File name: Pandora153s1_ChelseaMA_20240919_L2Fit_fwvt1c6d20231012p1-8.txt File generation date: 20240920T044510.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora153_OF_v3d20200209.txt Instrument calibration file used: Pandora153s1_CF_v6d20231012.txt Level 1 file used: Pandora153s1_ChelseaMA_20240919_L1_smca1c6d20231012p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20240919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 5 First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.0301 492.1513 492.2725 492.3937 492.5149 492.6361 492.7573 492.8784 492.9995 493.1206 493.2417 493.3628 493.4838 493.6048 493.7259 493.8469 493.9678 494.0888 494.2098 494.3307 494.4516 494.5725 494.6934 494.8143 494.9351 495.0560 495.1768 495.2976 495.4184 495.5391 495.6599 495.7806 495.9013 496.0220 496.1427 496.2634 496.3840 496.5047 496.6253 496.7459 496.8665 496.9870 497.1076 497.2281 497.3486 497.4691 497.5896 497.7101 497.8305 497.9510 498.0714 498.1918 498.3122 498.4325 498.5529 498.6732 498.7935 498.9138 499.0341 499.1544 499.2746 499.3948 499.5151 499.6353 499.7554 499.8756 499.9957 500.1159 500.2360 500.3561 500.4762 500.5962 500.7163 500.8363 500.9563 501.0763 501.1963 501.3162 501.4362 501.5561 501.6760 501.7959 501.9158 502.0357 502.1555 502.2753 502.3951 502.5149 502.6347 502.7545 502.8742 502.9939 503.1136 503.2333 503.3530 503.4727 503.5923 503.7119 503.8315 503.9511 504.0707 504.1902 504.3098 504.4293 504.5488 504.6683 504.7878 504.9072 505.0267 505.1461 505.2655 505.3849 505.5042 505.6236 505.7429 505.8622 505.9815 506.1008 506.2201 506.3393 506.4586 506.5778 506.6970 506.8161 506.9353 507.0545 507.1736 507.2927 507.4118 507.5309 507.6499 507.7690 507.8880 508.0070 508.1260 508.2450 508.3639 508.4829 508.6018 508.7207 508.8396 508.9585 509.0773 509.1962 509.3150 509.4338 509.5526 509.6714 509.7901 509.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240919T112339.6Z 9028.474764 239 1 14.81 2 80.75 96.92 81.70 271.33 0.00 1 0.00 1 0 22 3.168e-03 3.150e-03 1.647e-03 1.644e-03 9.197067e+03 1.171749e+02 6.315912e+02 -6.000000e+00 1.863431e+02 286.13 -2.00 20.00 -2.00 505.28 0.00e+00 8.402250e-04 4.665792e-05 5.568406e-05 -6.000000e+00 9.140062e-05 286.13 -2.00 20.00 -2.00 500.41 0.00e+00 5.015540e-01 3.328225e-02 5.534226e-02 -6.000000e+00 6.430483e-02 228.62 -2.00 3.54 -2.00 502.01 0.00e+00 5.906 0.004 489.00 513.00 1 6.6645e+00 2.5595e-03 9.7888e-03 -6.0000e+00 4.9477e-03 -5.2160e-04 6.4368e-04 1.4586e-03 -6.0000e+00 1.2685e-03 1.0113e-03 4.0576e-03 1.7903e-04 6.4555e-05 -6.0000e+00 3.7163e-04 3.3915e-02 -2.9748e-04 12 1 1 12 1 1 -81.48 18.27 1.13 0.03391 0.06206 3 3 1 4 0 3700.560 21.58 14.99 18.27 22.11 0.0 952.46 -858 -523 -256 12 -28 417 735 591 316 455 133 168 -100 -308 -355 -409 -363 -123 102 -181 -37 11 168 -31 346 216 -63 -58 23 -256 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401 459 525 65 249 371 153 250 176 318 248 181 163 238 305 -135 -249 -125 -472 -219 45 190 -165 64 -75 -48 136 256 390 -23 139 65 -608 -400 -409 SQ 20240919T112433.7Z 9028.475390 241 1 21.86 2 80.58 97.07 81.86 271.48 0.00 1 0.00 1 0 22 3.096e-03 3.077e-03 1.035e-03 1.034e-03 8.862405e+03 7.352137e+01 5.867897e+02 -6.000000e+00 1.821200e+02 286.13 -2.00 20.00 -2.00 505.29 0.00e+00 8.172312e-04 2.933795e-05 6.092190e-05 -6.000000e+00 8.926928e-05 286.13 -2.00 20.00 -2.00 500.46 0.00e+00 4.753986e-01 2.093802e-02 5.939394e-02 -6.000000e+00 6.268961e-02 228.62 -2.00 3.54 -2.00 502.05 0.00e+00 5.813 0.004 489.00 513.00 1 6.2782e+00 1.6101e-03 9.8213e-03 -6.0000e+00 4.8261e-03 -3.2508e-03 4.0472e-04 1.4848e-03 -6.0000e+00 1.2329e-03 1.5127e-03 -8.9356e-04 1.1278e-04 5.6633e-05 -6.0000e+00 3.6328e-04 1.9369e-02 8.8069e-06 12 1 1 12 1 1 97.95 18.27 1.20 0.01937 0.01317 8 4 1 4 0 2427.800 21.58 15.00 18.27 22.11 0.0 952.56 -397 -539 -254 77 250 375 411 515 510 306 51 -1 -120 -292 -417 -533 -304 -172 24 5 -277 -25 15 223 385 206 27 120 -172 -257 -510 -186 -10 384 318 46 -28 223 251 228 12 138 203 354 404 322 301 251 265 -160 -582 -392 -699 -682 -407 -157 -125 -93 87 112 344 470 556 348 134 166 -46 -168 18 -199 -466 -306 -496 22 51 -265 -312 -248 -225 -326 -532 -391 -382 -347 -148 -187 -7 14 41 238 383 499 395 313 107 414 112 -119 -293 -668 -628 -518 -318 -111 -50 -301 -291 -241 -301 -79 108 79 202 227 501 187 634 399 433 187 38 62 234 433 530 238 126 77 11 25 37 -134 -111 -345 -213 10 245 21 -70 93 315 185 130 51 99 48 -207 -549 -360 -492 -382 -524 -253 76 255 391 423 536 530 316 52 -1 -123 -297 -422 -542 -313 -176 25 6 -288 -26 15 232 401 215 28 123 -178 -260 -509 -185 -10 398 329 49 -29 231 257 232 12 141 209 369 424 339 316 260 270 -160 -585 -385 -682 -670 -408 -156 -127 -96 90 116 355 486 575 360 138 169 -46 -166 17 -198 -463 -304 -485 21 50 -261 -304 -244 -219 -317 -519 -383 -367 -336 -145 -184 -7 14 40 235 380 499 387 306 106 399 108 -112 -271 -613 -577 -485 -300 -108 -49 -297 -287 -236 -293 -78 107 79 203 224 496 187 635 402 434 186 37 62 230 425 520 235 125 76 11 25 36 -129 -106 -328 -203 9 240 20 -69 93 318 184 130 51 99 48 -207 -543 -352 -480 SQ 20240919T112523.6Z 9028.475967 243 1 18.95 2 80.43 97.22 82.00 271.62 0.00 1 0.00 1 0 22 2.973e-03 2.951e-03 7.472e-04 7.461e-04 8.810127e+03 5.294015e+01 5.864720e+02 -6.000000e+00 1.748762e+02 286.13 -2.00 20.00 -2.00 505.29 0.00e+00 8.188650e-04 2.119019e-05 5.964361e-05 -6.000000e+00 8.573333e-05 286.13 -2.00 20.00 -2.00 500.46 0.00e+00 4.320731e-01 1.505957e-02 5.880908e-02 -6.000000e+00 6.023396e-02 228.62 -2.00 3.54 -2.00 502.05 0.00e+00 5.730 0.003 489.00 513.00 1 5.5970e+00 1.1581e-03 9.6966e-03 -6.0000e+00 4.6365e-03 -5.4161e-03 2.9135e-04 1.4739e-03 -6.0000e+00 1.1855e-03 3.0348e-03 3.2270e-04 8.1389e-05 5.6354e-05 -6.0000e+00 3.4890e-04 1.6597e-02 -2.5616e-05 12 1 1 12 1 1 82.39 18.27 1.17 0.01660 0.01884 14 8 1 4 0 1263.320 21.58 15.00 18.27 22.11 0.0 952.48 -596 -441 -97 90 -89 314 580 571 380 213 260 31 -280 -287 -337 -373 -350 -153 51 -108 -79 24 123 282 336 324 68 121 -126 -365 -392 -185 -7 288 398 82 -5 193 145 41 18 240 230 317 260 205 323 181 50 -245 -487 -566 -731 -494 -226 -59 -199 14 -59 204 345 539 266 331 291 95 143 -39 -14 -306 -162 -361 -390 -136 23 -62 -420 -375 -207 -370 -432 -277 -366 -248 -185 -192 -58 -151 103 -13 236 495 411 310 272 130 47 -60 -254 -529 -619 -585 -425 -68 90 -369 -306 -420 -157 97 56 86 118 421 348 443 546 475 269 239 123 129 198 387 358 257 312 122 143 297 18 -206 -62 -232 -398 -152 -75 -47 63 63 180 128 290 42 269 -73 -159 -299 -566 -516 -582 -435 -96 91 -91 325 596 593 396 220 266 32 -286 -291 -339 -377 -359 -156 53 -112 -82 25 128 294 352 338 71 125 -131 -370 -391 -185 -7 292 412 87 -5 200 149 42 18 246 239 332 268 213 332 189 51 -246 -489 -557 -714 -485 -226 -59 -203 15 -59 207 349 547 271 337 294 98 144 -39 -14 -299 -161 -351 -383 -135 23 -62 -411 -362 -202 -360 -422 -272 -354 -242 -182 -191 -57 -151 102 -13 230 488 407 306 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