File name: Pandora249s1_ChicagoIL_20231127_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20231128T064956.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231127_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231127T140128.1Z 8731.584352 301 1 30.70 2 80.56 129.89 96.19 310.86 0.00 1 0.00 1 0 25 4.329e-01 2.533e-02 2.119e-01 7.357e-03 7.490529e-01 4.049730e-03 8.833698e-03 -6.000000e+00 2.553173e-01 222.76 -2.00 3.53 -2.00 321.22 0.00e+00 4.950726e-03 1.778664e-03 7.692530e-04 -6.000000e+00 1.134645e-02 277.17 -2.00 20.00 -2.00 320.72 0.00e+00 5.809 0.004 302.00 328.00 3 2.7242e+00 1.2911e-02 6.8808e-02 -6.0000e+00 6.2714e-01 6.4356e-01 1.6379e-02 4.0114e-02 -6.0000e+00 6.8247e-01 -8.2093e-01 1.4581e-02 2.0476e-02 -6.0000e+00 4.0619e-01 3.4844e-01 7.1511e-03 6.3853e-03 -6.0000e+00 1.7173e-01 5.0301e-05 -6.6369e-03 2.0965e-04 9.5907e-05 -6.0000e+00 1.3244e-02 -8.2613e-04 -8.5374e-04 12 9 9 12 1 1 99.98 23.52 0.09 -0.00083 -0.05070 23 4 1 5 0 1278.800 31.25 19.65 23.52 1.55 8.8 809.65 -161550 -50957 -118318 -10106 -125560 900000 -105453 -164976 -90128 37329 -3123 -126647 18968 900000 -52057 149321 -2424 -8876 -21056 73119 145538 73242 -38933 3827 70913 -84168 79916 72084 -32002 49435 110214 26033 -21109 -27089 60763 -16369 7153 76373 14821 -5254 46073 27834 25391 34354 23487 22467 30603 5014 67117 16171 17719 36589 22689 23581 16788 20970 8635 17390 5388 9729 360 19427 24132 14174 17108 14860 3619 3494 5915 -2050 6878 6632 11049 -4365 2508 1201 -11918 3339 -16223 -438 -3801 -2170 2460 -291 3117 -1391 -940 -319 1156 -3531 -5077 -3080 -3351 -1925 143 -3787 -3214 -1245 -952 -1440 -1099 -2677 998 799 -2194 -2751 -2057 -1269 -1951 201 -813 -93 -208 -358 16 157 996 1327 -464 1228 686 1385 1221 1376 2044 2504 2483 1213 718 1022 640 600 -724 1538 67 460 -720 -875 -713 -117 -182 -727 -1178 -8110 -963 -4551 -125 -4421 900000 -2750 -8175 -2233 268 -35 -5285 223 900000 -1935 1071 -73 -307 -865 1192 1253 1261 -1853 135 1322 -6860 1376 1292 -1584 1135 1581 1027 -1529 -2234 2048 -1151 410 2465 1042 -528 3106 2415 2349 2957 2257 2191 2787 604 4525 1925 2262 4277 3336 3704 2986 3700 1753 3205 1082 1807 74 3497 4638 3385 4294 3879 1048 1035 1837 -773 2629 2683 4279 -1875 921 401 -4171 991 -6364 -171 -1816 -1178 1426 -187 2052 -923 -652 -227 816 -2546 -3519 -2158 -2257 -1295 103 -2975 -2934 -1288 -1095 -1736 -1280 -2908 945 722 -2102 -2813 -2209 -1448 -2451 277 -1167 -145 -337 -577 25 233 1441 1963 -732 1987 1122 2187 1850 2006 3111 3657 3522 1766 1150 1699 1198 1222 -1470 3236 153 1101 -1801 -2223 -1809 -286 -422 -1579 -2632 SS 20231127T141356.4Z 8731.593014 310 1 12.69 2 78.82 132.26 97.82 313.04 0.00 1 0.00 1 0 25 4.732e-01 2.559e-02 2.396e-01 1.167e-02 6.496582e-01 6.323736e-03 7.869470e-03 -6.000000e+00 2.790204e-01 222.76 -2.00 3.53 -2.00 320.74 0.00e+00 2.703181e-03 2.439369e-03 1.238797e-03 -6.000000e+00 1.240007e-02 277.17 -2.00 20.00 -2.00 320.22 0.00e+00 4.978 0.002 302.00 328.00 3 3.5422e+00 1.9097e-02 5.9235e-02 -6.0000e+00 6.8536e-01 4.2146e-01 2.3543e-02 3.4974e-02 -6.0000e+00 7.4590e-01 -5.5386e-01 2.0316e-02 1.7464e-02 -6.0000e+00 4.4394e-01 2.5080e-01 1.0193e-02 5.1611e-03 -6.0000e+00 1.8763e-01 5.5261e-05 -6.4454e-03 3.4617e-04 8.0645e-05 -6.0000e+00 1.4478e-02 1.8444e-03 -8.1669e-04 12 9 9 12 9 1 99.80 23.53 0.12 0.00184 -0.04659 4 2 1 5 0 2537.640 31.25 19.32 23.53 1.61 8.7 809.49 -145365 -110786 -140659 180976 -77174 900000 -114816 -113507 -67915 116422 258808 -117823 -10234 900000 -68219 7491 -45570 33147 31162 89802 58289 16246 -26749 -16350 112075 -57678 49664 136016 -49238 57963 18555 69421 -12319 12710 42440 22890 -2553 39863 25838 -2622 39569 30043 21605 23480 16757 -2026 16417 -177 27155 -4427 22311 20759 9779 12412 16065 16219 12637 9595 720 3135 -9989 11859 23863 12419 10415 7667 -2685 3340 4668 -1509 377 1750 6105 -6217 325 8089 -14276 -7342 -10662 -783 -3305 -3429 -2755 -831 2076 -555 1139 -29 1800 -1104 -996 -3001 -3484 1180 2130 -5259 -1299 -1308 494 -1136 -776 -1067 386 -1621 -144 -1501 -3694 -765 -876 -1036 -738 1446 174 -191 132 357 1162 1352 -1259 892 -308 320 1215 1306 673 2690 1932 1716 1254 914 2277 -76 1072 1157 -1236 448 -1441 -983 26 364 -1159 -251 -1184 -6916 -4240 -7565 2059 -1916 900000 -3919 -4109 -1686 1325 2945 -5728 -201 900000 -3599 239 -2748 981 993 1635 1459 610 -1552 -893 1785 -5184 1526 1702 -3809 1583 844 2212 -1009 868 2125 1354 -203 2358 2087 -331 3692 3316 2704 2939 2250 -330 2241 -29 3491 -821 3427 3566 2047 2725 3601 3764 3106 2424 193 799 -2921 2968 5892 3829 3507 2669 -1017 1205 1774 -683 186 900 3021 -3332 150 3129 -6335 -2974 -4780 -366 -1854 -2208 -1781 -567 1460 -426 905 -24 1480 -912 -778 -2235 -2479 882 1547 -4678 -1283 -1478 608 -1471 -968 -1229 399 -1643 -149 -1673 -4448 -953 -1185 -1426 -1123 2323 290 -315 207 533 1691 2012 -2016 1462 -518 522 1890 1958 976 4007 2804 2509 1828 1497 4077 -150 2040 2318 -2689 1012 -3426 -2360 63 842 -2582 -519 -2354 SS 20231127T141724.2Z 8731.595419 313 1 1.47 2 78.34 132.92 98.27 313.66 0.00 1 0.00 1 0 25 3.374e-01 1.355e-02 2.240e-01 8.985e-03 6.445962e-01 4.743095e-03 7.588559e-03 -6.000000e+00 1.986914e-01 222.76 -2.00 3.53 -2.00 320.09 0.00e+00 4.639816e-03 1.621434e-03 5.683665e-04 -6.000000e+00 8.741466e-03 277.17 -2.00 20.00 -2.00 319.55 0.00e+00 4.792 0.002 302.00 328.00 3 1.6585e+00 1.3778e-02 5.7179e-02 -6.0000e+00 4.8854e-01 1.6110e-01 1.6918e-02 3.3533e-02 -6.0000e+00 5.3073e-01 -1.6284e-01 1.5495e-02 1.7942e-02 -6.0000e+00 3.1655e-01 5.9014e-02 7.9641e-03 7.1745e-03 -6.0000e+00 1.3462e-01 4.5268e-04 -1.4181e-03 2.5456e-04 8.3722e-05 -6.0000e+00 1.0270e-02 -4.3454e-03 1.3270e-04 12 9 9 12 1 1 -47.83 23.53 0.29 -0.00435 -0.01500 3 15 1 5 0 366.580 31.25 20.22 23.53 1.59 8.8 809.75 -135219 -11957 122639 -84661 -174028 -125838 -7915 -108170 -122582 -93815 -34391 -109930 -50452 -38621 -6076 -32741 4091 -18124 -4165 -66336 -25195 -15791 -39870 35442 11159 -34053 -31558 2622 -23348 -31263 10165 12507 15781 -15945 -8223 -9390 -7770 -5665 6149 1720 4913 -1092 12624 6214 -3917 -3407 2606 1466 3413 5614 2721 6371 6041 5723 2334 2687 -331 2896 -1584 3957 1871 6613 7355 418 5942 3916 1944 675 -178 1668 831 1147 2344 -292 -1193 -104 -37 650 -4557 -538 -1663 21 -882 -2927 -1036 -1429 16 -1613 -476 -1890 -1063 -1249 1338 -629 258 -442 245 -480 59 497 -1365 -463 -655 1844 -518 -395 -2213 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