File name: Pandora249s1_ChicagoIL_20231109_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T082029.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20231109_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231109T130748.7Z 8713.547092 171 1 55.09 2 85.01 118.07 47.75 144.06 0.00 1 0.00 1 0 25 6.165e-01 4.907e-02 2.597e-01 1.649e-02 9.420642e-01 9.722567e-03 1.211673e-02 -6.000000e+00 3.687195e-01 223.46 -2.00 3.53 -2.00 321.86 0.00e+00 -3.025272e-02 3.837946e-03 1.660036e-03 -6.000000e+00 1.740834e-02 279.27 -2.00 20.00 -2.00 321.35 0.00e+00 9.840 0.018 302.00 328.00 3 2.7720e-01 3.2458e-02 1.0991e-01 -6.0000e+00 9.0810e-01 1.7833e+00 3.8327e-02 6.5368e-02 -6.0000e+00 9.8820e-01 -1.9852e+00 2.4785e-02 2.7396e-02 -6.0000e+00 5.8752e-01 7.4009e-01 1.3112e-02 2.8308e-02 -6.0000e+00 2.5217e-01 1.0363e-05 -3.1491e-03 4.6490e-04 4.8353e-04 -6.0000e+00 1.9129e-02 -3.9611e-03 0.0000e+00 12 8 8 10 0 0 29.81 24.43 1.40 -0.00396 -0.02762 40 4 1 5 0 1377.200 32.00 20.07 24.43 11.25 9.2 877.37 900000 70418 -22376 215382 5191 900000 -54879 -28492 47602 900000 84692 61940 98954 900000 900000 142966 22868 159242 62673 900000 900000 16495 3272 30753 103044 -50968 157154 233744 -41841 63457 900000 192952 -35131 -29437 85403 -36669 44822 78343 80808 22246 900000 199603 66783 98778 26152 3020 47723 -23806 900000 3683 193168 151930 46377 24656 11276 94148 20881 89549 18158 43532 -27503 62974 134851 6461 64095 45521 -1976 1111 22330 7841 3190 44194 73301 -2843 22650 36075 -35698 1717 -43326 -18092 -12917 4371 15639 9140 49056 14688 10546 9234 6954 -2566 -6320 -5220 -726 -221 8145 -15030 -5256 1713 6178 -773 -5313 -9731 -2612 -7875 -8355 3031 -1227 120 -4665 -609 -3829 848 -5 816 58 -990 3287 -200 -3521 662 -507 2340 -681 1522 836 8678 9091 -1063 -2401 -6 1333 -1497 6309 3607 -2054 488 -1372 -2528 -257 1102 -1106 864 -1376 900000 3579 -2633 3456 356 900000 -6005 -2743 2500 900000 3583 3343 3753 900000 900000 3754 2002 3485 3474 900000 900000 1203 272 2154 4059 -10261 3898 3751 -5616 2592 900000 3096 -4305 -3522 3115 -4226 2289 3200 3890 2337 900000 4368 5456 5476 2709 357 3676 -3591 900000 437 3720 4876 4689 3363 1900 7403 3586 7760 3031 5100 -6002 5457 6059 1151 6892 5990 -415 233 4121 1887 896 8723 10822 -849 4725 5789 -10541 339 -14323 -5342 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1.9539e-02 -4.6358e-03 0.0000e+00 12 8 8 10 0 0 25.69 24.46 0.56 -0.00464 -0.01419 148 15 1 5 0 368.990 32.00 19.93 24.46 11.67 9.2 880.96 900000 -243752 -204654 -132985 -188417 -177017 -215023 -219811 -134934 900000 -157655 -193030 -52531 -59371 -152421 -43732 -83965 -11953 -41308 -70394 185714 -44589 -95864 -79190 -39532 -102966 59547 29338 -93374 -67303 198005 11246 -48968 -34058 53606 -19313 -14979 19002 15127 -5119 39695 24357 22312 7908 14165 18154 25969 3487 36036 14845 24774 31909 22846 18326 12042 18912 10045 18084 6640 10099 1947 9806 22549 8072 11909 10122 4898 6894 7528 3303 2264 7876 7099 1279 4076 1138 -5567 -422 -6921 -3863 -1263 -1012 175 -757 2362 430 -881 173 320 -103 -992 -391 -2497 -1979 -60 -2935 -1860 -666 -401 -847 -953 -897 -894 -1576 -1653 -1943 -1041 -680 -1542 124 -739 -644 277 344 719 184 374 -82 -296 385 -264 659 340 312 1312 1145 1887 1140 821 630 427 191 1007 583 -269 -18 -192 -298 -856 -157 -214 -86 -752 900000 -5098 -3181 -1015 -2343 -1851 -3342 -3914 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320.21 0.00e+00 6.276 0.005 302.00 328.00 3 5.1142e-01 2.2614e-03 7.0979e-02 -6.0000e+00 5.2740e-01 1.2995e-01 3.0052e-03 3.7323e-02 -6.0000e+00 5.7257e-01 -1.3383e-01 3.0673e-03 1.9615e-02 -6.0000e+00 3.4157e-01 4.2968e-02 1.5068e-03 6.8127e-03 -6.0000e+00 1.4616e-01 3.6726e-04 -5.7148e-04 3.8220e-05 8.1048e-05 -6.0000e+00 1.1099e-02 -5.1922e-03 0.0000e+00 11 8 0 10 0 0 19.75 24.51 0.50 -0.00519 -0.00949 342 35 1 5 0 159.240 32.00 20.21 24.51 11.99 9.1 881.90 900000 -87871 -138117 -123693 -71152 -156263 -131063 -99536 -97464 -64644 -108324 -86653 -83420 -77661 -96592 -29480 -51140 -28624 -24728 -62788 -18244 -22732 -55969 -39130 -27784 -46579 -17406 -27705 -35422 -39270 -15133 -14215 -22234 -21808 -7046 -20304 -9863 -5013 630 -3375 4898 1924 2696 218 -695 135 2346 -428 2556 2054 4346 3321 4587 3777 3701 3592 2449 4821 279 1522 338 2581 4291 2778 2013 2426 1965 1481 1292 866 867 1145 1282 130 -79 -604 -1631 -785 -2556 -1052 -1331 -862 -1300 -1192 -219 -502 -650 2 145 214 270 89 -170 384 437 -269 292 225 115 -5 -376 -525 -27 -292 -984 -1029 -923 -339 -376 -7 49 -78 150 139 278 322 440 411 -151 -283 -237 -74 -69 195 459 341 606 943 514 249 152 54 271 218 -185 -242 -183 -172 -233 -250 75 -78 6 900000 -363 -1059 -847 -277 -1383 -943 -646 -708 -378 -1069 -776 -888 -1008 -1943 -375 -949 -479 -440 -1752 -341 -454 -1620 -1036 -721 -1572 -456 -805 -1108 -1346 -469 -528 -1056 -1149 -328 -1075 -499 -280 40 -274 425 191 283 24 -80 16 277 -54 330 287 655 569 866 790 837 782 561 1092 65 345 79 629 1159 862 686 843 684 531 502 383 394 555 629 62 -38 -267 -673 -317 -1138 -537 -738 -551 -936 -857 -167 -409 -559 2 130 187 224 70 -128 290 360 -237 298 246 140 -6 -464 -597 -30 -311 -1096 -1139 -1080 -423 -479 -9 73 -126 236 228 438 485 654 629 -244 -452 -383 -123 -110 301 681 520 895 1411 796 413 281 103 548 444 -404 -534 -418 -401 -545 -572 163 -167 13 SS 20231109T134528.1Z 8713.573242 182 1 54.49 2 79.04 124.89 44.45 156.09 0.00 1 0.00 1 0 25 1.535e-01 5.894e-03 1.431e-02 6.320e-04 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