 -5540 -21162 8466 11547 -21255 900000 SO 20190402T110235.0Z 7031.460127 4 1 32.00 2 88.99 84.59 77.90 115.21 0.00 1 0.00 1 0 15 1.288e-01 1.189e-01 1.142e-01 1.097e-01 1.609821e+04 8.317333e+03 1.089517e+03 -6.000000e+00 6.828581e+03 281.53 -2.00 20.00 -2.00 505.33 0.00e+00 2.700391e-03 2.965002e-03 1.829411e-04 -6.000000e+00 3.543164e-03 281.53 -2.00 20.00 -2.00 500.20 0.00e+00 2.268582e+00 2.212462e+00 1.082597e-01 -6.000000e+00 2.500161e+00 227.98 -2.00 3.44 -2.00 501.80 0.00e+00 18.674 0.109 489.00 513.00 1 7.3496e+00 1.6898e-01 3.2657e-02 -6.0000e+00 1.9114e-01 6.6732e-02 4.3178e-02 3.1181e-03 -6.0000e+00 5.0242e-02 6.7776e-05 -2.5637e-03 8.7821e-03 1.2483e-04 -6.0000e+00 1.1286e-02 1.4548e-03 9.6409e-04 12 9 8 11 8 0 -62.44 18.75 0.98 0.00145 -0.01633 8 2 1 4 0 4000.000 25.58 19.60 18.75 26840 2306 -1973 8631 -928 32160 5199 18378 -20380 -8650 4519 4914 10528 2205 -8990 -3114 -2175 14302 -8839 16586 545 -6322 -3228 -4282 18569 6706 4452 -6174 16883 -5954 33748 7930 -5627 -16393 -5088 1872 2521 6417 -20137 -6610 6372 -6974 6449 2572 6671 2242 334 1202 -5711 11955 -6066 8608 -6946 10083 5672 -346 -11534 -1376 7606 12056 3640 3121 3775 -19177 4625 911 -15773 12990 -2849 15057 -10957 8226 -8847 15872 -20302 11105 7821 306 -10221 23721 -15234 -2466 -12077 22176 -4208 18034 -4885 13603 -1367 -10351 12158 1591 -7515 -12304 14416 -7444 6372 23348 28366 6533 -31150 30941 3574 -10725 -2127 -527 7953 1990 2548 -13390 11834 13863 -13732 -699 12424 11922 13159 36354 1190 4579 -11073 19282 -590 -12109 4929 -12840 -3978 -3360 13863 17894 -3868 8494 -4312 8729 -22416 12675 15453 14322 -9916 1391 16707 -11380 1212 15981 -7125 3110 -16949 23900 -390 32893 900000 19980 2219 -2054 8385 -1006 26034 5500 17204 -27213 -10175 4633 4944 9866 2215 -10052 -3324 -2343 13543 -10616 15717 602 -7434 -3694 -4973 17482 7049 4753 -7144 15147 -6448 25086 7590 -6288 -21113 -6007 2053 2712 6572 -26245 -7550 6479 -8128 6694 2805 7038 2466 370 1301 -6456 11090 -6473 7847 -7319 9219 5587 -370 -13934 -1515 7652 11580 3798 3293 3964 -24878 4723 946 -18885 11695 -2932 12893 -11956 7554 -9626 13840 -24960 9975 7081 292 -10642 17839 -16619 -2402 -12908 17352 -4275 14901 -4974 11513 -1321 -10898 10440 1532 -7905 -13286 11682 -7138 5176 15716 17850 4982 -34157 19531 3063 -11062 -2084 -512 7053 1835 2330 -14456 10235 11828 -15256 -688 10804 10515 11686 26224 1187 4341 -11886 15223 -559 -12903 4499 -13911 -3976 -3335 11671 14507 -3788 7253 -4131 7387 -25592 10639 12929 12274 -10809 1384 14505 -12960 1231 14140 -7805 3059 -19736 18527 -376 23301 900000 SO 20190402T110332.0Z 7031.460787 5 1 32.00 2 88.81 84.74 77.73 115.37 0.00 1 0.00 1 0 8 1.253e-01 1.163e-01 1.025e-01 9.928e-02 3.297462e+03 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