File name: Pandora249s1_ChicagoIL_20231118_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20231119T064053.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231118_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231118T131932.9Z 8722.555242 52 1 54.05 2 85.06 121.51 140.04 79.69 0.00 1 0.00 1 0 25 7.480e-01 5.182e-02 3.022e-01 1.737e-02 1.024550e+00 1.030963e-02 1.320272e-02 -6.000000e+00 4.472019e-01 222.89 -2.00 3.53 -2.00 321.99 0.00e+00 -2.702632e-02 3.662334e-03 2.830288e-03 -6.000000e+00 2.096954e-02 278.18 -2.00 20.00 -2.00 321.48 0.00e+00 9.925 0.018 302.00 328.00 3 -7.1256e-02 3.3867e-02 1.1098e-01 -6.0000e+00 1.1025e+00 2.0367e+00 3.9632e-02 6.0098e-02 -6.0000e+00 1.2010e+00 -2.3312e+00 2.3488e-02 2.8705e-02 -6.0000e+00 7.1354e-01 8.6912e-01 1.3115e-02 2.4065e-02 -6.0000e+00 3.0334e-01 1.1939e-05 -3.5682e-03 4.6320e-04 4.6454e-04 -6.0000e+00 2.2903e-02 -8.8276e-03 1.3116e-04 12 8 8 10 0 0 44.00 24.05 1.65 -0.00883 -0.03564 44 4 1 5 0 1228.320 31.75 20.07 24.05 8.00 9.0 854.91 31818 111541 3710 178976 -19876 900000 -27704 -27138 42126 900000 89332 -8557 175526 900000 24173 200280 57281 145814 900000 900000 900000 144759 -26599 35591 91147 -48617 106801 202641 -8382 52406 900000 170409 -60453 -36555 140660 -4377 -37610 62226 36039 4011 176185 175187 50351 53722 23913 1812 70888 -37644 900000 -21783 319188 92197 81240 19688 56430 211778 13560 124630 12076 32937 -30311 281427 165676 19490 75443 79648 11380 38167 27744 -4049 5593 47910 131649 -15898 34518 28678 -33496 8078 -42384 -8674 -15901 3284 38042 26931 58265 29387 22486 15234 15766 12929 -14882 2214 -5485 8857 7229 -13621 -7788 1603 5658 -75 -3841 -10005 1341 -16115 3106 -1767 -1631 1214 -5890 -1069 -2785 -200 1087 57 -40 -3609 3645 3412 -5725 3439 -2664 1088 -396 1220 860 5961 9159 2457 -2830 -740 -399 -2888 6294 3490 -961 1567 -1199 -2271 -1613 1105 261 192 -920 3857 5817 507 3532 -2297 900000 -3238 -3505 3044 900000 4396 -1132 3779 900000 2527 3695 4404 4484 900000 900000 900000 3339 -3354 2627 4345 -9942 4434 3427 -799 2417 900000 2882 -10039 -4890 3028 -370 -4395 2966 2660 487 4335 4579 4490 4295 2316 198 3957 -5441 900000 -3095 5399 4990 5359 2597 5536 4657 2248 6746 1879 3733 -5896 4760 4764 2670 6380 6601 1867 4971 4364 -986 1372 8103 9575 -4733 5547 4268 -8328 1298 -12187 -2069 -4841 966 9008 7789 13107 9295 7911 5875 6000 4877 -6972 824 -2162 3161 2947 -8017 -5098 1112 4249 -63 -3281 -8360 896 -11965 1933 -1223 -1195 932 -5400 -1076 -3317 -263 1521 83 -58 -5267 4901 4709 -9034 5124 -4200 1583 -555 1620 1114 7148 10441 3075 -4188 -1259 -783 -6515 14169 7963 -2480 4210 -3436 -6663 -4685 3020 670 454 -2255 SS 20231118T133116.0Z 8722.563379 55 1 54.32 2 83.23 123.59 137.99 81.92 0.00 1 0.00 1 0 25 6.367e-01 1.877e-02 1.580e-01 3.326e-03 8.731203e-01 1.893388e-03 9.696896e-03 -6.000000e+00 3.761031e-01 222.89 -2.00 3.53 -2.00 321.73 0.00e+00 1.324264e-03 1.038613e-03 1.390356e-03 -6.000000e+00 1.711668e-02 278.18 -2.00 20.00 -2.00 321.29 0.00e+00 7.747 0.009 302.00 328.00 3 2.0635e-01 6.8732e-03 8.9098e-02 -6.0000e+00 9.2628e-01 5.9680e-01 9.8582e-03 4.9266e-02 -6.0000e+00 1.0061e+00 -7.8768e-01 1.0105e-02 2.6836e-02 -6.0000e+00 5.9911e-01 3.1850e-01 4.6612e-03 8.5374e-03 -6.0000e+00 2.5589e-01 1.0151e-04 -1.2460e-03 9.3194e-05 1.2949e-04 -6.0000e+00 1.9439e-02 -1.0718e-02 1.6751e-04 12 8 8 10 0 0 35.90 24.08 0.56 -0.01072 -0.02008 158 16 1 5 0 343.780 31.75 20.37 24.08 8.32 9.0 857.81 -231020 -195370 -178548 -178767 -209232 -102048 -254302 -199933 -159859 900000 -180264 -162707 -75896 900000 -137592 23235 387 -13735 -62895 -47973 49587 24194 -110346 -75560 -18672 -118840 170590 -11168 -89291 -77433 900000 6623 -47874 -41619 10767 -5255 -21007 34101 16389 484 55588 55131 29035 15327 21507 18502 33425 4240 66771 14660 34727 40142 31925 28069 22040 25409 17469 33711 6549 15644 4730 20817 21090 15679 21307 19590 5910 12544 11468 4837 6989 8045 11360 1005 6287 2564 -5922 615 -8754 -1772 -2339 -492 823 705 3402 473 1064 -716 869 -143 -1572 -750 -2385 -1718 -1680 -3690 -2067 -1560 -931 -783 -1596 -1534 -553 -2137 -1740 -2096 -2024 -1460 -2486 -204 -544 -529 247 119 276 214 538 404 -313 429 202 694 832 850 1260 1276 1793 1825 468 610 671 84 1561 467 -416 3 -176 -377 -751 -133 -359 -228 -678 -4221 -2937 -2421 -2371 -3453 -541 -6296 -3123 -1837 900000 -2922 -2494 -604 900000 -3325 137 3 -150 -1205 -820 322 220 -3545 -2009 -303 -5509 553 -174 -2982 -2435 900000 129 -1894 -1700 262 -147 -715 763 526 22 1658 1805 1299 805 1067 954 1517 268 2403 965 2083 2577 2484 2493 2244 2636 2028 3333 824 1730 581 2322 2653 2384 3385 3290 1153 2391 2417 1237 1958 2371 3256 304 1649 627 -1455 142 -2458 -551 -878 -213 362 337 1692 257 605 -429 515 -84 -886 -396 -1246 -922 -1007 -2646 -1728 -1516 -928 -820 -1640 -1447 -507 -1884 -1569 -2013 -2063 -1464 -2788 -255 -780 -776 380 185 416 313 779 603 -493 697 330 1086 1241 1223 1893 1861 2544 2659 712 1071 1246 173 3422 1035 -998 7 -463 -1010 -2017 -343 -876 -516 -1564 SS 20231118T134200.0Z 8722.570833 58 1 54.42 2 81.59 125.54 136.09 83.86 0.00 1 0.00 1 0 25 5.220e-01 7.941e-03 8.013e-02 1.411e-03 7.591994e-01 7.680855e-04 8.582070e-03 -6.000000e+00 3.078918e-01 222.89 -2.00 3.53 -2.00 320.94 0.00e+00 2.085462e-03 3.498723e-04 6.901170e-04 -6.000000e+00 1.358578e-02 278.18 -2.00 20.00 -2.00 320.45 0.00e+00 6.433 0.005 302.00 328.00 3 1.8009e-01 2.4651e-03 7.4118e-02 -6.0000e+00 7.5700e-01 1.6326e-01 3.4227e-03 4.1036e-02 -6.0000e+00 8.2181e-01 -1.7700e-01 3.6353e-03 2.2204e-02 -6.0000e+00 4.9045e-01 6.1741e-02 1.7524e-03 7.9424e-03 -6.0000e+00 2.0898e-01 4.0767e-04 -4.8872e-04 3.8894e-05 9.5046e-05 -6.0000e+00 1.5884e-02 -1.1112e-02 1.8107e-04 11 8 0 10 0 0 26.63 24.12 0.47 -0.01111 -0.01478 344 35 1 5 0 158.170 31.75 20.21 24.12 8.88 9.0 861.25 -210290 -146290 -168789 -156913 -87449 -172807 -180911 -168598 -146807 -83105 -170488 -100835 -129531 -103294 -118322 -55544 -70093 -40496 -40105 -75075 -28249 -34197 -69284 -60680 -48763 -56345 -6553 -47286 -38363 -62622 -19717 -19093 -26072 -26720 -16144 -14527 -15472 -7879 -2041 -85 -2679 3697 1158 -2873 -89 -835 5214 1807 6329 1339 4542 8116 7863 5505 4619 5702 2964 2998 1278 495 1324 3107 4929 3521 4051 3269 773 1901 2917 1790 1121 2245 1955 -279 514 -798 -1878 -1175 -3089 -1812 -2272 -772 -1223 -1379 -299 -720 -247 -251 326 -51 17 132 -141 -19 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