File name: Pandora249s1_ChicagoIL_20230523_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T070849.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v1d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20230523_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230523T113355.8Z 8543.481896 76 1 53.67 2 78.84 72.28 103.13 34.11 0.00 1 0.00 1 0 25 4.112e-01 2.478e-02 1.853e-01 6.209e-03 6.718143e-01 3.504437e-03 7.825234e-03 -6.000000e+00 2.527699e-01 231.43 -2.00 3.53 -2.00 321.07 0.00e+00 6.323309e-03 1.584210e-03 2.087409e-03 -6.000000e+00 1.172123e-02 282.73 -2.00 20.00 -2.00 320.50 0.00e+00 4.986 0.002 302.00 328.00 3 3.9336e+00 1.1602e-02 6.1165e-02 -6.0000e+00 6.3461e-01 3.7648e-01 1.4996e-02 3.7154e-02 -6.0000e+00 6.8676e-01 -4.9359e-01 1.3467e-02 2.0870e-02 -6.0000e+00 4.0659e-01 2.0372e-01 6.4813e-03 8.4303e-03 -6.0000e+00 1.6924e-01 3.5694e-05 -6.9656e-04 1.8740e-04 1.2391e-04 -6.0000e+00 1.2647e-02 6.6270e-03 0.0000e+00 12 8 8 10 0 0 45.17 25.88 0.93 0.00663 0.00139 22 2 1 5 0 2439.460 33.00 20.00 25.88 22.87 9.3 961.86 -143832 24781 -126184 -26070 -132808 900000 -164870 -124552 -39700 -34300 900000 -158877 -90268 900000 -52823 -34334 -16828 900000 1998 900000 -2914 -11612 -71849 -43956 29846 -104952 14589 51967 -43040 190770 43249 68116 -24740 -14774 6964 -30821 3102 -20220 17496 -1149 48954 15562 23834 34495 28329 17910 6507 -2735 31127 1404 13426 57933 18741 -1379 6836 24230 7155 15137 7565 9188 -8647 12247 20093 1414 11469 11380 6690 4389 -43 4361 860 3227 12685 -2606 -762 8243 -5935 1190 -24176 -5512 -1752 -2797 991 -524 3286 790 1472 -41 348 1581 -2101 1316 -937 1203 522 -4824 -2336 -919 1231 -2211 -1390 -2420 212 -4954 -681 -1756 -817 -1376 -1679 260 -795 1853 -486 -410 -357 -134 2488 1616 -1464 116 -946 45 1123 820 573 2430 3350 1915 181 -86 616 76 2390 2070 -909 -35 -389 -850 -582 -220 -1067 -815 53 -3243 150 -3053 -229 -3140 900000 -4987 -2671 -393 -340 900000 -6203 -2135 900000 -1365 -887 -416 900000 48 900000 -79 -338 -3833 -2021 686 -8715 406 974 -2057 1154 1046 1525 -1616 -947 358 -2256 169 -1578 1111 -104 3021 1450 2148 2880 2553 1820 756 -357 3013 194 1787 5467 2868 -279 1348 4163 1489 2903 1528 1790 -2045 2526 4290 407 3205 3208 1947 1327 -15 1593 361 1400 5026 -1151 -305 2723 -2082 384 -10866 -2388 -857 -1587 601 -347 2228 584 1036 -31 258 1243 -1620 918 -638 807 384 -3894 -2134 -949 1375 -2638 -1584 -2557 200 -4757 -654 -1809 -883 -1598 -2128 359 -1233 2757 -758 -627 -569 -205 3652 2468 -2429 182 -1508 75 1798 1269 855 3426 4541 2676 282 -151 1089 145 4731 4349 -2092 -84 -899 -2001 -1369 -503 -2521 -1807 112 SS 20230523T114005.4Z 8543.486174 79 1 54.03 2 77.75 73.23 102.51 35.30 0.00 1 0.00 1 0 25 3.068e-01 1.002e-02 2.451e-01 3.212e-03 6.371206e-01 1.795744e-03 7.224445e-03 -6.000000e+00 1.874945e-01 231.43 -2.00 3.53 -2.00 320.68 0.00e+00 1.431061e-03 7.482933e-04 4.993090e-04 -6.000000e+00 8.605347e-03 282.74 -2.00 20.00 -2.00 320.09 0.00e+00 4.574 0.002 302.00 328.00 3 3.5232e+00 5.6525e-03 5.6623e-02 -6.0000e+00 4.7023e-01 5.7691e-02 7.4502e-03 3.5050e-02 -6.0000e+00 5.0779e-01 -6.1369e-02 7.3915e-03 1.7866e-02 -6.0000e+00 3.0079e-01 1.5774e-02 3.6258e-03 6.0457e-03 -6.0000e+00 1.2697e-01 8.7461e-05 -2.4691e-04 9.6448e-05 6.7116e-05 -6.0000e+00 9.6468e-03 6.0510e-03 0.0000e+00 12 8 8 10 0 0 53.98 25.91 0.75 0.00605 0.00420 43 4 1 5 0 1256.420 33.00 20.01 25.91 23.25 9.2 964.25 -40577 900000 -98513 900000 900000 20239 -109316 -93320 900000 16670 -6202 -1373 18039 124630 -94648 62254 -12724 157464 126254 27729 55757 3122 -26898 -7468 36799 -84740 21834 12751 -20604 31402 52938 34363 -19825 -17314 -11862 -22135 9836 -10970 621 3664 13517 1 -1609 2069 -776 -2170 -288 -4314 8007 -7931 7034 20648 -1949 1253 -30 4824 -391 1675 392 522 -3622 2707 6614 -2221 2895 5589 197 29 2416 -306 -561 949 3898 -1863 -873 1174 -2542 444 -9101 -1706 -1009 -2412 -2119 -172 1617 92 568 1043 460 451 124 1373 746 809 1654 -1275 -588 324 118 -379 -28 -942 322 -1841 -271 -1267 -429 -435 74 -138 -140 168 293 -224 215 140 619 658 -743 164 -444 -171 141 -476 371 218 1064 560 281 476 489 -432 410 780 -466 70 -60 -391 -126 -125 -417 -179 363 -127 900000 -673 900000 900000 63 -840 -690 900000 52 -29 -7 90 390 -2340 390 -195 493 593 373 593 58 -699 -173 599 -4986 458 291 -651 619 961 893 -1030 -965 -635 -1309 453 -724 45 307 1185 0 -191 246 -97 -280 -37 -601 1030 -1276 1070 3063 -401 273 -7 1146 -101 430 101 132 -972 734 1931 -792 1053 1994 73 11 966 -129 -265 470 1895 -923 -398 523 -1086 181 -4004 -806 -554 -1539 -1498 -128 1266 78 464 879 393 376 107 1094 570 620 1363 -1129 -596 372 138 -457 -35 -1093 339 -1926 -292 -1465 -519 -519 95 -197 -220 262 464 -350 343 213 926 1014 -1222 260 -714 -268 228 -750 556 315 1477 793 434 762 864 -827 822 1538 -990 156 -138 -867 -280 -289 -916 -372 720 SS 20230523T114534.7Z 8543.489985 82 1 54.16 2 76.77 74.09 101.94 36.35 0.00 1 0.00 1 0 25 2.649e-01 8.231e-03 5.731e-02 2.027e-03 5.981249e-01 1.104372e-03 6.877037e-03 -6.000000e+00 1.610478e-01 231.43 -2.00 3.53 -2.00 320.19 0.00e+00 1.044403e-03 3.935109e-04 3.556944e-04 -6.000000e+00 7.027248e-03 282.74 -2.00 20.00 -2.00 319.58 0.00e+00 4.259 0.001 302.00 328.00 3 3.1299e+00 3.2974e-03 5.2702e-02 -6.0000e+00 4.0331e-01 6.8812e-02 4.0709e-03 3.2226e-02 -6.0000e+00 4.3512e-01 -9.2643e-02 3.6372e-03 1.6113e-02 -6.0000e+00 2.5867e-01 3.2346e-02 1.8382e-03 4.9555e-03 -6.0000e+00 1.0841e-01 1.8155e-04 -1.7272e-04 6.0251e-05 6.1505e-05 -6.0000e+00 8.0816e-03 6.2973e-03 0.0000e+00 11 8 0 10 0 0 28.57 25.93 0.57 0.00630 0.00500 74 7 1 5 0 731.790 33.00 20.01 25.93 23.57 9.3 966.89 -130071 -39189 -89731 -81274 -69824 -119285 -99988 -103903 -14811 -18294 -79362 -28316 -59658 -37353 -57265 -28242 -23695 21343 -3681 -13412 -4724 2179 -26317 -19803 -4400 -40178 1247 -4374 -18126 -14092 15300 5798 -18949 -9485 -6607 -12440 -1513 -4802 -1942 233 4922 1653 -1933 4388 1342 2860 -1678 -548 3846 -1253 2839 7149 2361 1595 2490 1380 1834 607 686 1565 740 2786 4260 1764 1837 3821 1532 2103 1310 552 -226 285 1399 -333 -492 175 -1061 -93 -4566 -1204 -1356 -1422 -1484 -1623 -153 -477 -927 88 353 -381 753 1181 50 800 1036 -421 -21 44 17 -249 -399 -747 -10 -474 -630 -932 -481 -388 -533 64 -36 48 210 -7 -78 410 695 642 -417 -162 -298 -120 63 278 406 397 878 797 826 286 89 -159 388 551 -103 -125 131 -231 -181 -352 -302 -300 -108 -1894 -275 -1145 -964 -703 -2099 -1522 -1849 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