File name: Pandora249s1_ChicagoIL_20230909_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T075934.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20230909_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20230909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230909T121914.8Z 8652.513366 241 1 25.08 2 80.71 91.22 23.67 120.99 0.00 1 0.00 1 0 25 4.253e-01 2.086e-02 2.056e-01 7.550e-03 6.868838e-01 4.244239e-03 8.115426e-03 -6.000000e+00 2.568793e-01 229.63 -2.00 3.53 -2.00 321.16 0.00e+00 8.476235e-03 1.971324e-03 1.690843e-03 -6.000000e+00 1.146714e-02 286.60 -2.00 20.00 -2.00 320.56 0.00e+00 5.886 0.004 302.00 328.00 3 2.7956e+00 1.4196e-02 6.8222e-02 -6.0000e+00 6.3960e-01 4.5969e-01 1.8214e-02 3.7182e-02 -6.0000e+00 6.9052e-01 -5.7104e-01 1.5653e-02 2.1042e-02 -6.0000e+00 4.1209e-01 2.3226e-01 7.5685e-03 1.0366e-02 -6.0000e+00 1.7400e-01 4.7630e-05 -1.8547e-03 2.2243e-04 1.4605e-04 -6.0000e+00 1.2973e-02 7.5842e-03 0.0000e+00 12 9 9 12 1 1 99.98 25.33 0.43 0.00758 -0.00635 21 5 1 5 0 1139.720 32.50 20.00 25.33 20.24 9.3 939.22 -139126 -42565 -150692 -53410 -178521 -149482 -71609 -130958 -55459 -62178 -114138 -139135 -20908 3712 -63141 -74371 -81161 -31636 23890 24630 171478 -1690 -48767 -20808 14246 -79963 29205 -5497 -62240 16299 14776 23488 -20668 -29821 -14667 12370 66374 19984 52389 10992 57544 23507 -118 13861 14909 24495 -1845 5276 13878 7784 23512 49397 11616 6660 7604 17873 8723 15374 10595 14555 2888 10089 19456 4697 7846 15380 3274 1871 6830 2251 2633 10090 5952 -1560 4342 545 -4734 -130 -13660 -2335 -2848 -2140 -2893 2157 2455 -1203 -1074 -702 544 -409 -3683 -1326 -1395 -3036 239 -2996 -2619 -1989 -396 702 -1504 -1265 80 -1516 -493 -1634 -2175 -1976 -1430 278 -219 293 129 -1113 -177 1468 545 323 -892 603 288 329 860 1667 579 2260 2382 1921 245 1098 444 656 1266 1176 -554 255 -680 -632 -648 66 -638 -947 -487 -3073 -427 -4842 -644 -6931 -4002 -863 -2980 -631 -791 -2521 -4284 -238 42 -1775 -2838 -3803 -995 464 544 1263 -49 -2226 -735 367 -5417 667 -174 -3437 432 457 796 -1263 -2174 -918 574 1857 1001 2237 834 3093 1921 -13 1357 1471 2236 -224 614 1543 974 2735 4910 1847 1201 1439 3158 1721 2830 1997 2583 585 2043 4025 1266 2213 4077 967 569 2117 820 1062 4004 2476 -670 1621 191 -1611 -42 -5421 -963 -1390 -1195 -1812 1383 1670 -822 -772 -521 402 -298 -2633 -954 -958 -2135 177 -2393 -2426 -2109 -459 835 -1769 -1365 78 -1440 -482 -1719 -2437 -2367 -1857 362 -320 460 210 -1799 -272 2125 788 483 -1421 992 480 535 1338 2483 840 3387 3463 2848 371 1858 841 1343 2520 2482 -1266 613 -1704 -1612 -1658 163 -1507 -2112 -1034 SS 20230909T125028.5Z 8652.535052 258 1 54.62 2 74.93 96.54 19.19 135.04 0.00 1 0.00 1 0 25 2.438e-01 2.784e-02 1.877e-01 1.032e-02 4.715617e-01 5.524644e-03 5.626004e-03 -6.000000e+00 1.472905e-01 229.62 -2.00 3.53 -2.00 319.85 0.00e+00 -4.547275e-03 1.692912e-03 5.843682e-04 -6.000000e+00 6.573245e-03 286.60 -2.00 20.00 -2.00 319.12 0.00e+00 3.771 0.001 302.00 328.00 3 5.7900e+00 1.6010e-02 4.4540e-02 -6.0000e+00 3.6673e-01 2.0798e-01 1.9160e-02 2.5176e-02 -6.0000e+00 3.9589e-01 -1.6334e-01 1.4594e-02 1.3093e-02 -6.0000e+00 2.3627e-01 7.1212e-02 7.4552e-03 5.3480e-03 -6.0000e+00 9.9802e-02 2.2250e-05 -8.4204e-04 3.2490e-04 6.0087e-05 -6.0000e+00 7.4354e-03 5.2325e-03 0.0000e+00 12 8 8 10 0 0 99.98 25.48 0.60 0.00523 -0.00109 51 5 1 5 0 1070.800 32.50 20.01 25.48 21.60 9.3 947.82 -85684 54590 -34783 87054 -97685 37838 -84422 -84646 -19526 76991 2005 -11445 -40093 6315 -25739 5123 -42739 35088 45151 70347 59378 19186 -45448 12330 11545 -62364 11232 -14518 -2620 4817 38985 8960 -17484 -14125 -4499 -18919 15908 -4508 12194 14308 30257 11766 -4642 18483 2938 8964 3225 -4506 -4301 10125 8136 28334 6309 -1097 11756 6266 6432 1582 840 2482 1114 5810 10962 2894 -1981 9537 -2595 2243 -766 -4866 -592 3145 1385 -2258 102 1149 -3290 3436 -25620 -6061 -5348 -1749 -1674 1642 4782 1355 1065 1474 -658 1483 -488 344 -897 514 1156 -2525 -1637 -88 2850 200 24 -3187 50 -693 -519 -646 442 -2781 -2393 -277 -125 986 513 41 -939 -2676 -501 542 -1029 737 777 -973 1434 889 1180 2671 3335 3239 -1015 2004 -747 -95 1888 2961 -138 902 -1566 -174 -594 -252 -772 -1561 -1065 -3371 599 -987 876 -4737 450 -3553 -4028 -554 916 53 -367 -1908 220 -1437 239 -3520 1413 1735 2189 2119 1036 -4824 790 813 -9815 863 -1395 -232 388 2354 812 -2288 -1905 -548 -2609 1633 -653 1804 2477 5086 2570 -1243 3981 736 2102 795 -1193 -1143 2395 2088 6474 1950 -392 3917 2302 2434 634 333 947 433 2269 4436 1381 -1037 4368 -1285 1048 -389 -2870 -371 2019 917 -1502 62 627 -1709 1595 -16478 -3587 -3596 -1280 -1345 1364 4096 1282 1068 1525 -701 1508 -477 309 -764 422 990 -2488 -1804 -108 3660 270 31 -3942 55 -760 -598 -792 565 -3874 -3538 -395 -192 1576 828 64 -1392 -4188 -750 822 -1670 1238 1332 -1679 2342 1408 1783 3799 4525 4381 -1523 3188 -1323 -176 3577 5267 -268 1824 -3357 -375 -1292 -534 -1574 -3052 -1997 SS 20230909T130120.2Z 8652.542595 261 1 54.49 2 72.93 98.44 17.88 141.22 0.00 1 0.00 1 0 25 2.530e-02 5.352e-03 3.562e-03 5.025e-04 4.203761e-01 2.651101e-04 5.001104e-03 -6.000000e+00 1.529172e-02 229.62 -2.00 3.53 -2.00 318.33 0.00e+00 7.763734e-04 5.276685e-05 1.367192e-04 -6.000000e+00 6.822250e-04 286.60 -2.00 20.00 -2.00 317.54 0.00e+00 3.355 0.001 302.00 328.00 3 1.7071e+00 7.1953e-04 3.9548e-02 -6.0000e+00 3.8075e-02 1.6799e-02 8.1757e-04 2.2135e-02 -6.0000e+00 4.1096e-02 -2.3941e-02 5.4314e-04 1.0795e-02 -6.0000e+00 2.4527e-02 7.0955e-03 2.8203e-04 3.1128e-03 -6.0000e+00 1.0365e-02 2.2014e-03 -3.7171e-04 1.5305e-05 3.7391e-05 -6.0000e+00 7.7157e-04 2.6231e-03 0.0000e+00 10 0 0 10 0 0 99.99 25.54 0.27 0.00262 -0.00017 677 69 1 5 0 80.470 32.50 20.01 25.54 22.34 9.4 953.65 -10021 -5809 -2996 -7734 -8025 -11894 -11554 -5484 -5611 -4103 -7670 -6138 -5831 -4968 -4247 -1111 -1190 331 -80 -1145 450 106 -741 -1037 -805 -1765 -686 -1926 -1645 -2042 121 -14 -845 -944 -1787 -2036 -1718 -1712 -333 -649 -511 -620 -232 25 235 141 237 -88 8 374 690 1182 1223 1231 1153 1112 954 642 622 776 995 1311 1655 1171 861 727 308 176 478 608 2 -77 -167 -220 -218 -240 -192 -146 -502 -598 -1039 -1332 -1620 -1517 -1002 -805 -655 -262 -133 39 387 564 479 780 848 637 538 295 -61 -220 -377 -572 -202 90 -574 -907 -787 -417 -338 123 104 -174 -32 68 202 434 512 463 181 -159 -338 -189 -143 90 441 484 650 1115 847 469 344 119 59 214 -38 -81 -52 -63 -342 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