File name: Pandora153s1_ChelseaMA_20240715_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240716T045614.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240715_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240715T145536.0Z 8962.621945 4 1 50.49 2 31.88 122.26 133.39 74.14 0.00 1 0.00 1 0 17 7.939e-03 6.001e-03 1.996e-04 1.221e-04 1.683224e-01 6.385122e-05 2.044333e-03 -6.000000e+00 4.682530e-03 233.01 -2.00 3.54 -2.00 315.51 0.00e+00 3.478921e-04 6.112316e-06 2.109203e-05 -6.000000e+00 2.083560e-04 288.52 -2.00 20.00 -2.00 314.76 0.00e+00 1.177 0.000 302.00 328.00 3 1.1567e-02 1.6625e-04 1.4846e-02 -6.0000e+00 1.1755e-02 2.9842e-02 1.8456e-04 8.9107e-03 -6.0000e+00 1.2705e-02 -6.6273e-03 1.0516e-04 4.3046e-03 -6.0000e+00 7.5640e-03 -6.2952e-04 4.6323e-05 1.1898e-03 -6.0000e+00 3.1676e-03 1.3675e-01 -1.8861e-05 3.5862e-06 1.5598e-05 -6.0000e+00 2.2434e-04 1.0396e-02 3.6581e-06 10 0 0 10 0 0 21.79 20.94 0.31 0.01040 0.01025 3039 575 1 5 0 16.600 23.64 15.00 20.94 39.11 0.0 1030.98 -216 -745 -1149 -2825 -2451 -1151 -234 826 224 -1116 -1589 -551 -307 -29 467 -120 109 505 860 1078 479 691 1485 1036 896 612 -68 -307 184 1079 1441 1772 1267 -1205 -2067 -1396 -1520 -554 -216 -687 -959 -725 -727 -600 -186 -430 -580 -373 -504 335 761 599 851 731 548 846 505 189 404 628 983 1192 1394 971 -329 -367 -269 0 1005 394 141 176 138 311 48 -128 -228 -220 82 -600 -1021 -1523 -2018 -1323 -921 -670 -345 21 143 72 309 204 353 897 585 378 647 516 -260 -413 -429 -577 31 145 -826 -1044 -692 -716 -97 216 139 42 37 86 172 491 453 454 365 -71 -289 41 332 332 640 451 844 1357 647 330 12 -132 83 162 -25 -269 73 36 -313 -275 -322 -457 -498 -61 -227 -353 -818 -627 -275 -58 223 67 -350 -491 -169 -102 -11 190 -48 45 210 365 469 212 303 652 475 429 301 -33 -141 85 479 654 845 642 -632 -1026 -673 -793 -302 -139 -468 -711 -556 -570 -472 -145 -332 -436 -269 -383 250 587 449 667 597 459 716 434 162 340 526 847 1092 1367 922 -310 -343 -230 0 864 382 137 179 141 304 48 -115 -201 -182 69 -521 -990 -1620 -2111 -1441 -1069 -831 -418 26 178 86 366 220 373 905 617 402 755 660 -326 -508 -534 -666 34 166 -1034 -1384 -887 -957 -134 314 210 63 53 113 223 598 550 576 498 -96 -405 57 448 461 839 562 997 1595 806 436 17 -186 117 222 -36 -409 114 57 -470 -432 -491 -678 -727 SS 20240715T150054.1Z 8962.625627 7 1 50.47 2 31.06 124.03 132.50 75.25 0.00 1 0.00 1 0 17 7.908e-03 6.011e-03 1.935e-04 1.195e-04 1.670593e-01 6.262919e-05 2.025659e-03 -6.000000e+00 4.664047e-03 233.01 -2.00 3.54 -2.00 315.45 0.00e+00 3.428440e-04 5.923835e-06 2.066335e-05 -6.000000e+00 2.075291e-04 288.52 -2.00 20.00 -2.00 314.72 0.00e+00 1.167 0.000 302.00 328.00 3 -1.4188e-02 1.6305e-04 1.4719e-02 -6.0000e+00 1.1708e-02 2.9908e-02 1.8123e-04 8.8337e-03 -6.0000e+00 1.2655e-02 -6.2558e-03 1.0312e-04 4.2669e-03 -6.0000e+00 7.5341e-03 -7.9802e-04 4.5121e-05 1.1790e-03 -6.0000e+00 3.1552e-03 1.4209e-01 -3.0297e-05 3.5039e-06 1.5535e-05 -6.0000e+00 2.2344e-04 1.0223e-02 4.9906e-06 10 0 0 10 0 0 55.64 20.97 0.31 0.01022 0.01000 3086 583 1 5 0 16.350 23.72 15.00 20.97 39.25 0.0 1031.13 -223 -787 -1217 -2818 -2313 -1206 -165 798 235 -1056 -1540 -630 -316 -53 433 -92 68 536 901 1102 463 646 1441 1009 892 572 -62 -262 208 1062 1476 1743 1321 -1216 -2040 -1372 -1564 -560 -172 -679 -981 -734 -710 -578 -224 -445 -591 -395 -515 349 750 596 894 761 541 855 534 197 401 581 976 1165 1373 946 -337 -350 -285 -13 1000 391 124 192 138 304 42 -148 -233 -205 74 -602 -1029 -1542 -2031 -1354 -896 -691 -333 12 159 69 300 202 372 871 571 367 631 524 -250 -421 -435 -595 40 138 -809 -1035 -699 -728 -99 234 120 37 39 90 178 501 468 464 370 -87 -290 51 334 336 618 467 811 1355 658 325 8 -136 64 167 -41 -255 63 45 -298 -271 -303 -443 -522 -64 -244 -380 -829 -601 -293 -41 219 71 -337 -483 -196 -106 -20 179 -37 28 225 387 485 208 286 641 469 432 285 -31 -122 98 477 677 840 676 -586 -1023 -668 -825 -308 -112 -467 -734 -569 -562 -459 -176 -347 -449 -287 -395 263 584 450 705 627 457 729 462 170 340 491 847 1076 1356 904 -319 -329 -246 -11 865 380 121 196 141 299 42 -133 -189 -171 63 -525 -1003 -1648 -2135 -1482 -1044 -861 -405 15 198 83 357 218 395 882 605 392 740 673 -315 -519 -543 -690 44 158 -1017 -1280 -900 -977 -138 340 181 56 56 119 232 612 570 591 507 -119 -408 71 452 434 813 584 961 1597 822 429 11 -192 85 228 -59 -388 98 68 -448 -427 -464 -657 -764 SS 20240715T150605.3Z 8962.629229 10 1 50.49 2 30.27 125.83 131.62 76.32 0.00 1 0.00 1 0 17 7.900e-03 6.026e-03 1.858e-04 1.154e-04 1.656267e-01 6.050009e-05 2.009645e-03 -6.000000e+00 4.659688e-03 233.01 -2.00 3.54 -2.00 315.43 0.00e+00 3.442905e-04 5.697659e-06 2.043173e-05 -6.000000e+00 2.073266e-04 288.52 -2.00 20.00 -2.00 314.70 0.00e+00 1.157 0.000 302.00 328.00 3 -6.8011e-02 1.5746e-04 1.4598e-02 -6.0000e+00 1.1698e-02 3.0296e-02 1.7480e-04 8.7602e-03 -6.0000e+00 1.2643e-02 -6.0783e-03 9.9594e-05 4.2312e-03 -6.0000e+00 7.5270e-03 -8.1429e-04 4.3649e-05 1.1699e-03 -6.0000e+00 3.1524e-03 1.5176e-01 -1.4778e-05 3.3914e-06 1.5454e-05 -6.0000e+00 2.2322e-04 9.7534e-03 2.0767e-06 10 0 0 10 0 0 23.33 21.00 0.31 0.00975 0.00964 3296 623 1 5 0 15.310 23.72 15.01 21.00 39.31 0.0 1031.23 -201 -754 -1156 -2878 -2289 -1130 -71 796 290 -1038 -1510 -542 -374 -21 403 -118 57 488 838 1063 447 657 1482 1027 870 562 -50 -273 208 1042 1501 1799 1307 -1215 -2013 -1357 -1618 -562 -223 -665 -961 -737 -722 -604 -207 -475 -571 -387 -503 352 755 598 875 766 531 860 537 206 381 591 1000 1187 1399 921 -305 -372 -276 -37 1013 386 109 196 130 306 41 -151 -241 -196 94 -596 -1015 -1547 -2025 -1359 -910 -681 -332 7 147 65 281 208 356 917 593 366 628 530 -270 -416 -421 -581 34 143 -788 -1022 -702 -714 -104 217 137 45 22 95 174 500 454 470 371 -69 -280 53 348 353 613 459 831 1341 654 334 26 -135 47 173 -39 -240 74 32 -314 -285 -315 -461 -513 -58 -236 -365 -857 -601 -277 -18 221 89 -334 -478 -170 -127 -8 168 -48 24 206 363 471 202 293 663 480 424 282 -25 -128 98 470 692 871 672 -588 -1013 -662 -856 -310 -145 -459 -721 -573 -573 -481 -163 -372 -434 -282 -387 266 589 452 692 631 448 734 465 178 323 500 867 1096 1381 881 -290 -350 -237 -31 875 376 107 200 133 302 41 -136 -195 -162 80 -519 -986 -1650 -2124 -1484 -1058 -846 -403 9 183 78 334 225 377 926 625 389 734 678 -339 -512 -524 -672 38 164 -986 -1356 -901 -953 -144 314 207 67 32 125 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