File name: Pandora249s1_ChicagoIL_20231208_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T082906.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20231208_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231208T134248.1Z 8742.571390 197 1 54.74 2 85.13 126.73 51.79 172.22 0.00 1 0.00 1 0 25 7.555e-01 1.177e-01 3.074e-01 3.973e-02 1.016681e+00 2.442349e-02 1.286807e-02 -6.000000e+00 4.678406e-01 222.61 -2.00 3.53 -2.00 320.78 0.00e+00 -4.011512e-02 4.902433e-03 3.928951e-03 -6.000000e+00 2.327782e-02 275.95 -2.00 20.00 -2.00 320.08 0.00e+00 10.037 0.019 302.00 328.00 3 5.7696e-01 6.8526e-02 1.2356e-01 -6.0000e+00 1.1470e+00 2.5718e+00 7.9052e-02 1.0560e-01 -6.0000e+00 1.2518e+00 -2.1210e+00 4.4682e-02 2.5440e-02 -6.0000e+00 7.4255e-01 6.3080e-01 2.3442e-02 3.5918e-02 -6.0000e+00 3.1477e-01 3.9320e-06 -4.8571e-03 1.0432e-03 5.1330e-04 -6.0000e+00 2.4509e-02 -7.0810e-03 0.0000e+00 12 8 8 10 0 0 85.85 24.55 2.30 -0.00708 -0.04358 17 2 1 5 0 3219.340 32.00 19.85 24.55 12.95 9.2 889.14 900000 5013 -9446 215162 -18591 900000 26565 -32496 92357 152151 900000 9748 145384 900000 53010 88822 78191 250666 102807 900000 299990 47344 -16197 54113 94022 -34931 900000 900000 9250 900000 900000 73808 -21857 -29297 900000 -21814 -19917 188378 18548 8750 272721 14565 98626 84297 49790 11945 46882 -39394 900000 -37710 85111 900000 79532 -7103 66547 900000 5210 900000 66321 65192 -40881 201016 900000 176 67154 99746 -16805 21840 26220 8320 43314 43016 335602 -34778 44874 58587 -42257 26642 -75536 -3887 -11527 -9927 36392 63900 112172 49401 63725 25734 46014 3772 -23317 -111 2140 22082 28915 -23056 1478 9693 33345 2794 6105 -17805 19380 -23799 6667 6902 -4278 6393 1989 4400 1545 13745 1301 991 748 -7280 14549 11174 -3741 -359 -7118 -4771 -603 -2305 262 4282 17153 -1721 -9289 -1658 -3499 -9331 19297 15133 -7296 3765 -6323 -6011 124 4404 -261 1182 8169 900000 1210 -2372 8312 -3531 900000 2822 -7427 7433 7837 900000 2322 8892 900000 7850 9150 8810 9683 9026 900000 11589 5819 -3754 7031 9906 -15212 900000 900000 1852 900000 900000 6221 -5066 -7511 900000 -4597 -4057 7277 3452 2212 10535 4348 12469 11250 8218 2517 6257 -11621 900000 -10992 7771 900000 9217 -2120 10283 900000 1683 900000 10947 9616 -15362 7765 900000 46 9669 10509 -5607 5062 6262 2659 10800 11330 12965 -18564 10574 10411 -18120 5455 -44937 -1276 -4765 -4679 12231 17773 20366 17557 20186 12029 17242 2054 -15493 -55 992 8616 11617 -17903 1039 7189 21770 2601 5353 -18158 12128 -21145 4378 4746 -3454 4939 1760 4317 1797 15929 1835 1436 1072 -10941 17198 13813 -5549 -529 -11164 -6985 -798 -2974 319 4847 16632 -2041 -13134 -2529 -6272 -19861 33694 29815 -19447 9615 -18589 -17880 345 11433 -663 2730 16410 SS 20231208T135446.9Z 8742.579710 200 1 54.86 2 83.37 128.87 51.61 175.92 0.00 1 0.00 1 0 25 4.875e-01 2.586e-02 2.316e-01 6.012e-03 8.409913e-01 3.415825e-03 9.479261e-03 -6.000000e+00 2.889246e-01 222.61 -2.00 3.53 -2.00 321.81 0.00e+00 1.127281e-03 1.779995e-03 1.447485e-03 -6.000000e+00 1.308629e-02 275.95 -2.00 20.00 -2.00 321.37 0.00e+00 7.891 0.009 302.00 328.00 3 1.1229e+00 1.2232e-02 8.9375e-02 -6.0000e+00 7.1128e-01 8.7175e-01 1.6146e-02 4.7108e-02 -6.0000e+00 7.7354e-01 -1.1436e+00 1.4980e-02 2.4797e-02 -6.0000e+00 4.5869e-01 4.6476e-01 7.1061e-03 7.7248e-03 -6.0000e+00 1.9627e-01 3.5187e-05 -2.1597e-03 1.7339e-04 1.2305e-04 -6.0000e+00 1.4955e-02 -7.8414e-03 0.0000e+00 12 8 8 10 0 0 67.14 24.56 0.83 -0.00784 -0.02407 74 7 1 5 0 741.220 32.00 20.00 24.56 13.15 9.2 890.91 900000 -94078 -137893 -12762 -64971 900000 -173081 -135071 6076 900000 -31974 -117083 10189 43342 -120134 197542 -18831 121384 18889 20234 125867 17462 -24195 18381 15595 -103066 87217 111424 -38573 9912 900000 16547 -54711 -29750 64006 -33706 -742 159895 49040 3559 111244 -1662 72184 27906 16320 10549 63360 12993 110848 24273 45168 81660 45185 31538 24772 46084 26476 33239 15649 12841 9328 32361 35833 21029 37298 30915 10178 11836 19097 2292 8578 12046 20789 1682 16816 13983 -9850 4223 -20150 -1413 -2955 -1820 1423 1934 7400 1290 2616 -1001 1507 -1061 -1783 -1138 -5796 -46 -952 -7586 -3892 -1687 -904 -872 -1373 -4047 -758 -3962 -1051 -2706 -2262 -2026 -4048 -1346 -666 -1128 -993 10 203 -414 912 734 -1094 1030 787 1358 460 1978 1708 2575 3628 1593 783 1202 118 61 2260 1056 -153 460 -320 -682 -957 -509 -448 -386 -1173 900000 -2255 -5361 -136 -1038 900000 -7006 -3885 45 900000 -375 -3430 98 369 -6462 1157 -491 840 382 410 872 344 -709 362 332 -7411 929 890 -1315 211 900000 485 -3439 -1743 1462 -1955 -31 1499 1638 221 2672 -133 2876 1749 1138 773 2747 952 3182 1763 2911 4067 3574 3104 2787 4374 3133 3661 1980 1595 1181 3413 4073 3142 5201 4745 1926 2268 3670 587 2302 3317 5274 492 3862 2957 -2418 891 -5915 -404 -1025 -729 624 918 3542 697 1465 -601 889 -628 -1009 -603 -3111 -24 -551 -5475 -2906 -1438 -862 -877 -1355 -3781 -618 -3150 -833 -2314 -2044 -1968 -4429 -1628 -912 -1721 -1464 14 317 -628 1353 1123 -1788 1576 1213 2199 719 2941 2465 3573 4868 2227 1222 1974 223 126 4956 2507 -364 1155 -839 -1823 -2566 -1322 -1096 -950 -2746 SS 20231208T140539.5Z 8742.587263 203 1 54.41 2 81.82 130.86 51.57 179.28 0.00 1 0.00 1 0 25 5.357e-01 1.061e-02 1.120e-01 2.213e-03 7.392970e-01 1.208832e-03 8.335585e-03 -6.000000e+00 3.158387e-01 222.61 -2.00 3.53 -2.00 321.09 0.00e+00 2.230884e-03 5.559109e-04 7.553339e-04 -6.000000e+00 1.385273e-02 275.95 -2.00 20.00 -2.00 320.63 0.00e+00 6.598 0.005 302.00 328.00 3 1.0254e+00 3.9056e-03 7.4926e-02 -6.0000e+00 7.7672e-01 2.1050e-01 5.4200e-03 4.0109e-02 -6.0000e+00 8.4410e-01 -2.6486e-01 5.7785e-03 2.1855e-02 -6.0000e+00 5.0285e-01 1.0163e-01 2.7828e-03 7.6050e-03 -6.0000e+00 2.1503e-01 1.5623e-04 -8.7577e-04 6.3227e-05 9.5935e-05 -6.0000e+00 1.6397e-02 -8.4359e-03 0.0000e+00 12 8 8 10 0 0 20.99 24.58 0.54 -0.00844 -0.01502 184 19 1 5 0 295.670 32.00 20.25 24.58 13.51 9.2 892.72 900000 -200740 -207492 -159619 -187365 -179393 -215910 -169764 -101342 -21762 -168495 -155107 -104139 4624 -132810 -28873 -86997 -27958 -13278 -60453 -2852 -60851 -59672 -55090 -31818 -78534 -4421 -39287 -41535 -64108 21114 -19830 -46789 -31012 22939 -19303 -11459 -2819 -1405 -6263 9498 -5519 4548 1638 1462 -592 10041 156 10459 3465 7704 12814 11099 4990 5018 7047 6071 7746 492 3717 1750 6849 7238 3855 5209 6248 2758 3163 3769 1092 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