File name: Pandora40s1_CharlesCityVA_20190408_L2Fit_fwvt1c12d20180910p1-8.txt File generation date: 20250129T161516.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20170420.txt Instrument calibration file used: Pandora40s1_CF_v12d20180910.txt Level 1 file used: Pandora40s1_CharlesCityVA_20190408_L1_smca1c12d20180910p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20190408 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.0114 492.1322 492.2529 492.3736 492.4943 492.6150 492.7357 492.8563 492.9770 493.0976 493.2182 493.3387 493.4593 493.5798 493.7004 493.8209 493.9414 494.0618 494.1823 494.3027 494.4232 494.5436 494.6640 494.7843 494.9047 495.0250 495.1454 495.2657 495.3859 495.5062 495.6265 495.7467 495.8669 495.9871 496.1073 496.2275 496.3476 496.4677 496.5878 496.7079 496.8280 496.9481 497.0681 497.1881 497.3081 497.4281 497.5481 497.6681 497.7880 497.9079 498.0278 498.1477 498.2676 498.3874 498.5073 498.6271 498.7469 498.8667 498.9864 499.1062 499.2259 499.3456 499.4653 499.5850 499.7046 499.8243 499.9439 500.0635 500.1831 500.3027 500.4222 500.5418 500.6613 500.7808 500.9003 501.0197 501.1392 501.2586 501.3780 501.4974 501.6168 501.7362 501.8555 501.9749 502.0942 502.2135 502.3327 502.4520 502.5712 502.6905 502.8097 502.9288 503.0480 503.1672 503.2863 503.4054 503.5245 503.6436 503.7627 503.8817 504.0007 504.1197 504.2387 504.3577 504.4767 504.5956 504.7145 504.8334 504.9523 505.0712 505.1900 505.3089 505.4277 505.5465 505.6653 505.7840 505.9028 506.0215 506.1402 506.2589 506.3776 506.4962 506.6149 506.7335 506.8521 506.9707 507.0893 507.2078 507.3264 507.4449 507.5634 507.6818 507.8003 507.9188 508.0372 508.1556 508.2740 508.3924 508.5107 508.6290 508.7474 508.8657 508.9840 509.1022 509.2205 509.3387 509.4569 509.5751 509.6933 509.8114 509.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190408T105108.0Z 7037.452176 2 1 32.00 2 89.53 81.32 111.44 51.12 0.00 1 0.00 1 0 36 1.519e-01 1.400e-01 1.110e-01 1.063e-01 9.327031e+03 7.034769e+03 8.435726e+02 -6.000000e+00 8.062748e+03 282.10 -2.00 20.00 -2.00 505.27 0.00e+00 7.213346e-04 2.871381e-03 1.282139e-04 -6.000000e+00 4.180964e-03 282.10 -2.00 20.00 -2.00 500.26 0.00e+00 -7.039815e-01 2.062488e+00 3.013509e-02 -6.000000e+00 2.948011e+00 228.46 -2.00 3.44 -2.00 501.88 0.00e+00 19.797 0.130 489.00 513.00 1 7.3993e+00 1.5804e-01 3.4288e-02 -6.0000e+00 2.2546e-01 1.3556e-01 4.0391e-02 2.1663e-03 -6.0000e+00 5.9165e-02 7.0636e-05 1.9157e-02 8.8256e-03 1.0915e-04 -6.0000e+00 1.3297e-02 3.2762e-02 -1.2678e-04 12 8 8 10 0 0 76.79 19.78 18.44 0.03276 0.16564 8 2 1 4 0 4000.000 26.32 20.00 19.78 8401 -17314 12710 5595 6337 17879 -18759 5463 -287 28141 201 9376 10677 -1408 12382 -22460 25901 -7266 17631 -8004 -3747 9353 -4266 -815 -3268 14911 -12624 8492 965 -17539 36183 -2122 20532 -3338 12066 16779 -10247 5259 -13045 -2636 -9080 16487 3190 4131 -16916 4867 -3082 -18634 23586 -6046 -3294 -1831 -5167 29945 10485 8715 -8052 15634 -1825 2826 -562 2543 14278 -6576 9116 -4827 24259 7485 -9183 105 -15103 37625 -18335 25981 -7766 5460 -10623 -11392 34603 -28282 13068 -5456 34077 22973 14820 -2057 -3408 20243 8500 8721 -3099 441 2470 -10786 25785 -12314 35439 -8261 -13868 -6205 6724 3866 -7649 8647 -333 21264 -256 -827 32920 -35032 20190 -12983 -3170 19231 932 93 -13654 20935 -11094 25889 -5238 25170 15458 8174 16068 -14710 13620 -10314 14828 -17952 21885 10892 -4355 15272 -5260 5478 -18017 9651 3295 9735 17426 -4757 37312 -10205 20955 -4757 3026 -9067 2182 5301 -14552 7460 -20210 11593 5606 6422 16529 -24872 5749 -314 23184 214 8969 9906 -1454 11251 -28776 21366 -8439 16416 -9523 -4284 9423 -4894 -909 -3741 14301 -15606 8386 985 -20876 25862 -2212 17782 -3769 11929 15714 -12243 5349 -15640 -2851 -10516 15090 3353 4346 -21863 5086 -3438 -23711 19636 -6462 -3331 -1797 -5237 22242 9686 8409 -9242 14322 -1968 2903 -600 2648 13323 -7431 8755 -5209 19564 6999 -9904 102 -17045 26001 -21810 20540 -8467 5162 -11463 -12211 23742 -35234 11079 -5572 24005 18203 12866 -2106 -3517 16589 7777 7996 -3211 449 2479 -12070 19848 -13247 23501 -8059 -13959 -5754 5581 3397 -7862 7950 -341 17614 -257 -820 23610 -48633 16825 -14940 -3343 16426 949 96 -16266 17983 -12765 20545 -5475 19352 13003 7425 13586 -16680 11779 -11150 12594 -20786 17049 9221 -4226 12210 -5128 4935 -20784 8655 3177 8933 14914 -5051 26679 -11481 17441 -4990 2877 -9428 2014 4765 -16023 SO 20190408T105300.0Z 7037.453472 4 1 31.99 2 89.16 81.60 111.16 51.47 0.00 1 0.00 1 0 29 8.589e-02 8.339e-02 8.631e-02 8.471e-02 6.824723e+03 5.608893e+03 1.029458e+03 -6.000000e+00 4.560940e+03 282.10 -2.00 20.00 -2.00 505.34 0.00e+00 6.932724e-04 2.261718e-03 9.323014e-05 -6.000000e+00 2.363889e-03 282.10 -2.00 20.00 -2.00 500.29 0.00e+00 1.862355e+00 1.650817e+00 1.356249e-01 -6.000000e+00 1.660492e+00 228.46 -2.00 3.44 -2.00 501.91 0.00e+00 19.053 0.116 489.00 513.00 1 7.0960e+00 1.2618e-01 3.3438e-02 -6.0000e+00 1.2709e-01 7.9082e-02 3.1995e-02 2.1667e-03 -6.0000e+00 3.3177e-02 9.0010e-05 1.8678e-02 6.9988e-03 7.2224e-05 -6.0000e+00 7.5147e-03 -6.0835e-02 7.5737e-04 12 8 8 10 0 0 64.46 19.79 9.52 -0.06084 0.06872 8 2 1 4 0 4000.000 26.41 20.00 19.79 -4857 17036 2336 -11835 -5977 -3109 8834 379 15321 3733 -1472 -1477 -79 6359 -1085 20549 3546 8889 -8422 -9292 10527 -5656 5478 1608 15353 -13640 905 1390 -171 -11056 2607 1665 -3332 -2405 4032 611 -7330 2642 4618 5697 4522 -3875 8782 -4307 8835 1719 -64 4897 -12066 4175 -11093 -17963 26947 -4079 9709 -2460 -2053 16070 3387 2294 2420 8383 -7268 -2518 -5682 -13350 -7514 5933 766 -2999 1292 -3198 -6694 -4979 6953 10615 4971 -4545 -7848 14634 -1371 -3291 5579 329 -4076 12497 2714 19523 -3831 6407 1462 -907 5564 -196 16580 -2987 3414 14240 10803 -2623 -5631 -7252 -12693 -14179 -1445 7026 -13850 -4303 5916 10551 -4947 10764 9446 586 -434 357 2197 -1660 16540 7093 5828 -24147 -10526 3720 5265 8904 9659 -4421 -5906 -7406 1625 3154 2536 684 6866 7231 3492 -13190 9503 -730 3146 19804 -4708 -669 8628 -3866 -1278 -14122 16613 10228 -3832 -4832 14240 2332 -13850 -6737 -3476 8888 412 14262 3820 -1567 -1544 -80 6049 -1115 17435 3622 8858 -10017 -11155 10464 -6550 5722 1752 14676 -17130 979 1454 -175 -12368 2571 1686 -3665 -2713 4303 666 -8506 2750 4674 5699 4610 -4327 8776 -4921 8919 1846 -69 4944 -13946 4001 -11971 -20424 20127 -4203 9061 -2637 -2212 14535 3439 2350 2490 8180 -8226 -2694 -6170 -15336 -8059 5518 737 -2958 1230 -3205 -7019 -5181 6430 9286 4495 -4443 -7853 11859 -1308 -3211 5029 316 -4127 10806 2561 15649 -3841 5847 1415 -912 5261 -192 13521 -2861 2983 10936 8396 -2309 -5185 -7010 -13559 -15880 -1446 6421 -15183 -4247 5322 9228 -5088 9618 8610 582 -437 361 2197 -1714 14169 6526 5326 -29045 -11186 3475 4854 7947 8545 -4457 -6050 -7656 1510 2843 2284 624 5977 6453 3295 -14769 8686 -743 3095 16724 -5051 -692 8112 -4028 -1265 -15464 13503 8917 -3890 SO 20190408T105452.0Z 7037.454769 6 1 32.01 2 88.79 81.88 110.88 51.82 0.00 1 0.00 1 0 15 8.916e-02 8.346e-02 6.760e-02 6.625e-02 4.831279e+03 4.214617e+03 1.952619e+02 -6.000000e+00 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