File name: Pandora153s1_ChelseaMA_20250418_L2Fit_fwvt1c7d20240424p1-8.txt File generation date: 20250419T045208.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora153_OF_v3d20200209.txt Instrument calibration file used: Pandora153s1_CF_v7d20240424.txt Level 1 file used: Pandora153s1_ChelseaMA_20250418_L1_smca1c7d20240424p1-8.txt Full location name: Chelsea, Massachusetts Short location name: ChelseaMA Country of location: United States Location latitude [deg]: 42.3946 Location longitude [deg]: -71.0307 Location altitude [m]: 30 Local noon date: 20250418 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld of OoB session 6. First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.0264 492.1477 492.2689 492.3900 492.5112 492.6324 492.7535 492.8746 492.9957 493.1168 493.2379 493.3590 493.4800 493.6010 493.7220 493.8430 493.9640 494.0849 494.2059 494.3268 494.4477 494.5686 494.6895 494.8103 494.9311 495.0520 495.1728 495.2936 495.4143 495.5351 495.6558 495.7765 495.8972 496.0179 496.1386 496.2593 496.3799 496.5005 496.6211 496.7417 496.8623 496.9828 497.1034 497.2239 497.3444 497.4649 497.5853 497.7058 497.8262 497.9466 498.0671 498.1874 498.3078 498.4282 498.5485 498.6688 498.7891 498.9094 499.0297 499.1499 499.2701 499.3904 499.5106 499.6308 499.7509 499.8711 499.9912 500.1113 500.2314 500.3515 500.4716 500.5916 500.7116 500.8317 500.9517 501.0716 501.1916 501.3116 501.4315 501.5514 501.6713 501.7912 501.9110 502.0309 502.1507 502.2705 502.3903 502.5101 502.6299 502.7496 502.8693 502.9891 503.1087 503.2284 503.3481 503.4677 503.5874 503.7070 503.8266 503.9461 504.0657 504.1852 504.3048 504.4243 504.5438 504.6632 504.7827 504.9021 505.0216 505.1410 505.2604 505.3797 505.4991 505.6184 505.7377 505.8570 505.9763 506.0956 506.2149 506.3341 506.4533 506.5725 506.6917 506.8109 506.9300 507.0492 507.1683 507.2874 507.4065 507.5255 507.6446 507.7636 507.8826 508.0016 508.1206 508.2396 508.3585 508.4775 508.5964 508.7153 508.8341 508.9530 509.0718 509.1907 509.3095 509.4283 509.5471 509.6658 509.7846 509.9033 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20250418T101704.3Z 9239.428522 77 1 31.65 2 87.41 77.47 74.83 200.25 0.00 1 0.00 1 0 15 4.848e-03 4.812e-03 1.279e-03 1.276e-03 5.395670e+03 8.366158e+01 3.590325e+02 -6.000000e+00 2.780908e+02 279.53 -2.00 20.00 -2.00 505.38 0.00e+00 3.712489e-03 3.571665e-05 2.017798e-04 -6.000000e+00 1.374999e-04 279.53 -2.00 20.00 -2.00 500.84 0.00e+00 1.516123e+00 2.547308e-02 5.534649e-02 -6.000000e+00 9.862259e-02 228.65 -2.00 3.54 -2.00 502.38 0.00e+00 14.536 0.058 489.00 513.00 1 5.5482e+00 1.9529e-03 2.3394e-02 -6.0000e+00 7.5720e-03 -1.5591e-02 4.8975e-04 1.6484e-03 -6.0000e+00 1.9403e-03 8.1021e-04 3.1797e-04 1.4443e-04 9.0965e-05 -6.0000e+00 5.6867e-04 7.2415e-02 -3.2201e-04 12 8 8 10 0 0 33.99 17.07 1.78 0.07241 0.07462 8 2 1 4 0 3956.120 20.56 14.99 17.07 10.86 1.9 1024.21 -1040 -1025 -506 68 -134 431 882 730 590 547 -321 48 -360 -496 -555 -699 -309 -188 336 -144 35 233 160 582 499 625 415 370 -215 -590 -450 -432 -313 211 519 208 79 297 130 -52 179 108 413 414 420 655 499 347 118 -80 -878 -1016 -821 -828 -449 -263 68 112 237 311 741 723 641 673 303 337 -245 -159 -94 -439 -600 -402 -459 -206 87 -291 -413 -667 -516 -669 -583 -729 -285 -360 -352 -277 -319 -54 159 208 216 299 486 512 400 263 67 -402 -330 -755 -1102 -768 -538 -8 20 -415 -284 -492 -474 -307 -115 175 610 763 753 652 922 1034 646 542 228 179 194 502 341 286 316 262 420 358 212 -130 -307 -628 -676 -161 -218 -346 -18 51 226 380 361 265 221 118 -408 -569 -1063 -632 -932 -931 -470 65 -132 415 861 720 583 536 -313 46 -343 -468 -522 -662 -296 -184 333 -145 35 236 164 595 494 620 411 377 -215 -581 -436 -420 -310 207 517 210 80 298 129 -52 178 109 419 426 437 683 519 357 120 -79 -862 -980 -785 -801 -442 -266 70 112 239 314 747 732 652 684 307 337 -243 -162 -95 -438 -597 -399 -460 -201 85 -283 -413 -659 -505 -654 -571 -719 -272 -347 -343 -271 -312 -52 155 204 213 298 489 517 400 258 64 -380 -316 -718 -1051 -716 -515 -8 20 -421 -286 -495 -476 -300 -114 176 618 781 777 679 965 1084 677 562 235 182 197 510 349 294 326 271 433 368 217 -132 -310 -631 -684 -164 -219 -355 -18 53 238 404 386 284 237 125 -429 -590 -1095 -649 SO 20250418T101856.8Z 9239.429824 80 1 32.79 2 87.07 77.78 74.95 200.64 0.00 1 0.00 1 0 15 4.687e-03 4.661e-03 1.134e-03 1.133e-03 5.098265e+03 7.400414e+01 3.415763e+02 -6.000000e+00 2.688808e+02 279.53 -2.00 20.00 -2.00 505.34 0.00e+00 3.280643e-03 3.168121e-05 1.785256e-04 -6.000000e+00 1.329374e-04 279.53 -2.00 20.00 -2.00 500.72 0.00e+00 1.470155e+00 2.267686e-02 5.056419e-02 -6.000000e+00 9.532157e-02 228.65 -2.00 3.54 -2.00 502.27 0.00e+00 13.712 0.049 489.00 513.00 1 5.4510e+00 1.7398e-03 2.1687e-02 -6.0000e+00 7.3192e-03 -1.3402e-02 4.3619e-04 1.5299e-03 -6.0000e+00 1.8743e-03 1.0140e-03 7.9046e-04 1.2849e-04 8.2541e-05 -6.0000e+00 5.4968e-04 1.0184e-02 8.6091e-05 12 8 8 10 0 0 4.51 17.07 1.58 0.01018 0.01567 10 2 1 4 0 3278.540 20.56 15.00 17.07 11.01 1.9 1024.65 -920 -703 -191 -50 -41 426 568 822 752 423 19 43 -171 -549 -870 -599 -617 -126 72 146 -124 162 124 320 580 560 164 435 -99 -622 -518 -367 -207 260 483 207 243 171 324 -52 112 166 176 524 473 573 565 374 111 -392 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351 164 -225 -218 -378 -422 -365 -202 -276 -208 109 268 369 323 221 309 126 -426 -735 -625 -716 SO 20250418T102045.7Z 9239.431084 83 1 33.20 2 86.74 78.08 75.07 201.03 0.00 1 0.00 1 0 22 4.235e-03 4.201e-03 1.019e-03 1.017e-03 4.767671e+03 6.657052e+01 3.229191e+02 -6.000000e+00 2.429503e+02 279.53 -2.00 20.00 -2.00 505.37 0.00e+00 2.865646e-03 2.860305e-05 1.552086e-04 -6.000000e+00 1.201400e-04 279.53 -2.00 20.00 -2.00 500.73 0.00e+00 1.390490e+00 2.045380e-02 4.602539e-02 -6.000000e+00 8.618971e-02 228.65 -2.00 3.54 -2.00 502.30 0.00e+00 12.964 0.041 489.00 513.00 1 5.3566e+00 1.5692e-03 2.0198e-02 -6.0000e+00 6.6171e-03 -1.0861e-02 3.9295e-04 1.4240e-03 -6.0000e+00 1.6962e-03 1.2549e-03 1.5562e-03 1.1541e-04 7.2499e-05 -6.0000e+00 4.9680e-04 2.9955e-02 -9.1000e-05 11 8 0 10 0 0 -50.78 17.08 1.51 0.02996 0.04075 12 2 1 4 0 2765.890 20.56 15.01 17.08 11.13 1.9 1024.99 -1082 -683 -409 -38 25 568 602 500 396 447 82 110 -36 -539 -493 -661 -445 -212 303 -21 -48 93 230 269 440 301 174 281 -68 -512 -443 -149 -141 407 241 234 85 276 187 -7 208 153 197 444 616 495 439 199 71 -238 -593 -878 -869 -749 -158 -238 -36 180 220 37 484 681 743 640 361 210 -142 -87 -157 -253 -526 -440 -256 -30 -30 -445 -518 -486 -575 -482 -736 -574 -696 -289 -274 -259 -337 -158 129 212 -34 302 617 544 593 147 43 -185 -520 -781 -874 -691 -493 -34 -172 -183 -357 -481 -117 -229 152 83 365 368 745 712 860 756 542 563 292 184 36 498 252 236 424 122 196 363 86 -276 -64 -495 -307 -369 -39 -142 -161 215 -21 160 286 342 213 36 -253 -842 -596 -622 -1003 -639 -392 -36 24 563 607 510 404 452 82 109 -36 -524 -477 -645 -439 -213 297 -21 -48 94 232 273 448 308 178 283 -67 -497 -440 -142 -138 407 247 242 88 283 190 -7 211 157 205 448 626 505 447 201 73 -241 -588 -857 -842 -732 -157 -235 -36 183 224 38 493 695 760 655 368 212 -142 -85 -153 -245 -507 -424 -248 -29 -30 -437 -503 -465 -546 -456 -701 -549 -672 -280 -268 -255 -333 -156 127 209 -34 304 626 553 596 146 42 -176 -487 -723 -810 -650 -477 -34 -168 -180 -350 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