File name: Pandora249s1_ChicagoIL_20230525_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T070839.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v1d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20230525_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230525T121925.7Z 8545.513491 109 1 54.51 2 70.45 78.99 112.32 24.97 0.00 1 0.00 1 0 25 3.994e-02 5.646e-03 7.278e-03 8.819e-04 4.469894e-01 4.687157e-04 5.260503e-03 -6.000000e+00 2.429378e-02 231.56 -2.00 3.53 -2.00 318.54 0.00e+00 7.437328e-04 9.719429e-05 1.586818e-04 -6.000000e+00 1.060677e-03 282.94 -2.00 20.00 -2.00 317.82 0.00e+00 2.954 0.000 302.00 328.00 3 3.0877e+00 1.2791e-03 3.7529e-02 -6.0000e+00 6.0853e-02 3.6457e-02 1.4537e-03 2.3614e-02 -6.0000e+00 6.5649e-02 -2.9498e-02 9.9658e-04 1.1508e-02 -6.0000e+00 3.9027e-02 8.4675e-03 5.1864e-04 3.3172e-03 -6.0000e+00 1.6352e-02 7.5418e-04 -1.4700e-04 2.6720e-05 3.9358e-05 -6.0000e+00 1.2189e-03 7.8452e-03 0.0000e+00 10 0 0 10 0 0 99.82 25.00 0.30 0.00785 0.00674 164 17 1 5 0 332.320 32.25 20.03 25.00 15.78 9.1 914.16 -21103 -10732 -8955 -9921 -12536 -15774 -18300 -9028 -5913 -8838 -10957 -7970 -8660 -2785 -9253 -920 -2723 964 357 -794 1492 1426 -2116 -2323 -1098 -5347 -752 -2508 -2920 -3063 770 341 -1323 -814 -1578 -3044 -1532 -1229 -176 -1050 -123 -189 -39 641 -9 100 230 -329 1020 56 846 1804 1058 1253 1003 973 1117 622 561 974 764 1878 1703 1021 544 894 221 177 387 605 163 -136 -58 -325 -179 -112 -268 40 -947 -657 -953 -1139 -1701 -1639 -875 -775 -659 -191 -283 194 405 717 491 877 852 500 462 334 -159 -345 -402 -595 3 44 -531 -750 -783 -521 -469 3 21 -125 -79 -48 150 480 730 510 232 -142 -346 -17 38 91 314 449 755 1152 800 437 258 43 135 316 -11 -147 -9 -144 -416 -332 -206 -347 -278 -713 -379 -334 -372 -453 -563 -694 -347 -248 -416 -553 -417 -522 -190 -804 -85 -285 105 42 -99 188 183 -288 -337 -153 -823 -113 -374 -465 -491 128 59 -258 -169 -329 -634 -333 -307 -52 -342 -45 -75 -16 270 -3 40 92 -133 410 23 374 862 552 649 550 555 652 368 327 559 448 1161 1081 711 398 638 152 121 277 453 136 -113 -49 -266 -146 -83 -193 28 -689 -502 -787 -1061 -1648 -1693 -904 -854 -730 -218 -326 217 449 733 497 862 882 547 542 419 -208 -460 -538 -737 4 53 -667 -958 -1053 -705 -676 4 33 -201 -126 -74 225 678 1056 727 349 -218 -542 -26 57 137 452 645 1039 1578 1170 671 410 69 225 551 -20 -266 -17 -275 -772 -626 -373 -622 -482 SS 20230525T122908.0Z 8545.520232 112 1 26.50 2 68.67 80.49 111.58 27.16 0.00 1 0.00 1 0 17 3.698e-02 5.659e-03 1.350e-02 1.895e-03 4.137439e-01 1.003281e-03 4.889329e-03 -6.000000e+00 2.248980e-02 231.56 -2.00 3.53 -2.00 318.38 0.00e+00 2.127434e-04 1.995697e-04 1.400376e-04 -6.000000e+00 9.820400e-04 282.94 -2.00 20.00 -2.00 317.66 0.00e+00 2.724 0.000 302.00 328.00 3 3.9729e+00 2.7291e-03 3.4656e-02 -6.0000e+00 5.6334e-02 4.5724e-02 3.0964e-03 2.1842e-02 -6.0000e+00 6.0777e-02 -1.9531e-02 2.0732e-03 1.0642e-02 -6.0000e+00 3.6130e-02 3.8410e-03 1.0704e-03 2.9581e-03 -6.0000e+00 1.5136e-02 4.0075e-04 -1.4280e-04 5.8056e-05 3.5696e-05 -6.0000e+00 1.1286e-03 8.9150e-03 0.0000e+00 12 1 1 12 1 1 99.95 25.03 0.40 0.00891 0.00784 29 7 1 5 0 826.550 32.25 19.92 25.03 16.37 9.1 917.85 -20608 -6649 -12757 -7640 -16038 -7397 -14278 -15346 -2741 -1479 -8772 -8927 -4543 -3693 -6514 -777 -3118 1162 430 791 2294 2595 -4447 -1853 1522 -5667 375 -1798 -2928 1893 2224 2405 -2580 285 629 -2090 -2730 -1765 34 -491 -406 -45 -1038 -87 -565 497 52 -738 1289 -361 1483 2161 1308 332 255 1229 1147 760 636 1002 879 1342 1592 938 609 402 155 334 416 253 -565 202 274 -413 -490 390 -231 -302 -1090 -825 -890 -1127 -1616 -1040 -704 -889 -391 -114 135 162 75 658 403 947 657 418 495 52 67 -231 -539 -637 -151 -163 -605 -844 -438 -469 19 -21 58 -390 33 -103 274 552 610 481 -21 -184 -271 -98 131 -68 179 359 776 1366 820 266 312 -174 257 413 -153 125 5 -140 -309 -188 -468 -391 -287 -845 -273 -594 -335 -714 -288 -617 -746 -132 -77 -511 -551 -304 -290 -622 -80 -364 139 55 106 313 358 -675 -291 247 -1044 66 -316 -499 307 384 463 -526 60 131 -441 -613 -452 10 -176 -151 -18 -437 -37 -244 213 23 -320 551 -161 688 1080 712 180 146 721 691 462 382 592 529 856 1109 662 448 288 106 225 295 200 -464 175 240 -352 -392 301 -164 -220 -773 -652 -748 -1067 -1573 -1071 -769 -978 -453 -137 163 191 83 710 406 923 673 446 594 66 88 -306 -726 -794 -184 -197 -733 -1092 -593 -635 27 -31 90 -611 51 -161 398 793 858 697 -30 -284 -429 -153 198 -100 263 504 1098 1915 1161 390 493 -277 420 703 -263 226 9 -258 -572 -342 -855 -683 -508 SS 20230525T125509.8Z 8545.538308 127 1 54.40 2 63.87 84.57 109.31 32.85 0.00 1 0.00 1 0 17 1.108e-02 5.354e-03 2.855e-03 7.396e-04 3.448093e-01 3.930543e-04 4.124343e-03 -6.000000e+00 6.741849e-03 231.56 -2.00 3.53 -2.00 317.48 0.00e+00 1.303677e-04 5.973556e-05 9.537766e-05 -6.000000e+00 2.943253e-04 282.94 -2.00 20.00 -2.00 316.75 0.00e+00 2.257 0.000 302.00 328.00 3 3.5296e+00 1.0470e-03 2.8776e-02 -6.0000e+00 1.6888e-02 2.5634e-02 1.1722e-03 1.8140e-02 -6.0000e+00 1.8218e-02 -1.3506e-02 7.1406e-04 8.8222e-03 -6.0000e+00 1.0830e-02 2.6076e-03 3.5247e-04 2.4369e-03 -6.0000e+00 4.5383e-03 1.0796e-03 6.7178e-05 2.2807e-05 3.1090e-05 -6.0000e+00 3.3822e-04 7.0506e-03 0.0000e+00 10 0 0 10 0 0 100.00 25.13 0.36 0.00705 0.00756 294 30 1 5 0 185.000 32.25 20.03 25.13 16.60 9.1 919.67 -1109 -1977 -2308 -1571 -2543 -6518 -4035 -2759 598 -1006 -3889 -1153 -1301 -1604 -2241 -719 -697 223 1424 -1102 1247 1223 312 -167 513 -639 289 -825 -240 67 801 990 -115 -826 -1212 -1946 -924 -965 -336 -513 -834 -797 -381 -305 -473 -113 -296 -271 -230 48 637 1071 1081 790 979 901 693 459 615 667 834 1356 1370 784 348 244 358 48 506 519 -4 -90 -235 -168 -125 -214 93 230 -386 -465 -769 -1219 -1532 -1524 -914 -742 -663 -246 -217 107 342 392 579 968 1076 773 537 294 -21 -274 -403 -508 -173 191 -494 -806 -630 -485 -332 46 0 -318 -296 -17 79 453 663 639 261 -95 -411 -132 -125 52 464 393 845 1209 871 434 351 33 87 245 -23 -14 17 -103 -319 -381 -229 -351 -411 -84 -170 -211 -140 -212 -535 -332 -247 58 -107 -440 -132 -166 -238 -353 -126 -133 44 295 -244 278 275 72 -41 133 -175 80 -223 -61 17 209 282 -36 -253 -368 -582 -289 -346 -143 -237 -434 -413 -205 -167 -260 -62 -162 -147 -123 26 360 648 701 509 660 626 494 329 435 467 593 1018 1048 649 297 201 278 37 399 427 -4 -82 -219 -161 -112 -186 73 183 -297 -395 -698 -1171 -1605 -1606 -1018 -838 -792 -304 -257 130 389 433 622 998 1147 859 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