File name: Pandora153s1_ChelseaMA_20241217_L2Fit_fout2c7d20240424p1-8.txt File generation date: 20241218T045309.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora153_OF_v3d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20241217_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20241217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0659 305.2069 305.3478 305.4887 305.6296 305.7706 305.9114 306.0523 306.1932 306.3341 306.4749 306.6157 306.7566 306.8974 307.0382 307.1790 307.3197 307.4605 307.6013 307.7420 307.8828 308.0235 308.1642 308.3049 308.4456 308.5863 308.7269 308.8676 309.0082 309.1489 309.2895 309.4301 309.5707 309.7113 309.8519 309.9924 310.1330 310.2735 310.4140 310.5546 310.6951 310.8356 310.9761 311.1165 311.2570 311.3975 311.5379 311.6783 311.8187 311.9591 312.0995 312.2399 312.3803 312.5207 312.6610 312.8014 312.9417 313.0820 313.2223 313.3626 313.5029 313.6431 313.7834 313.9237 314.0639 314.2041 314.3443 314.4845 314.6247 314.7649 314.9051 315.0452 315.1854 315.3255 315.4656 315.6057 315.7458 315.8859 316.0260 316.1661 316.3061 316.4462 316.5862 316.7262 316.8662 317.0062 317.1462 317.2862 317.4262 317.5661 317.7061 317.8460 317.9859 318.1258 318.2657 318.4056 318.5455 318.6853 318.8252 318.9650 319.1048 319.2446 319.3844 319.5242 319.6640 319.8038 319.9435 320.0833 320.2230 320.3628 320.5025 320.6422 320.7819 320.9215 321.0612 321.2009 321.3405 321.4801 321.6198 321.7594 321.8990 322.0385 322.1781 322.3177 322.4572 322.5968 322.7363 322.8758 323.0153 323.1548 323.2943 323.4338 323.5732 323.7127 323.8521 323.9915 324.1310 324.2704 324.4097 324.5491 324.6885 324.8279 324.9672 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241217T141100.1Z 9117.590973 280 1 10.95 2 74.27 144.62 87.73 302.53 0.00 1 0.00 1 0 25 5.602e-02 6.684e-03 3.665e-02 2.879e-03 4.380487e-01 1.422596e-03 5.120507e-03 -6.000000e+00 3.100306e-02 222.59 -2.00 3.54 -2.00 319.53 0.00e+00 7.461364e-04 3.914936e-04 4.419881e-04 -6.000000e+00 1.358731e-03 275.63 -2.00 20.00 -2.00 318.95 0.00e+00 3.625 0.001 302.00 328.00 3 2.4458e+00 3.9782e-03 4.2172e-02 -6.0000e+00 7.6326e-02 3.1803e-02 4.6874e-03 2.2322e-02 -6.0000e+00 8.3490e-02 -1.5978e-03 3.7900e-03 1.1312e-02 -6.0000e+00 4.9718e-02 -6.2766e-03 1.9998e-03 3.4278e-03 -6.0000e+00 2.1074e-02 7.6143e-04 1.2735e-06 8.1800e-05 3.6602e-05 -6.0000e+00 1.4825e-03 2.1911e-02 0.0000e+00 12 9 1 12 1 1 99.99 18.27 0.16 0.02191 0.02192 48 44 1 5 0 223.420 21.58 15.01 18.27 18.91 0.0 946.32 2893 -11318 -16778 -28837 -16559 -13983 -16842 -17730 -14540 -16694 -19135 -15867 -15733 -12697 -8606 -4146 595 -3085 3859 449 -1493 -3163 -7238 2828 -1944 -655 -3987 -2510 -3100 -4207 -137 838 3494 -1738 -4840 -5562 -4668 -4086 -112 1694 -366 861 -579 -58 -791 -504 -182 469 511 634 1169 2029 1063 452 608 2422 1294 887 643 5 469 1271 1934 2998 1143 -645 -1185 -674 620 488 1106 566 769 242 355 -754 -1499 -2354 -1105 -536 -1279 -728 -2161 -1927 -959 -117 329 795 991 770 825 126 -397 -355 -310 -146 259 1061 712 277 -816 -1362 -1485 -268 -1038 -830 -787 -803 59 480 857 283 208 -213 -498 -537 117 344 396 321 188 71 223 549 556 300 190 295 370 138 289 -446 -501 -319 253 -277 183 364 219 304 -406 -578 -331 54 -264 -429 -771 -367 -300 -405 -490 -434 -539 -645 -565 -668 -624 -481 -250 37 -213 264 33 -114 -245 -615 236 -181 -63 -397 -236 -283 -406 -14 98 444 -237 -639 -745 -695 -711 -23 392 -94 229 -162 -16 -226 -145 -52 135 149 193 384 718 406 184 257 1041 569 391 277 2 211 617 1021 1685 657 -358 -636 -366 366 324 778 414 551 167 226 -444 -832 -1318 -666 -367 -981 -609 -1934 -1801 -945 -121 350 862 1062 800 804 116 -350 -319 -300 -157 307 1350 945 361 -1019 -1584 -1654 -307 -1276 -1054 -1044 -1111 86 741 1393 468 337 -329 -731 -768 169 514 619 520 304 112 344 821 805 422 260 421 566 224 494 -786 -902 -597 493 -559 373 748 451 608 -788 -1086 -618 SS 20241217T143906.0Z 9117.610486 290 1 12.80 2 71.50 150.71 91.87 306.99 0.00 1 0.00 1 0 17 4.672e-02 7.768e-03 4.024e-02 4.737e-03 3.792358e-01 2.323947e-03 4.500567e-03 -6.000000e+00 2.585610e-02 222.60 -2.00 3.54 -2.00 319.04 0.00e+00 7.897226e-04 5.446889e-04 2.099288e-04 -6.000000e+00 1.133232e-03 275.63 -2.00 20.00 -2.00 318.44 0.00e+00 3.112 0.001 302.00 328.00 3 4.0079e+00 6.3583e-03 3.6295e-02 -6.0000e+00 6.3655e-02 4.2472e-02 7.3536e-03 1.9298e-02 -6.0000e+00 6.9632e-02 -2.5158e-03 5.4081e-03 9.6755e-03 -6.0000e+00 4.1465e-02 -4.0076e-03 2.8630e-03 2.8966e-03 -6.0000e+00 1.7574e-02 2.7776e-04 -2.2899e-04 1.3592e-04 3.0751e-05 -6.0000e+00 1.2365e-03 2.2753e-02 0.0000e+00 12 9 1 12 1 1 100.00 18.38 0.21 0.02275 0.02103 17 14 1 5 0 710.910 21.58 15.00 18.38 19.39 0.0 947.26 -4196 -30121 6137 -18450 -3248 2325 -11628 -10988 -12545 6373 -335 15372 -19182 2496 3544 2691 -971 -3617 3550 -3153 10176 -3256 4072 -7618 1373 5869 -3134 -572 -2619 4074 -189 5523 2298 -1192 -4639 -7460 -3510 -6131 959 -2667 613 -2382 1088 499 1308 632 -1434 994 -1887 348 -1375 716 -76 2151 1380 703 827 -191 1245 -463 3370 450 2803 2436 902 650 -636 -1147 -573 829 -190 1346 -54 1366 487 -1087 -913 -2048 -508 -1291 -267 -1527 -1557 -1495 -720 -519 -422 813 425 681 696 168 -596 -606 -400 22 916 890 599 -93 -672 -1605 -243 481 -904 -987 -873 -988 -273 1177 872 521 637 -474 -311 -388 -360 -503 332 169 169 -218 320 104 536 377 -20 1243 -186 643 38 -543 -455 -212 247 -110 674 88 333 116 -168 -588 -708 -143 -1429 215 -763 -107 72 -441 -469 -602 270 -15 652 -1302 164 268 229 -91 -367 356 -349 1016 -366 446 -995 176 750 -433 -73 -327 494 -26 816 384 -211 -794 -1316 -661 -1393 244 -809 197 -824 376 175 457 224 -514 348 -680 127 -548 303 -34 1008 672 353 423 -98 618 -232 1702 252 1681 1563 585 397 -376 -687 -371 595 -147 1062 -42 1017 340 -699 -547 -1228 -326 -943 -216 -1353 -1459 -1461 -740 -561 -475 925 483 742 710 162 -546 -559 -398 24 1087 1152 807 -123 -844 -1883 -272 557 -1127 -1278 -1177 -1388 -402 1822 1417 856 1021 -729 -450 -543 -509 -740 511 270 271 -343 491 154 766 521 -26 1709 -278 1012 62 -923 -787 -380 462 -212 1317 175 658 224 -316 -1072 -1283 SS 20241217T144056.6Z 9117.611766 292 1 50.32 2 71.33 151.12 92.14 307.29 0.00 1 0.00 1 0 17 1.126e-01 9.623e-03 1.265e-01 1.094e-02 3.785505e-01 5.402691e-03 4.427173e-03 -6.000000e+00 6.233434e-02 222.60 -2.00 3.54 -2.00 319.53 0.00e+00 -4.824111e-04 1.431502e-03 4.381335e-04 -6.000000e+00 2.730629e-03 275.63 -2.00 20.00 -2.00 318.93 0.00e+00 3.086 0.001 302.00 328.00 3 5.1570e+00 1.5091e-02 3.6070e-02 -6.0000e+00 1.5347e-01 2.4371e-02 1.7657e-02 1.9367e-02 -6.0000e+00 1.6782e-01 3.7306e-02 1.3601e-02 9.6689e-03 -6.0000e+00 9.9939e-02 -1.8555e-02 7.1654e-03 2.8303e-03 -6.0000e+00 4.2401e-02 9.0031e-05 3.4318e-04 3.2290e-04 3.1032e-05 -6.0000e+00 2.9783e-03 1.6406e-02 0.0000e+00 12 9 8 11 8 0 99.98 18.38 0.30 0.01641 0.01899 129 25 1 5 0 390.050 21.69 15.00 18.38 19.34 0.0 947.18 -17350 63433 -39993 40502 -45495 38091 31491 -24384 -140 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