File name: Pandora40s1_CharlesCityVA_20190912_L2Fit_fout2c12d20180910p1-8.txt File generation date: 20250129T175939.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20170420.txt Instrument calibration file used: Pandora40s1_CF_v12d20180910.txt Level 1 file used: Pandora40s1_CharlesCityVA_20190912_L1_smca1c12d20180910p1-8.txt Full location name: VCU Rice Rivers Center Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20190912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1210 305.2619 305.4027 305.5435 305.6843 305.8250 305.9658 306.1066 306.2473 306.3881 306.5288 306.6695 306.8102 306.9509 307.0916 307.2322 307.3729 307.5135 307.6542 307.7948 307.9354 308.0760 308.2166 308.3572 308.4977 308.6383 308.7788 308.9194 309.0599 309.2004 309.3409 309.4814 309.6219 309.7623 309.9028 310.0432 310.1837 310.3241 310.4645 310.6049 310.7453 310.8857 311.0260 311.1664 311.3067 311.4471 311.5874 311.7277 311.8680 312.0083 312.1486 312.2888 312.4291 312.5693 312.7096 312.8498 312.9900 313.1302 313.2704 313.4106 313.5507 313.6909 313.8310 313.9711 314.1113 314.2514 314.3915 314.5315 314.6716 314.8117 314.9517 315.0918 315.2318 315.3718 315.5118 315.6518 315.7918 315.9318 316.0717 316.2117 316.3516 316.4915 316.6315 316.7714 316.9113 317.0511 317.1910 317.3309 317.4707 317.6105 317.7504 317.8902 318.0300 318.1698 318.3096 318.4493 318.5891 318.7288 318.8685 319.0083 319.1480 319.2877 319.4274 319.5670 319.7067 319.8464 319.9860 320.1256 320.2652 320.4048 320.5444 320.6840 320.8236 320.9632 321.1027 321.2422 321.3818 321.5213 321.6608 321.8003 321.9397 322.0792 322.2187 322.3581 322.4975 322.6370 322.7764 322.9158 323.0552 323.1945 323.3339 323.4733 323.6126 323.7519 323.8912 324.0305 324.1698 324.3091 324.4484 324.5876 324.7269 324.8661 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20190912T152825.5Z 7194.644740 3 1 33.04 2 39.91 140.44 155.40 336.88 0.00 1 0.00 1 0 17 8.659e-03 6.545e-03 5.321e-04 2.966e-04 1.668476e-01 1.601825e-04 2.012800e-03 -6.000000e+00 5.294319e-03 229.59 -2.00 3.44 -2.00 315.89 0.00e+00 3.072865e-04 1.662498e-05 8.262907e-05 -6.000000e+00 2.376733e-04 290.36 -2.00 20.00 -2.00 315.11 0.00e+00 1.302 0.000 302.00 328.00 3 1.3062e+00 4.1472e-04 1.5584e-02 -6.0000e+00 1.3165e-02 -7.0198e-03 4.5884e-04 8.5385e-03 -6.0000e+00 1.4170e-02 -5.3849e-03 2.6451e-04 4.1619e-03 -6.0000e+00 8.4713e-03 -3.4632e-03 1.2114e-04 1.1560e-03 -6.0000e+00 3.6413e-03 3.3739e-02 -3.9775e-04 9.4745e-06 1.7021e-05 -6.0000e+00 2.6702e-04 -2.4804e-02 0.0000e+00 11 8 0 10 0 0 86.90 20.85 0.29 -0.02480 -0.02779 718 153 1 5 0 45.560 27.26 20.00 20.85 -15 -608 -853 -2677 -1746 -320 684 616 -56 -1265 -1701 -64 -15 277 75 -107 -162 755 971 1164 581 525 1558 1479 916 587 -267 -341 -88 1274 1763 1408 705 -2218 -3093 -1731 -1367 -868 -613 -962 -1210 -825 -645 -526 -155 -465 -721 -627 -659 127 875 508 788 893 711 1066 576 109 201 562 1125 1648 1509 1142 -499 -611 3 400 1342 680 211 326 429 472 -27 -391 -517 -532 -257 -975 -1592 -1804 -2037 -1366 -412 -352 42 267 541 254 94 52 190 666 361 136 560 698 -98 -843 -684 -618 -80 86 -1004 -1289 -779 -515 235 619 535 276 91 163 149 392 497 320 453 -17 -332 51 370 299 473 80 325 1162 564 -96 -338 -487 5 145 107 -248 68 283 -77 -230 -304 -667 -4 -151 -210 -681 -399 -70 156 155 -15 -360 -481 -18 -5 87 26 -39 -61 289 380 465 235 212 636 629 406 266 -119 -142 -34 528 750 576 303 -975 -1309 -727 -627 -461 -381 -679 -844 -594 -473 -387 -113 -335 -506 -462 -473 90 644 362 587 690 563 853 467 88 161 451 932 1449 1413 1105 -475 -538 2 319 1129 637 214 342 447 473 -26 -332 -436 -431 -217 -836 -1518 -1872 -2247 -1459 -466 -425 53 344 692 311 107 59 196 667 380 156 649 874 -128 -1084 -827 -700 -96 99 -1247 -1697 -1068 -733 322 887 790 406 128 228 192 478 608 411 620 -24 -498 75 534 413 619 100 422 1510 714 -129 -471 -693 7 218 156 -383 107 455 -124 -366 -472 -1009 SU 20190912T153750.4Z 7194.651278 7 1 32.85 2 38.76 143.67 156.01 341.99 0.00 1 0.00 1 0 17 8.650e-03 6.584e-03 5.166e-04 2.930e-04 1.644949e-01 1.582274e-04 1.986052e-03 -6.000000e+00 5.287512e-03 229.59 -2.00 3.44 -2.00 315.83 0.00e+00 2.742227e-04 1.621889e-05 8.458763e-05 -6.000000e+00 2.374165e-04 290.36 -2.00 20.00 -2.00 315.05 0.00e+00 1.281 0.000 302.00 328.00 3 1.3106e+00 4.0940e-04 1.5341e-02 -6.0000e+00 1.3147e-02 -7.2049e-03 4.5287e-04 8.4148e-03 -6.0000e+00 1.4152e-02 -5.2645e-03 2.6071e-04 4.1034e-03 -6.0000e+00 8.4608e-03 -3.3461e-03 1.1903e-04 1.1398e-03 -6.0000e+00 3.6360e-03 3.4467e-02 -3.8245e-04 9.3446e-06 1.6663e-05 -6.0000e+00 2.6673e-04 -2.3561e-02 0.0000e+00 11 8 0 10 0 0 86.73 20.66 0.30 -0.02356 -0.02643 724 155 1 5 0 45.170 27.05 20.00 20.66 178 -234 -739 -2547 -1883 -362 713 765 112 -1283 -1626 -335 8 140 75 -273 -96 735 940 1102 461 641 1586 1418 853 537 -214 -249 93 1189 1804 1327 615 -2273 -3089 -1879 -1387 -826 -671 -951 -1257 -857 -708 -552 -130 -462 -739 -643 -636 143 912 527 780 888 743 988 567 143 242 566 1157 1578 1509 1081 -459 -665 0 401 1421 760 184 304 473 516 -125 -382 -474 -530 -152 -1006 -1540 -1856 -2048 -1363 -381 -347 79 222 553 295 42 17 188 697 362 134 543 671 -90 -856 -696 -585 -125 60 -977 -1292 -801 -538 236 643 546 267 112 165 154 446 449 328 428 -29 -336 73 336 318 475 125 324 1190 505 -103 -339 -465 2 166 94 -257 64 277 -102 -211 -327 -628 43 -60 -186 -662 -441 -81 167 197 31 -373 -470 -98 2 45 26 -102 -37 286 375 449 190 264 659 614 386 247 -97 -106 37 501 779 551 268 -1012 -1324 -801 -645 -444 -423 -623 -888 -626 -526 -410 -96 -336 -523 -479 -461 103 678 379 586 692 593 798 463 117 195 458 967 1400 1423 1054 -440 -589 0 321 1202 715 187 320 495 519 -117 -325 -401 -431 -128 -868 -1473 -1934 -2268 -1462 -433 -419 100 287 709 363 48 19 194 700 382 155 631 843 -118 -1101 -842 -663 -149 69 -1215 -1704 -1100 -767 325 923 807 392 157 229 197 543 548 420 587 -42 -469 108 485 439 621 156 388 1544 639 -137 -471 -660 3 249 138 -395 101 444 -166 -335 -505 -948 SU 20190912T153915.4Z 7194.652262 9 1 32.89 2 38.59 144.17 156.09 342.78 0.00 1 0.00 1 0 17 8.562e-03 6.557e-03 5.116e-04 2.912e-04 1.639644e-01 1.570441e-04 1.975800e-03 -6.000000e+00 5.231755e-03 229.59 -2.00 3.44 -2.00 315.80 0.00e+00 3.038206e-04 1.605990e-05 7.872919e-05 -6.000000e+00 2.350190e-04 290.36 -2.00 20.00 -2.00 315.04 0.00e+00 1.278 0.000 302.00 328.00 3 1.3094e+00 4.0637e-04 1.5297e-02 -6.0000e+00 1.3008e-02 -6.8228e-03 4.4983e-04 8.3800e-03 -6.0000e+00 1.4005e-02 -4.9224e-03 2.5860e-04 4.0852e-03 -6.0000e+00 8.3726e-03 -3.5791e-03 1.1786e-04 1.1362e-03 -6.0000e+00 3.5961e-03 3.4641e-02 -3.8534e-04 9.2625e-06 1.6640e-05 -6.0000e+00 2.6406e-04 -2.0443e-02 0.0000e+00 11 8 0 10 0 0 85.32 20.65 0.31 -0.02044 -0.02334 715 153 1 5 0 45.730 27.05 20.01 20.65 335 -432 -819 -2487 -1976 -251 485 636 -29 -1284 -1469 -161 91 88 184 -210 -72 670 992 1049 494 677 1577 1461 746 557 -339 -170 52 1200 1802 1313 687 -2340 -2952 -1697 -1296 -815 -677 -993 -1285 -830 -675 -530 -139 -489 -652 -726 -630 137 919 549 778 939 721 1042 558 99 286 594 1113 1558 1521 1074 -472 -674 38 502 1342 669 190 276 462 528 -65 -421 -486 -478 -237 -1053 -1600 -1863 -2035 -1330 -346 -394 54 285 497 282 52 33 224 690 390 124 592 650 -129 -848 -661 -586 -20 118 -1040 -1270 -769 -488 261 615 515 267 96 96 168 369 479 345 418 -57 -300 50 401 329 460 114 372 1190 537 -92 -338 -500 31 165 97 -221 112 276 -108 -175 -365 -659 81 -111 -208 -649 -465 -57 115 165 -8 -376 -426 -47 29 28 65 -79 -28 263 398 430 205 280 659 636 339 258 -154 -72 21 508 712 548 301 -1047 -1268 -725 -607 -441 -429 -655 -912 -608 -503 -396 -103 -358 -463 -543 -457 99 686 397 588 734 577 844 458 81 231 482 935 1389 1441 1050 -453 -598 32 403 1142 633 194 291 484 532 -61 -359 -412 -390 -202 -912 -1538 -1950 -2261 -1430 -394 -479 68 370 638 348 60 37 231 694 413 144 690 819 -169 -1092 -800 -665 -24 136 -1298 -1678 -1058 -699 359 885 763 393 134 134 216 450 586 443 575 -83 -418 69 578 453 601 142 447 1429 681 -124 -471 -711 44 248 142 -340 177 444 -175 -278 -565 -996 SU 20190912T154040.5Z 7194.653246 11 1 32.93 2 38.43 144.67 156.16 343.57 0.00 1 0.00 1 0 17 8.552e-03 6.563e-03 5.093e-04 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