File name: Pandora153s1_ChelseaMA_20240730_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240731T045944.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240730_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240730T104351.9Z 8977.447128 236 1 50.79 2 78.97 75.19 27.66 119.00 0.00 1 0.00 1 0 17 5.612e-01 1.685e-02 2.790e-01 8.837e-03 7.256512e-01 4.883256e-03 8.554612e-03 -6.000000e+00 3.295723e-01 232.46 -2.00 3.54 -2.00 321.54 0.00e+00 4.936571e-03 2.613300e-03 4.412605e-03 -6.000000e+00 1.473193e-02 288.84 -2.00 20.00 -2.00 320.93 0.00e+00 5.036 0.002 302.00 328.00 3 2.6508e+00 1.8092e-02 6.7004e-02 -6.0000e+00 8.2608e-01 3.3607e-01 2.4671e-02 4.7135e-02 -6.0000e+00 8.9401e-01 -3.9105e-01 2.2027e-02 2.3723e-02 -6.0000e+00 5.3260e-01 1.5493e-01 1.0201e-02 6.5216e-03 -6.0000e+00 2.2266e-01 1.0545e-04 -9.6054e-04 2.4867e-04 1.2847e-04 -6.0000e+00 1.5871e-02 2.8546e-02 -2.0905e-05 12 8 8 10 0 0 99.91 19.13 0.41 0.02855 0.02133 32 6 1 5 0 1587.120 22.19 15.00 19.13 28.06 0.0 979.55 -163855 -161059 133608 -210973 -119660 -181880 -209498 -26896 -182326 -172389 -154154 -119289 -119043 -105169 -89440 21841 -78709 -49379 -64519 740 157464 -95689 -40786 -82922 -17381 -36647 67781 -73749 -52443 -5116 -62424 44137 -209 40859 -25447 18694 -13818 -295 19158 -3167 1896 20505 30212 4640 14493 10396 20535 31557 15671 31696 20539 16944 17184 19418 18174 20103 7133 4787 10756 5836 18577 4250 11560 11157 2530 4670 3738 8116 4160 7768 727 5458 5053 1873 2108 911 -3438 -6464 -812 -4613 79 -2017 -460 -2063 -1267 -436 2104 721 -672 449 -90 -207 -4107 72 -906 -1909 -345 477 -313 -1629 -1092 -3027 -2302 -2592 -3289 -2013 -455 -50 -1282 306 -366 228 6 395 -444 729 955 -359 243 -584 900 1645 1484 1361 1459 814 220 1395 39 974 -338 365 -119 506 21 -342 209 -423 -46 -233 -27 -615 -687 -2054 -2271 1151 -4959 -1031 -2850 -4596 -232 -3714 -3377 -2657 -1682 -2145 -2142 -1962 207 -2097 -1192 -1769 12 1357 -3748 -1054 -3183 -404 -1074 701 -3051 -1763 -119 -3120 913 -8 1056 -1228 580 -655 -14 941 -229 145 1396 1953 396 1137 869 1593 2284 1405 2622 2124 1845 2046 2449 2449 2756 1134 769 1576 887 2591 759 2192 2378 614 1094 885 1927 1147 2361 259 1911 1734 619 629 248 -927 -1869 -254 -1785 34 -1014 -248 -1204 -783 -284 1394 495 -463 292 -55 -119 -2407 43 -617 -1534 -317 497 -353 -1842 -1143 -2901 -2025 -2321 -3169 -2022 -477 -56 -1623 429 -572 372 9 623 -671 1056 1403 -561 397 -988 1471 2558 2226 1967 2025 1096 293 1961 63 1759 -679 775 -269 1210 48 -841 522 -1071 -113 -553 -65 -1404 -1539 SS 20240730T104930.9Z 8977.451052 239 1 50.61 2 77.96 76.09 26.77 120.89 0.00 1 0.00 1 0 25 5.070e-01 1.096e-02 2.630e-01 6.199e-03 6.859879e-01 3.384552e-03 7.784576e-03 -6.000000e+00 2.975328e-01 232.46 -2.00 3.54 -2.00 321.35 0.00e+00 4.073118e-03 1.754833e-03 1.599690e-03 -6.000000e+00 1.330637e-02 288.84 -2.00 20.00 -2.00 320.72 0.00e+00 4.646 0.002 302.00 328.00 3 2.4973e+00 1.2231e-02 5.9757e-02 -6.0000e+00 7.4573e-01 1.6741e-01 1.6898e-02 3.7879e-02 -6.0000e+00 8.0729e-01 -1.6240e-01 1.5865e-02 2.0058e-02 -6.0000e+00 4.8093e-01 5.7982e-02 7.3879e-03 7.0181e-03 -6.0000e+00 2.0088e-01 1.9051e-04 -1.1800e-03 1.7634e-04 9.5948e-05 -6.0000e+00 1.4342e-02 3.0460e-02 -1.6966e-04 12 8 8 10 0 0 99.99 19.15 0.29 0.03046 0.02159 54 10 1 5 0 937.150 22.19 15.00 19.15 28.18 0.0 980.12 -245065 -144827 -61865 -118946 -148392 -107930 -187052 -113220 -188816 -86419 -180746 184879 -94341 -124626 -108936 -47636 -26754 30982 832 -48416 23090 -55305 -37231 23058 -57637 -16760 -43718 -37383 -31614 -8323 -20599 -14933 6251 2814 13954 6071 -12828 4058 -10065 -6665 12874 7125 19163 -1323 8690 5288 9453 -573 11546 8665 5174 10886 5654 8205 3374 4170 7400 4861 10120 -2207 6872 8959 7346 3869 2471 2385 1902 -266 3042 3183 2166 2162 -618 1652 44 -2172 1261 -4768 499 -3389 -2068 -522 -2012 -197 -2761 529 -1147 6 898 1386 578 321 -1068 1406 -866 -1379 1106 200 -644 -290 -804 -1341 -100 -969 -2007 -1200 -1651 -482 -203 321 339 -33 377 -153 -34 369 735 318 -95 189 -468 721 459 625 516 508 714 1151 173 393 -338 -512 437 262 -282 -407 259 65 -38 -213 -68 -326 -215 -4714 -1194 -374 -784 -1223 -652 -2467 -890 -3217 -627 -3278 1118 -1198 -2787 -2634 -749 -388 281 11 -1112 265 -1404 -833 307 -1847 -375 -1295 -1017 -822 -191 -647 -533 208 102 439 209 -597 191 -669 -508 903 568 1425 -124 751 486 857 -55 1131 948 597 1328 798 1226 560 715 1257 839 1613 -395 1178 1674 1591 967 652 619 495 -74 919 1098 824 850 -244 597 15 -668 356 -1486 168 -1412 -992 -280 -1193 -122 -1874 369 -851 4 660 969 380 199 -654 885 -631 -1174 1064 220 -765 -338 -875 -1322 -90 -903 -2022 -1265 -1853 -575 -267 471 545 -51 631 -247 -52 546 1100 502 -158 323 -791 1156 712 930 738 699 963 1650 283 719 -680 -1005 894 572 -661 -995 642 162 -95 -503 -151 -684 -483 SS 20240730T105454.9Z 8977.454803 242 1 50.48 2 76.99 76.94 25.94 122.79 0.00 1 0.00 1 0 17 3.984e-01 7.610e-03 1.114e-01 3.571e-03 6.453012e-01 1.926778e-03 7.300831e-03 -6.000000e+00 2.339917e-01 232.46 -2.00 3.54 -2.00 321.13 0.00e+00 2.901608e-03 9.261965e-04 1.721658e-03 -6.000000e+00 1.045923e-02 288.84 -2.00 20.00 -2.00 320.48 0.00e+00 4.324 0.001 302.00 328.00 3 2.1539e+00 6.6424e-03 5.5821e-02 -6.0000e+00 5.8651e-01 1.4360e-01 8.9558e-03 3.5628e-02 -6.0000e+00 6.3472e-01 -1.3471e-01 8.3274e-03 1.8660e-02 -6.0000e+00 3.7813e-01 4.2682e-02 3.9635e-03 6.0334e-03 -6.0000e+00 1.5810e-01 3.8377e-04 -3.1858e-04 1.0315e-04 7.7718e-05 -6.0000e+00 1.1267e-02 2.8044e-02 -2.1234e-05 11 8 0 10 0 0 97.94 19.16 0.42 0.02804 0.02565 64 12 1 5 0 788.710 22.19 15.00 19.16 28.33 0.0 980.95 -145193 -159766 -126862 -158943 -134412 -113812 -116067 -88257 -118440 -102623 -141578 -104736 -101639 -38928 -33913 -29357 -19231 -37865 -8784 -20140 4488 -33773 -18832 -18579 -8438 -649 -21943 -18925 -15190 -13999 -14810 -2098 -251 1726 3166 -7119 8357 2512 9482 174 3308 3516 1902 1095 859 1922 620 7118 1930 3150 3116 4207 3437 5069 1642 3431 2186 2731 -372 1733 2582 2518 4142 4418 1815 2132 1093 147 1043 1687 562 887 818 -188 -473 -519 -2061 -2080 -1182 -1855 -1842 -511 -1827 -1496 -71 353 -34 1411 377 895 68 -208 -104 210 -616 -372 620 554 -457 -644 -311 -1030 -390 -142 -1640 -1514 -922 -616 -278 276 278 247 321 -52 -56 124 600 62 307 -291 -16 287 690 504 376 135 434 858 174 200 -243 27 -64 -15 -121 -357 381 97 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