File name: Pandora249s1_ChicagoIL_20231225_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240212T202525.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20231225_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20231225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231225T153635.0Z 8759.650405 344 1 19.60 2 72.36 147.82 110.54 345.48 0.00 1 0.00 1 0 17 2.200e-01 1.181e-02 1.338e-01 6.472e-03 4.642380e-01 3.411616e-03 5.573394e-03 -6.000000e+00 1.302817e-01 222.84 -2.00 3.53 -2.00 319.45 0.00e+00 2.946111e-03 9.181154e-04 2.221416e-04 -6.000000e+00 5.829683e-03 274.53 -2.00 20.00 -2.00 318.94 0.00e+00 3.255 0.001 302.00 328.00 3 4.8563e+00 9.4105e-03 3.9636e-02 -6.0000e+00 3.2035e-01 1.0644e-01 1.1007e-02 2.4100e-02 -6.0000e+00 3.4804e-01 -6.1612e-02 9.0209e-03 1.2467e-02 -6.0000e+00 2.0694e-01 2.2266e-02 4.7910e-03 4.7990e-03 -6.0000e+00 8.8052e-02 9.3683e-05 -8.7654e-04 2.0069e-04 5.4585e-05 -6.0000e+00 6.7600e-03 -1.4745e-02 1.4444e-04 12 9 9 12 1 1 95.27 25.07 0.25 -0.01475 -0.02133 4 1 1 5 0 3917.850 32.25 20.01 25.07 18.04 9.4 923.87 -64955 -12207 -10766 900000 -71974 900000 -23784 -45562 17398 67201 158213 -31360 -25166 123736 -2862 1354 10071 2667 1488 44996 -7135 2065 -18065 2641 14621 -14833 1657 9572 -11957 37913 9325 4020 9909 -12526 -4048 -16807 -3489 -2306 -3389 475 1593 -8324 -418 4404 5089 -5163 4073 -350 -224 1155 1021 7197 1998 -1659 1513 6050 -217 1267 1979 -621 -591 277 5750 -568 1608 2016 -1706 2742 -1732 -525 882 1241 3997 -2827 -1214 1397 -4244 68 -4918 -1522 -1684 -1145 -2667 -1217 1545 -218 181 -590 1489 789 -503 -556 864 -67 1219 -1081 -1095 1304 1192 -160 -1087 -406 178 -325 -630 -949 -1396 -283 376 -503 373 1221 82 -90 -94 -146 1126 801 -764 83 -68 -644 157 -188 397 200 729 1278 612 448 -274 -846 1084 1079 -734 -1 -343 -828 -140 -26 -300 -44 472 -1788 -231 -216 900000 -2477 900000 -540 -1409 318 806 998 -1128 -984 1327 -132 70 534 165 99 2044 -563 150 -1630 203 1061 -1516 146 767 -1154 2248 800 413 1082 -1841 -547 -2524 -480 -356 -631 101 379 -2368 -115 1195 1390 -1580 1146 -104 -67 352 331 2388 758 -699 652 2580 -92 530 891 -283 -273 122 2648 -306 895 1107 -932 1412 -975 -324 596 889 2829 -2079 -822 840 -2458 36 -2832 -948 -1206 -922 -2402 -1154 1386 -212 185 -633 1583 828 -506 -519 808 -61 1151 -1061 -1217 1593 1597 -207 -1482 -508 204 -363 -736 -1185 -1842 -390 507 -740 590 2020 139 -147 -144 -211 1565 1140 -1159 131 -111 -1046 245 -284 573 276 1041 1799 918 680 -454 -1496 1958 1886 -1377 -2 -700 -1734 -294 -54 -595 -83 848 SS 20231225T154650.3Z 8759.657526 350 1 53.54 2 71.38 150.07 110.94 347.78 0.00 1 0.00 1 0 25 8.154e-02 8.619e-03 3.834e-02 2.985e-03 4.430585e-01 1.547756e-03 5.324212e-03 -6.000000e+00 4.809766e-02 222.85 -2.00 3.53 -2.00 319.19 0.00e+00 8.475639e-04 3.889882e-04 2.003819e-04 -6.000000e+00 2.091062e-03 274.53 -2.00 20.00 -2.00 318.66 0.00e+00 3.093 0.000 302.00 328.00 3 4.8002e+00 4.2515e-03 3.7662e-02 -6.0000e+00 1.1840e-01 7.1754e-02 4.9318e-03 2.2783e-02 -6.0000e+00 1.2860e-01 -3.7398e-02 3.8420e-03 1.1616e-02 -6.0000e+00 7.6581e-02 1.2955e-02 2.0379e-03 3.5513e-03 -6.0000e+00 3.2538e-02 1.2078e-04 -6.1040e-04 9.2324e-05 4.2977e-05 -6.0000e+00 2.4806e-03 -1.4482e-02 1.5287e-04 11 9 0 11 8 0 99.77 25.10 0.30 -0.01448 -0.01907 23 2 1 5 0 2327.480 32.25 20.00 25.10 18.26 9.3 924.91 -25902 -34594 -30642 16441 -25817 37760 -25212 -27789 -6544 1664 7440 -9936 -8714 19941 -7722 -2101 -15542 6831 -677 19132 2095 -3208 -6730 480 3386 -22458 -4359 1307 -8128 9072 4995 735 -3790 -4493 -1396 -6104 -2371 856 -2127 -1393 2814 -2632 -111 2781 2923 -3236 -760 -1575 -942 -412 1436 8107 2465 -864 2317 3897 903 1438 -55 1205 -317 1605 3459 1058 1086 1099 -320 -316 -144 -559 -856 12 1806 -972 124 446 -1509 -846 -4037 -1377 -868 -1638 -1571 -807 375 -8 -315 77 403 824 -220 -305 201 581 700 -124 -439 728 951 -339 -427 -995 -20 -651 -472 -1231 -1019 -567 100 164 373 1010 81 -69 81 -171 717 1059 -781 -109 -901 -300 -251 445 322 341 939 1382 380 242 -105 -146 834 796 -514 -83 -391 -506 -73 -215 -385 142 -44 -641 -1077 -981 325 -729 539 -697 -874 -187 47 210 -356 -353 726 -443 -132 -1239 469 -53 1297 174 -284 -631 44 325 -2948 -487 135 -889 837 516 89 -538 -689 -207 -931 -366 146 -447 -345 759 -812 -35 875 927 -1099 -253 -529 -318 -142 515 2959 938 -364 999 1717 421 671 -26 547 -148 779 1807 619 668 667 -188 -183 -87 -376 -641 10 1426 -766 91 297 -931 -494 -2506 -928 -666 -1311 -1381 -752 367 -8 -350 89 467 932 -237 -305 187 521 653 -129 -516 877 1248 -464 -563 -1223 -24 -776 -587 -1517 -1320 -771 144 236 580 1643 134 -110 121 -259 1049 1575 -1155 -168 -1445 -475 -386 707 489 495 1300 1888 554 385 -168 -248 1458 1450 -932 -158 -775 -1025 -148 -431 -742 259 -82 SS 20231225T155629.4Z 8759.664229 353 1 10.62 2 70.51 152.22 111.26 349.96 0.00 1 0.00 1 0 25 6.821e-02 7.563e-03 2.982e-02 3.551e-03 4.272138e-01 1.834024e-03 5.172165e-03 -6.000000e+00 4.022654e-02 222.85 -2.00 3.53 -2.00 318.64 0.00e+00 4.354388e-04 3.887719e-04 2.301921e-04 -6.000000e+00 1.749235e-03 274.53 -2.00 20.00 -2.00 318.09 0.00e+00 2.964 0.000 302.00 328.00 3 3.8993e+00 4.9369e-03 3.6136e-02 -6.0000e+00 9.9019e-02 3.0096e-02 5.6346e-03 2.1841e-02 -6.0000e+00 1.0757e-01 -1.9699e-02 4.0490e-03 1.1045e-02 -6.0000e+00 6.4054e-02 4.7129e-03 2.1464e-03 3.2549e-03 -6.0000e+00 2.7208e-02 3.4982e-04 -6.9858e-04 1.0866e-04 4.0182e-05 -6.0000e+00 2.0755e-03 -1.3923e-02 1.0095e-04 12 9 1 12 1 1 99.84 25.13 0.38 -0.01392 -0.01917 9 5 1 5 0 1061.430 32.50 19.99 25.13 18.54 9.3 926.92 -15859 -26397 -38855 -20191 -22448 7798 -25212 -22422 -10665 -9588 -19942 -22653 -12551 402 -9700 -4276 -5015 1867 654 264 388 2869 -3723 -635 415 -8302 3941 214 -3649 -3043 7571 -164 667 -1691 2759 -3033 -4973 431 -2813 -2112 2575 -142 -474 -67 -1173 -19 192 -746 1210 145 331 4369 1595 1276 1094 2321 -122 1140 539 1633 1216 2390 2744 931 993 1160 352 -466 409 650 -151 376 887 -976 -280 375 -714 -858 -2713 -945 -998 -1297 -1604 -2004 -664 -621 -4 -211 -265 -50 29 80 117 597 356 -336 306 979 536 -362 -726 -734 -345 199 -585 -1278 -938 -770 -258 209 613 107 571 309 215 303 61 207 -15 -21 -500 -324 302 230 630 730 841 1142 491 437 521 121 163 446 -265 -78 142 -260 -461 -542 -539 27 -317 -494 -1051 -1871 -797 -847 208 -969 -932 -443 -428 -1036 -1287 -735 25 -783 -378 -493 184 70 30 45 327 -464 -81 56 -1302 558 31 -524 -434 1041 -27 123 -341 531 -607 -1068 100 -736 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