File name: Pandora153s1_ChelseaMA_20240913_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20240914T044508.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_ChelseaMA_20240913_L1_smca1c1d20210519p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240913T113920.9Z 9022.485659 82 1 51.82 2 76.69 97.53 161.46 318.71 0.00 1 0.00 1 0 17 3.634e-01 1.186e-02 3.120e-01 1.042e-02 5.622624e-01 5.547704e-03 6.622390e-03 -6.000000e+00 2.107593e-01 229.29 -2.00 3.54 -2.00 320.84 0.00e+00 2.470287e-03 2.347042e-03 2.582471e-03 -6.000000e+00 9.456905e-03 286.82 -2.00 20.00 -2.00 320.16 0.00e+00 4.236 0.001 302.00 328.00 3 3.9717e+00 1.8052e-02 5.2862e-02 -6.0000e+00 5.2449e-01 1.8115e-01 2.3026e-02 3.3234e-02 -6.0000e+00 5.6944e-01 -1.2433e-01 2.0290e-02 1.6367e-02 -6.0000e+00 3.3973e-01 3.8857e-02 9.9846e-03 4.4477e-03 -6.0000e+00 1.4247e-01 7.3711e-05 -3.9773e-04 3.1395e-04 7.3393e-05 -6.0000e+00 1.0271e-02 3.6794e-02 -2.3751e-05 12 8 8 10 0 0 97.68 18.37 0.50 0.03679 0.03381 16 3 1 5 0 3238.630 21.58 14.99 18.37 23.37 0.0 958.58 -154795 -3338 -23863 -57487 -111547 -47893 -138911 -4842 -141598 -43666 86326 58610 189727 24985 162877 7516 27219 -51723 28517 98154 4918 19286 -29092 361 7066 -1283 -1178 -9496 58857 -15559 8031 -15863 -8246 -14114 9740 -30175 -4647 9259 2540 1711 3282 13245 4938 2051 -629 8828 8078 -1603 6133 3669 1238 -4617 4034 2945 16765 -1140 4623 -4499 -502 1232 2906 5858 610 5173 287 3927 -535 2069 89 1712 3879 -233 2065 -3014 -213 -1561 -4745 -3103 -1874 -106 -1305 -3489 -1535 437 -1772 891 22 2145 -351 -257 994 -1744 -915 -819 -777 1559 818 -1110 -124 -335 -567 -930 -761 -1261 -1638 -1556 -1082 -379 1209 1156 403 683 747 110 -921 -723 632 637 -264 -3 468 278 610 620 328 558 -496 264 135 132 -581 87 279 -178 -318 -470 817 -358 -126 530 -235 14 -495 -4005 -34 -243 -637 -1958 -487 -3465 -49 -4579 -621 877 596 1928 330 1655 168 553 -2294 667 1197 155 529 -1360 14 266 -55 -50 -425 1316 -791 375 -997 -541 -1017 584 -2481 -364 753 244 194 406 1579 666 290 -92 1199 1120 -250 918 600 229 -998 868 689 3578 -301 1175 -1239 -129 311 754 1629 201 1778 106 1342 -188 732 36 767 1846 -119 1009 -1456 -91 -610 -1802 -1184 -793 -51 -739 -2266 -1055 312 -1383 720 19 1825 -303 -211 749 -1258 -631 -586 -619 1392 842 -1305 -152 -405 -636 -948 -730 -1255 -1754 -1754 -1282 -477 1633 1724 655 1139 1222 173 -1369 -1035 907 960 -425 -5 764 438 927 905 459 749 -658 368 210 226 -1080 168 565 -382 -728 -1125 1970 -885 -306 1225 -518 28 -1028 SS 20240913T115023.1Z 9022.493323 85 1 50.05 2 74.68 99.47 162.63 325.20 0.00 1 0.00 1 0 17 1.093e-01 5.756e-03 9.093e-02 3.378e-03 5.023744e-01 1.753206e-03 5.728137e-03 -6.000000e+00 6.338068e-02 229.29 -2.00 3.54 -2.00 320.42 0.00e+00 7.478497e-04 6.663043e-04 6.421977e-04 -6.000000e+00 2.844396e-03 286.82 -2.00 20.00 -2.00 319.71 0.00e+00 3.713 0.001 302.00 328.00 3 2.8866e+00 5.4134e-03 4.5530e-02 -6.0000e+00 1.5773e-01 5.7023e-02 6.7735e-03 2.6623e-02 -6.0000e+00 1.7125e-01 -1.8820e-02 5.8536e-03 1.3174e-02 -6.0000e+00 1.0217e-01 -7.3911e-03 2.9388e-03 3.7338e-03 -6.0000e+00 4.2839e-02 4.0303e-04 -3.0088e-04 1.0177e-04 4.3014e-05 -6.0000e+00 3.0896e-03 3.7411e-02 -5.3748e-05 10 0 0 10 0 0 93.93 18.38 0.33 0.03741 0.03515 50 9 1 5 0 1000.890 21.69 15.01 18.38 23.76 0.0 960.97 -38269 22229 -18549 -45011 -24604 -27287 -7790 -42302 -54845 -57511 -21127 -31667 -5189 724 -13056 -8474 -3971 -3180 -3419 -8759 -8007 -6757 -2581 -4516 4248 -2274 -6183 -657 -2510 -6978 3875 -11825 -487 -2787 -726 1399 -3652 3954 -3714 1967 -4125 2130 -1674 1846 641 604 1504 -246 800 43 2259 -167 2261 860 2358 864 1683 406 -808 1735 -1 1808 905 1795 47 534 749 -827 2065 -57 1108 766 637 176 -568 -1269 -1682 -1677 -1477 -691 -1243 -1637 -1886 -1078 -809 -4 260 722 1019 586 742 -31 112 356 321 590 1060 716 153 -628 -704 -532 -152 -593 -1328 -1471 -838 -837 330 96 559 326 344 221 -316 245 151 188 -142 -241 -268 602 737 39 156 -322 625 855 110 -298 46 -180 148 -49 -199 -154 133 137 -431 -206 154 14 61 -429 154 -202 -608 -251 -288 -74 -655 -1084 -1251 -334 -626 -96 16 -387 -276 -136 -117 -135 -384 -356 -301 -116 -226 210 -126 -357 -34 -131 -407 232 -954 -39 -238 -58 112 -345 416 -467 275 -677 349 -296 321 114 109 270 -46 151 9 490 -41 584 242 685 264 521 126 -249 520 0 623 351 748 20 218 298 -344 926 -30 618 443 362 95 -282 -572 -713 -720 -705 -380 -787 -1163 -1446 -869 -697 -4 247 697 972 535 627 -24 84 276 276 577 1172 887 201 -811 -845 -580 -157 -637 -1543 -1804 -1077 -1145 484 141 882 527 544 331 -487 362 226 295 -218 -384 -425 1001 1184 61 231 -460 864 1241 178 -486 80 -329 281 -99 -426 -343 302 317 -991 -455 321 28 121 SS 20240913T120030.6Z 9022.500354 88 1 50.21 2 72.84 101.28 163.55 331.81 0.00 1 0.00 1 0 25 8.933e-02 5.634e-03 3.425e-02 2.050e-03 4.583148e-01 1.065776e-03 5.344697e-03 -6.000000e+00 5.180077e-02 229.29 -2.00 3.54 -2.00 319.98 0.00e+00 1.481484e-03 3.473704e-04 3.067489e-04 -6.000000e+00 2.324506e-03 286.82 -2.00 20.00 -2.00 319.22 0.00e+00 3.339 0.001 302.00 328.00 3 2.5050e+00 3.1618e-03 4.1199e-02 -6.0000e+00 1.2891e-01 5.5991e-02 3.8118e-03 2.4263e-02 -6.0000e+00 1.3996e-01 -2.2085e-02 3.0284e-03 1.1967e-02 -6.0000e+00 8.3500e-02 -3.3605e-03 1.5484e-03 3.6509e-03 -6.0000e+00 3.5015e-02 8.8507e-04 -4.1926e-04 6.1987e-05 4.2366e-05 -6.0000e+00 2.5249e-03 3.6672e-02 -5.4468e-05 10 0 0 10 0 0 94.28 18.41 0.31 0.03667 0.03352 89 17 1 5 0 564.040 21.69 15.01 18.41 24.28 0.0 963.30 -34998 11408 -37309 -40691 -23792 -44672 -15683 -38477 -1900 -33889 -14525 -6620 -11320 -6296 -10496 7982 2568 4311 -6342 2749 -4676 999 1475 -287 667 -5801 542 -7941 116 -5139 5048 -2350 4501 730 -4672 -3069 -4774 1488 -2913 173 -2134 831 -744 -449 1189 -523 1662 -1802 1110 314 1915 1223 1007 1668 895 2131 -639 478 -940 -129 1434 1897 1818 1054 758 -220 733 -115 1837 112 616 592 132 251 -688 -422 -1674 -325 -1297 -805 -1203 -1519 -1587 -1334 -351 -400 362 672 967 570 570 472 173 670 -354 483 573 777 -371 -466 -622 -793 71 -474 -813 -1443 -798 -781 243 178 345 293 -4 282 18 465 269 251 -6 -452 -361 136 445 145 439 -142 1016 1000 240 -101 -275 -63 -137 182 -236 -31 95 268 -308 -114 -51 -250 12 -644 148 -821 -879 -400 -920 -263 -923 -35 -922 -337 -158 -340 -219 -455 329 122 216 -377 156 -292 59 91 -19 48 -465 41 -622 8 -403 405 -231 460 80 -516 -337 -597 189 -470 32 -440 176 -166 -101 267 -121 377 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