File name: Pandora249s1_ChicagoIL_20230801_L2Fit_fwvt1c2d20230104p1-8.txt File generation date: 20230803T205509.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20230801_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0095 492.1302 492.2510 492.3717 492.4924 492.6131 492.7337 492.8544 492.9750 493.0956 493.2162 493.3368 493.4574 493.5779 493.6985 493.8190 493.9395 494.0600 494.1805 494.3009 494.4213 494.5418 494.6622 494.7825 494.9029 495.0233 495.1436 495.2639 495.3842 495.5045 495.6248 495.7450 495.8652 495.9855 496.1057 496.2258 496.3460 496.4662 496.5863 496.7064 496.8265 496.9466 497.0667 497.1867 497.3067 497.4268 497.5468 497.6667 497.7867 497.9066 498.0266 498.1465 498.2664 498.3863 498.5061 498.6260 498.7458 498.8656 498.9854 499.1052 499.2250 499.3447 499.4644 499.5841 499.7038 499.8235 499.9432 500.0628 500.1824 500.3021 500.4216 500.5412 500.6608 500.7803 500.8998 501.0194 501.1388 501.2583 501.3778 501.4972 501.6166 501.7361 501.8554 501.9748 502.0942 502.2135 502.3328 502.4521 502.5714 502.6907 502.8099 502.9292 503.0484 503.1676 503.2868 503.4060 503.5251 503.6442 503.7634 503.8825 504.0015 504.1206 504.2397 504.3587 504.4777 504.5967 504.7157 504.8347 504.9536 505.0725 505.1914 505.3103 505.4292 505.5481 505.6669 505.7857 505.9046 506.0233 506.1421 506.2609 506.3796 506.4983 506.6171 506.7357 506.8544 506.9731 507.0917 507.2103 507.3289 507.4475 507.5661 507.6846 507.8032 507.9217 508.0402 508.1587 508.2772 508.3956 508.5140 508.6325 508.7508 508.8692 508.9876 509.1059 509.2243 509.3426 509.4609 509.5792 509.6974 509.8157 509.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230801T122652.1Z 8613.518659 236 1 7.40 2 72.68 81.10 113.60 257.79 0.00 1 0.00 1 0 15 2.451e-03 2.439e-03 1.272e-04 1.271e-04 5.085156e+03 8.402779e+00 3.415537e+02 -6.000000e+00 1.437272e+02 288.27 -2.00 20.00 -2.00 505.33 0.00e+00 1.478617e-03 3.598906e-06 8.663014e-05 -6.000000e+00 7.050115e-05 288.27 -2.00 20.00 -2.00 500.69 0.00e+00 2.032600e-01 2.517121e-03 3.850526e-02 -6.000000e+00 4.921780e-02 232.27 -2.00 3.53 -2.00 502.26 0.00e+00 3.309 0.001 489.00 513.00 1 1.9941e+00 1.9371e-04 6.0073e-03 -6.0000e+00 3.7914e-03 -3.3800e-02 4.8633e-05 9.0424e-04 -6.0000e+00 9.6557e-04 1.6100e-01 1.4531e-03 1.3859e-05 4.6653e-05 -6.0000e+00 2.7713e-04 -3.8273e-03 2.9700e-04 10 0 0 10 0 0 69.42 26.76 1.37 -0.00383 0.00625 502 51 1 4 0 14.730 33.50 20.00 26.76 28.74 9.5 996.84 -444 -305 -112 32 120 389 505 416 412 271 147 23 -135 -122 -175 -228 -187 17 115 73 127 191 152 237 278 228 76 53 -86 -221 -283 -298 -242 88 99 4 38 101 41 -39 -6 7 72 221 265 280 268 108 -29 -223 -360 -438 -538 -522 -342 -191 -86 -11 80 185 248 292 236 229 240 144 34 -68 -110 -196 -168 -191 -231 -121 -7 -105 -252 -348 -325 -387 -395 -380 -420 -269 -144 -167 -194 -129 -89 -69 -22 93 196 217 221 157 -12 -181 -219 -357 -490 -470 -365 -139 -115 -209 -179 -163 -157 -113 -12 6 154 270 361 414 484 510 381 281 260 218 182 322 276 199 280 286 177 238 161 -10 -61 -100 -213 -70 62 -5 22 218 223 191 178 191 77 -50 -126 -298 -364 -405 -384 -422 -289 -108 31 119 389 512 420 417 275 147 23 -134 -119 -171 -223 -186 17 116 74 129 194 156 242 285 234 77 53 -87 -220 -277 -292 -241 88 102 4 38 103 41 -40 -7 7 73 226 273 286 276 110 -29 -222 -355 -427 -521 -508 -336 -190 -86 -11 82 188 253 295 240 232 242 146 34 -68 -109 -193 -164 -187 -226 -119 -7 -104 -247 -341 -316 -375 -383 -370 -413 -263 -142 -165 -192 -128 -89 -69 -22 93 198 220 222 156 -12 -175 -210 -341 -467 -448 -353 -137 -115 -209 -179 -163 -157 -113 -11 6 155 275 370 422 497 524 391 285 263 218 183 323 279 199 280 286 177 238 162 -10 -61 -99 -210 -69 61 -5 22 222 226 196 184 198 79 -51 -128 -302 -366 -406 -387 SQ 20230801T122659.6Z 8613.518745 236 2 7.40 2 72.65 81.12 113.62 257.81 0.00 1 0.00 1 0 15 2.404e-03 2.391e-03 1.354e-04 1.353e-04 5.100508e+03 8.939924e+00 3.423179e+02 -6.000000e+00 1.410002e+02 288.27 -2.00 20.00 -2.00 505.33 0.00e+00 1.466748e-03 3.829645e-06 8.624668e-05 -6.000000e+00 6.916413e-05 288.27 -2.00 20.00 -2.00 500.69 0.00e+00 2.002849e-01 2.680095e-03 3.858077e-02 -6.000000e+00 4.828554e-02 232.27 -2.00 3.53 -2.00 502.25 0.00e+00 3.305 0.001 489.00 513.00 1 2.1201e+00 2.0619e-04 6.0025e-03 -6.0000e+00 3.7195e-03 -3.3527e-02 5.1813e-05 9.0587e-04 -6.0000e+00 9.4731e-04 1.4208e-01 1.5190e-03 1.4752e-05 4.6839e-05 -6.0000e+00 2.7187e-04 -3.7289e-03 2.9402e-04 10 0 0 10 0 0 66.07 26.76 1.37 -0.00373 0.00681 502 51 1 4 0 14.730 33.50 20.00 26.76 28.74 9.5 996.84 -412 -269 -100 44 125 386 525 407 384 325 135 -3 -123 -141 -147 -251 -208 18 121 73 91 171 153 231 278 224 88 64 -82 -226 -257 -270 -230 91 97 1 43 100 33 -43 -3 28 87 171 248 240 243 126 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-32 -110 -198 -86 105 4 60 211 214 198 209 194 77 -63 -140 -287 -394 -403 -366 SQ 20230801T122707.1Z 8613.518832 236 3 7.40 2 72.63 81.14 113.64 257.83 0.00 1 0.00 1 0 15 2.338e-03 2.328e-03 1.534e-04 1.533e-04 5.128539e+03 1.013558e+01 3.453741e+02 -6.000000e+00 1.371382e+02 288.27 -2.00 20.00 -2.00 505.32 0.00e+00 1.464389e-03 4.342751e-06 8.579803e-05 -6.000000e+00 6.727006e-05 288.27 -2.00 20.00 -2.00 500.69 0.00e+00 2.107232e-01 3.037714e-03 3.853034e-02 -6.000000e+00 4.696400e-02 232.27 -2.00 3.53 -2.00 502.25 0.00e+00 3.301 0.001 489.00 513.00 1 2.3698e+00 2.3376e-04 5.9949e-03 -6.0000e+00 3.6177e-03 -3.3361e-02 5.8712e-05 9.0763e-04 -6.0000e+00 9.2141e-04 1.1065e-01 1.5190e-03 1.6705e-05 4.7214e-05 -6.0000e+00 2.6443e-04 -2.4763e-03 2.8482e-04 10 0 0 10 0 0 84.35 26.76 1.36 -0.00248 0.00806 502 51 1 4 0 14.730 33.50 20.00 26.76 28.74 9.5 996.84 -384 -309 -107 49 117 383 480 384 363 242 132 6 -126 -98 -185 -213 -193 18 108 46 96 155 151 246 317 221 113 64 -48 -190 -205 -251 -145 114 83 -7 22 93 9 -78 2 10 97 159 242 238 225 94 -20 -227 -339 -426 -530 -495 -326 -185 -116 -15 52 163 263 281 230 189 220 125 21 -47 -120 -176 -149 -170 -201 -96 16 -89 -283 -311 -314 -332 -359 -360 -406 -257 -158 -184 -200 -149 -76 -108 -33 92 209 206 207 137 -18 -176 -204 -321 -467 -475 -400 -130 -125 -232 -156 -167 -125 -82 -35 22 137 274 370 402 441 479 392 264 251 196 195 287 303 191 281 299 172 231 196 49 -46 -101 -209 -50 89 7 53 181 224 147 178 173 38 -54 -129 -277 -368 -418 -351 -361 -294 -103 48 116 387 485 392 371 245 132 6 -124 -96 -183 -208 -192 18 109 47 98 159 153 250 324 226 115 65 -48 -188 -203 -248 -144 114 84 -7 23 94 9 -79 2 10 99 162 248 244 230 95 -20 -228 -337 -415 -518 -480 -323 -185 -117 -15 53 165 266 285 234 193 223 125 21 -47 -119 -173 -145 -167 -199 -95 16 -88 -280 -304 -303 -324 -351 -349 -397 -254 -155 -182 -199 -149 -76 -108 -33 93 211 206 208 136 -18 -171 -197 -305 -443 -456 -389 -129 -125 -232 -156 -165 -125 -82 -35 22 138 280 380 409 452 491 402 268 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