File name: Pandora153s1_ChelseaMA_20240916_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241015T154231.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20240916_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240916T111140.7Z 9025.466443 189 1 50.57 2 82.36 93.82 121.34 279.01 0.00 1 0.00 1 0 25 5.781e-01 3.218e-02 4.473e-01 2.914e-02 7.780043e-01 1.634572e-02 8.934289e-03 -6.000000e+00 3.364803e-01 228.97 -2.00 3.54 -2.00 321.83 0.00e+00 -8.228118e-04 8.896334e-03 6.969892e-03 -6.000000e+00 1.596133e-02 286.50 -2.00 20.00 -2.00 321.26 0.00e+00 6.982 0.006 302.00 328.00 3 2.8453e+00 6.2401e-02 9.0505e-02 -6.0000e+00 8.4694e-01 7.6709e-01 8.1716e-02 6.8131e-02 -6.0000e+00 9.2844e-01 -9.3271e-01 6.5558e-02 2.5880e-02 -6.0000e+00 5.4613e-01 3.8324e-01 3.0619e-02 6.6819e-03 -6.0000e+00 2.2721e-01 1.2861e-05 -7.2525e-04 8.2206e-04 1.0826e-04 -6.0000e+00 1.6082e-02 2.9992e-02 0.0000e+00 12 9 8 11 8 0 81.23 17.83 1.00 0.02999 0.02454 14 3 1 5 0 3611.960 21.17 15.00 17.83 21.47 0.0 950.96 -142725 900000 -43785 900000 -182597 -155210 -106248 900000 900000 -145340 -7882 -109077 900000 -92880 900000 64714 900000 36370 900000 900000 3642 -51945 -15693 -43088 -12019 281597 -28813 216991 82268 136187 65350 -7933 900000 -58718 23797 14436 199934 118854 18042 900000 16556 119681 -23656 43939 13100 59554 6509 69988 80029 17520 58295 11347 62286 13152 74564 3281 50380 10107 37616 37099 11744 9123 27385 52585 17786 31043 15889 13989 4411 10792 12417 5536 6462 4939 19655 -17512 -15027 -25048 3103 -612 2569 611 -6209 2226 -7771 1815 1637 -3987 1005 6398 -118 -9516 -4354 -6404 -1854 -2558 985 -2777 -2845 206 -3728 -1642 -7953 -952 -5410 3802 2168 -1514 187 622 3043 -1015 695 -1271 269 -1112 -926 1825 -1923 3914 2955 355 572 1768 -921 970 -572 24 303 2793 1641 -35 -418 -1407 -797 -211 1283 999 -762 953 -280 -842 -2153 -5363 900000 -1242 900000 -8444 -5311 -3013 900000 900000 -5942 -224 -3602 900000 -3943 900000 1835 900000 1031 900000 900000 103 -2279 -505 -1947 -426 7986 -1179 6154 2333 3862 1853 -360 900000 -4930 841 552 5670 3371 1041 900000 1227 3465 -2732 2635 1040 3054 556 3358 3663 1563 3948 1319 4858 1748 5815 520 5182 1480 4040 3872 1606 1420 4052 6805 3317 4970 2951 2780 1085 2833 3463 1677 1880 1352 4197 -4784 -3855 -7443 815 -198 936 259 -3043 1063 -4347 976 920 -2407 572 3271 -60 -5061 -2179 -3532 -1123 -1822 789 -2630 -2871 199 -3448 -1331 -6367 -739 -4700 3195 1957 -1540 208 783 4168 -1517 1030 -1857 369 -1517 -1285 2599 -3006 5878 4374 514 797 2371 -1226 1220 -721 33 475 4816 3144 -72 -920 -3328 -2005 -549 3331 2623 -1998 2329 -642 -1826 -4659 SS 20240916T111353.3Z 9025.467978 191 1 49.83 2 81.95 94.19 121.72 279.42 0.00 1 0.00 1 0 17 4.808e-01 2.740e-02 4.236e-01 2.388e-02 7.330424e-01 1.334362e-02 8.408776e-03 -6.000000e+00 2.769655e-01 228.97 -2.00 3.54 -2.00 321.82 0.00e+00 1.022498e-03 7.217798e-03 5.951901e-03 -6.000000e+00 1.390943e-02 286.50 -2.00 20.00 -2.00 321.24 0.00e+00 6.676 0.006 302.00 328.00 3 2.8463e+00 5.0258e-02 8.3337e-02 -6.0000e+00 6.9121e-01 6.1580e-01 6.7740e-02 5.8456e-02 -6.0000e+00 7.5422e-01 -8.0687e-01 5.6749e-02 2.6334e-02 -6.0000e+00 4.4594e-01 3.2627e-01 2.6088e-02 5.8876e-03 -6.0000e+00 1.8988e-01 1.9128e-05 -5.0170e-04 6.8673e-04 1.0838e-04 -6.0000e+00 1.3176e-02 3.0348e-02 0.0000e+00 12 8 8 10 0 0 85.50 17.84 0.67 0.03035 0.02658 18 3 1 5 0 2767.870 21.17 15.00 17.84 21.76 0.0 952.13 900000 -49490 900000 -154864 900000 -6397 900000 -43448 -202479 900000 -161789 900000 -114403 900000 -50467 -41036 154614 900000 -45964 -20653 112706 72839 174422 900000 12187 -21936 -41912 39041 -53268 19091 56092 102342 141600 40651 32208 73586 132536 -4902 113754 66493 63508 9992 28225 28272 6578 19860 1498 22051 42536 8031 22315 1133 55752 30123 36577 21513 43507 27743 12021 522 28950 22742 25026 14137 3873 18541 15128 13729 618 11816 -4121 15254 9912 -4769 3199 -11426 -8841 -18106 6030 -3504 -10015 866 -955 247 1799 1596 1375 973 3166 -671 -125 -2835 168 -5761 -4812 -5375 1260 -1625 -5002 -3155 -2813 -3451 -1822 -2078 -1615 -2658 2361 1503 2893 -665 90 583 911 1266 -205 -2459 -1938 -95 1993 1212 -635 2639 315 1123 1119 2077 237 220 247 155 956 -1787 44 620 594 -389 945 1005 92 -438 -219 72 -3039 900000 -1151 900000 -5643 900000 -149 900000 -1010 -12424 900000 -7127 900000 -4469 900000 -1591 -1348 3595 900000 -1896 -680 2621 1694 4056 900000 329 -836 -1873 908 -2419 477 1304 2380 3292 1309 1045 1711 3082 -292 2645 2798 2992 817 1989 1982 563 1514 137 1713 2843 796 2152 147 4684 3449 4131 2893 4806 3476 1671 79 3475 3213 3902 2713 842 3412 2880 2778 160 3127 -1362 4285 2836 -1462 819 -3034 -2197 -5141 1570 -1189 -4199 370 -449 122 934 876 790 571 1803 -377 -65 -1447 82 -3195 -3033 -3975 1015 -1524 -5191 -3151 -2591 -2867 -1396 -1657 -1377 -2415 2171 1511 3197 -860 127 864 1343 1800 -282 -3368 -2712 -138 3005 1883 -980 3785 447 1538 1480 2622 302 304 391 276 1844 -3750 97 1442 1472 -1008 2469 2655 240 -1097 -512 159 -6788 SS 20240916T112425.1Z 9025.475291 194 1 50.66 2 80.02 96.00 123.51 281.38 0.00 1 0.00 1 0 17 4.778e-01 1.565e-02 2.438e-01 7.101e-03 6.542660e-01 3.836224e-03 7.619183e-03 -6.000000e+00 2.714573e-01 228.97 -2.00 3.54 -2.00 321.47 0.00e+00 4.021419e-03 2.001746e-03 3.710144e-03 -6.000000e+00 1.307922e-02 286.50 -2.00 20.00 -2.00 320.86 0.00e+00 5.516 0.003 302.00 328.00 3 2.5350e+00 1.3905e-02 6.7049e-02 -6.0000e+00 6.7483e-01 1.9449e-01 1.8862e-02 4.0814e-02 -6.0000e+00 7.3413e-01 -2.7503e-01 1.7745e-02 2.0592e-02 -6.0000e+00 4.3744e-01 1.1124e-01 8.3473e-03 5.8507e-03 -6.0000e+00 1.8726e-01 8.9712e-05 -4.5737e-04 2.0361e-04 1.0340e-04 -6.0000e+00 1.2837e-02 2.9672e-02 0.0000e+00 12 8 8 10 0 0 93.85 17.87 0.46 0.02967 0.02624 47 9 1 5 0 1077.780 21.17 15.01 17.87 22.56 0.0 955.50 900000 -180956 900000 -199888 900000 -222499 -110299 21483 -157917 -79453 -148656 900000 -134023 98929 -95046 -27452 -39942 -20174 -15009 -46435 141199 -38397 123108 -68005 63227 7608 23631 46971 -72101 16821 -38222 64475 -22804 58949 1943 26419 5710 5303 39807 5238 32318 6141 33473 -102 31762 8265 12539 9503 456 20037 3260 21708 7324 15842 6613 4349 8931 -41 11927 -2795 12831 1204 13381 1351 5128 3247 4445 3154 -879 7564 -482 7036 -1539 3797 -2931 -3503 -1450 -4245 1711 -3871 997 -3638 -112 -2885 -824 787 219 1507 -1082 2054 -2075 1298 -2637 -2329 -892 -2391 836 -97 1104 -2225 477 -3362 -1177 -1746 -2142 -1042 -1725 357 -679 1604 156 1205 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