File name: Pandora40s1_CharlesCityVA_20191012_L2Fit_fwvt1c12d20180910p1-8.txt File generation date: 20250129T182139.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20170420.txt Instrument calibration file used: Pandora40s1_CF_v12d20180910.txt Level 1 file used: Pandora40s1_CharlesCityVA_20191012_L1_smca1c12d20180910p1-8.txt Full location name: VCU Rice Rivers Center Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20191012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.0114 492.1322 492.2529 492.3736 492.4943 492.6150 492.7357 492.8563 492.9770 493.0976 493.2182 493.3387 493.4593 493.5798 493.7004 493.8209 493.9414 494.0618 494.1823 494.3027 494.4232 494.5436 494.6640 494.7843 494.9047 495.0250 495.1454 495.2657 495.3859 495.5062 495.6265 495.7467 495.8669 495.9871 496.1073 496.2275 496.3476 496.4677 496.5878 496.7079 496.8280 496.9481 497.0681 497.1881 497.3081 497.4281 497.5481 497.6681 497.7880 497.9079 498.0278 498.1477 498.2676 498.3874 498.5073 498.6271 498.7469 498.8667 498.9864 499.1062 499.2259 499.3456 499.4653 499.5850 499.7046 499.8243 499.9439 500.0635 500.1831 500.3027 500.4222 500.5418 500.6613 500.7808 500.9003 501.0197 501.1392 501.2586 501.3780 501.4974 501.6168 501.7362 501.8555 501.9749 502.0942 502.2135 502.3327 502.4520 502.5712 502.6905 502.8097 502.9288 503.0480 503.1672 503.2863 503.4054 503.5245 503.6436 503.7627 503.8817 504.0007 504.1197 504.2387 504.3577 504.4767 504.5956 504.7145 504.8334 504.9523 505.0712 505.1900 505.3089 505.4277 505.5465 505.6653 505.7840 505.9028 506.0215 506.1402 506.2589 506.3776 506.4962 506.6149 506.7335 506.8521 506.9707 507.0893 507.2078 507.3264 507.4449 507.5634 507.6818 507.8003 507.9188 508.0372 508.1556 508.2740 508.3924 508.5107 508.6290 508.7474 508.8657 508.9840 509.1022 509.2205 509.3387 509.4569 509.5751 509.6933 509.8114 509.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191012T111850.1Z 7224.471413 1 1 32.19 2 89.86 99.41 107.33 278.73 0.00 1 0.00 1 0 22 8.369e-02 7.980e-02 7.145e-02 6.978e-02 4.248684e+03 4.455766e+03 7.396836e+01 -6.000000e+00 4.530513e+03 287.22 -2.00 20.00 -2.00 505.21 0.00e+00 9.510710e-04 1.913902e-03 8.364461e-05 -6.000000e+00 2.333821e-03 287.22 -2.00 20.00 -2.00 499.95 0.00e+00 5.171248e-01 1.382462e+00 6.369323e-02 -6.000000e+00 1.611701e+00 226.80 -2.00 3.44 -2.00 501.61 0.00e+00 20.158 0.138 489.00 513.00 1 6.8507e+00 1.0584e-01 3.5372e-02 -6.0000e+00 1.2360e-01 1.6628e-01 2.7684e-02 2.1785e-03 -6.0000e+00 3.2250e-02 1.0927e-04 -3.9202e-03 5.8906e-03 2.2449e-05 -6.0000e+00 7.3276e-03 -1.1006e-02 3.6540e-04 12 9 8 11 8 0 44.14 19.41 4.46 -0.01101 -0.03820 8 2 1 4 0 4000.000 26.21 20.01 19.41 -3205 2281 -138 -3818 880 9156 16825 -4534 7871 8445 -12181 2797 -9209 1174 -809 -11469 -7859 -4234 6670 1429 372 -6151 -1041 2199 5561 9019 -6192 2549 1481 6492 -6878 5840 -3811 536 12718 -989 2825 4708 18685 3596 63 2796 -15888 8305 -6100 5432 -1055 -2117 -5826 -4922 -9033 -42 11010 16295 789 -10757 8569 4948 -11736 11542 -11527 6664 10570 -3838 4460 -6173 12660 -4232 10800 5208 -3462 6488 -8867 16356 -3420 1292 9880 7171 2683 -1663 -10801 -6937 2459 969 3968 -1279 -3404 -4009 -8910 10918 3835 -4568 -192 17862 -3596 -2379 -5461 -379 7315 -3271 13850 1631 -10832 7077 3905 21455 -11458 8987 -10988 25110 -1648 -13434 1387 -6786 17425 -11078 1040 -4995 11944 -6033 5475 10134 -5874 16114 2989 9855 -2878 1441 867 -7747 4054 -3364 9583 -624 -2197 1395 -5938 -3397 -10495 8174 -7746 14185 -1347 -759 16820 -13030 -7384 -3197 5768 14383 3912 -3279 2225 -142 -4214 955 9348 16256 -5439 8386 8826 -15279 3001 -10890 1233 -857 -13496 -9018 -4784 6967 1596 420 -7393 -1190 2435 5988 9412 -7454 2799 1605 6450 -7565 5681 -4108 570 12517 -1127 3075 4961 17000 3731 67 2925 -20026 8391 -7148 5730 -1179 -2361 -6619 -5422 -10015 -41 9595 13478 772 -12137 8251 5001 -13922 10904 -13507 6578 10113 -4215 4496 -6796 11424 -4420 9645 4827 -3434 5853 -9338 13681 -3495 1262 8760 6380 2452 -1570 -11105 -6942 2267 908 3647 -1254 -3412 -4023 -9335 9473 3570 -4643 -190 15037 -3680 -2360 -5462 -351 6113 -2950 10477 1395 -10690 6126 3619 17054 -12372 7845 -11406 18372 -1576 -14606 1326 -7072 14505 -12125 1019 -5217 10588 -6258 5001 8687 -5774 12834 2719 8411 -2770 1330 800 -7753 3620 -3170 7818 -554 -1963 1203 -5609 -3211 -10754 7089 -7890 11745 -1297 -731 13727 -14087 -7466 -3023 4872 11027 3323 SO 20191012T112047.0Z 7224.472766 3 1 32.01 2 89.47 99.71 107.70 279.04 0.00 1 0.00 1 0 15 5.985e-02 5.798e-02 6.192e-02 6.074e-02 5.786281e+02 3.531753e+03 2.861468e+01 -6.000000e+00 3.238841e+03 287.22 -2.00 20.00 -2.00 505.25 0.00e+00 -1.082665e-04 1.654917e-03 3.240988e-05 -6.000000e+00 1.671954e-03 287.22 -2.00 20.00 -2.00 499.88 0.00e+00 4.427360e+00 1.204528e+00 1.501773e-02 -6.000000e+00 1.164805e+00 226.80 -2.00 3.44 -2.00 501.56 0.00e+00 19.569 0.126 489.00 513.00 1 6.5253e+00 9.2263e-02 3.3371e-02 -6.0000e+00 8.9109e-02 8.2436e-02 2.4136e-02 1.8577e-03 -6.0000e+00 2.3621e-02 1.2644e-04 3.3606e-03 5.0614e-03 9.3830e-06 -6.0000e+00 5.2596e-03 2.5083e-02 -4.6554e-04 12 8 8 10 0 0 -60.95 19.41 3.81 0.02508 0.04839 8 2 1 4 0 4000.000 26.21 19.96 19.41 900000 -6558 -4084 -8408 6337 7873 5951 -2946 -2272 -6889 -4171 -5714 6872 -1750 7298 -483 -52 4362 -1466 -4582 2823 5660 -1805 5134 -352 -2219 5752 3716 -1009 -7644 -9290 -524 -55 6020 -10193 4662 4751 7951 -2463 7055 5730 7772 -745 -2583 -5704 9830 6559 1334 3471 -3895 -7178 1159 -1974 5504 -6620 -10153 8342 -3753 9930 -1632 5448 -883 -6073 6518 650 -5944 5709 18464 -6365 1807 -2575 -4202 -8623 -302 -4469 10779 -5500 3764 14824 -1901 5044 2492 3196 3389 4103 8226 2264 4065 -4048 -5722 -1858 2692 -647 8122 -631 68 1125 -2338 512 407 -2594 -8365 11931 3832 6961 3835 -9800 -2764 -4302 3027 532 3436 -3426 1758 -3453 4717 -7423 2638 11479 -6194 -3625 -1635 1817 4308 -7904 3761 -1898 -594 -5719 -6664 8995 12151 872 -152 473 12428 -12307 -1894 7173 -5064 2274 -6032 16695 4129 4249 -5726 867 -3487 -844 -1246 -6831 900000 -6836 -4252 -9475 6413 8012 6287 -3443 -2653 -8338 -4850 -6661 7002 -1899 7181 -512 -55 4540 -1657 -5455 3150 6148 -2109 5604 -406 -2617 6273 4109 -1147 -8948 -10688 -550 -58 6132 -12595 5121 5195 8319 -2810 7240 5903 7862 -824 -2930 -6728 10057 6911 1461 3664 -4321 -7961 1146 -1966 5053 -6914 -11287 7996 -4106 9575 -1748 5407 -932 -6765 6432 675 -6495 5474 15397 -6633 1714 -2502 -4119 -8872 -289 -4503 9444 -5558 3408 11838 -1758 4347 2213 2843 3019 3648 7117 2089 3671 -3938 -5660 -1777 2474 -622 7294 -615 65 1048 -2205 456 353 -2270 -7726 9232 3308 6062 3504 -10148 -2631 -4072 2642 479 3059 -3311 1640 -3417 4338 -7704 2495 9985 -6302 -3544 -1547 1640 3781 -7870 3370 -1793 -555 -5599 -6574 7661 9970 781 -136 415 9683 -12334 -1769 6269 -5046 2135 -6172 13780 3869 4005 -5955 841 -3456 -793 -1149 -6642 SO 20191012T112239.0Z 7224.474063 5 1 32.01 2 89.11 99.99 108.05 279.33 0.00 1 0.00 1 0 15 5.534e-02 5.349e-02 5.183e-02 5.087e-02 -2.504913e+02 2.902560e+03 7.431246e+01 -6.000000e+00 2.995749e+03 287.22 -2.00 20.00 -2.00 505.18 0.00e+00 -3.660321e-04 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