File name: Pandora249s1_ChicagoIL_20240103_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240113T053459.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240103_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240103T202253.6Z 8768.849231 492 1 25.58 2 73.22 215.32 122.59 298.54 0.00 1 0.00 1 0 25 6.692e-02 5.505e-03 1.637e-02 1.100e-03 5.377687e-01 5.728187e-04 6.365773e-03 -6.000000e+00 3.950507e-02 223.16 -2.00 3.53 -2.00 319.06 0.00e+00 7.737940e-04 1.396445e-04 2.468802e-04 -6.000000e+00 1.712134e-03 273.97 -2.00 20.00 -2.00 318.53 0.00e+00 3.410 0.001 302.00 328.00 3 2.0885e+00 1.5633e-03 4.3047e-02 -6.0000e+00 9.7329e-02 7.4993e-02 1.8092e-03 2.7461e-02 -6.0000e+00 1.0573e-01 -4.8535e-02 1.4350e-03 1.3952e-02 -6.0000e+00 6.2921e-02 1.4074e-02 7.6622e-04 4.2465e-03 -6.0000e+00 2.6690e-02 1.2004e-03 -5.7151e-04 3.2198e-05 5.1430e-05 -6.0000e+00 2.0365e-03 -1.2777e-02 9.7283e-05 12 1 1 12 1 1 99.99 24.12 0.39 -0.01278 -0.01707 169 37 1 5 0 150.430 31.75 19.74 24.12 7.34 9.0 850.86 -29482 -9160 -19801 -19419 -19781 -30306 -26265 -26244 -12015 -14877 -13855 -19736 -12180 -7632 -10986 -511 -3102 -3523 24 -6842 -1226 -2597 -3614 -5366 -3682 -7588 -3666 -4655 -7309 -4888 -1286 746 -2731 -3874 -2843 -3840 -1104 -483 -172 -214 387 -393 -847 -564 -120 -583 264 -26 968 628 1437 1891 2135 1633 1238 1230 1014 731 380 572 762 1622 2082 1293 769 159 -96 395 943 1037 410 97 369 -406 -449 -293 -347 -65 -739 -592 -756 -1136 -1593 -1328 -1189 -836 -451 -317 -126 -43 337 648 557 954 938 399 318 351 -24 -254 -379 -502 -53 156 -403 -1004 -971 -566 -421 -9 124 -316 -16 31 270 508 614 432 189 -102 -338 2 67 62 460 441 708 955 802 212 187 77 6 6 -124 -216 -15 -4 -269 -208 -123 -279 -199 -519 -154 -402 -392 -378 -621 -541 -605 -272 -380 -373 -616 -416 -306 -558 -28 -194 -243 2 -554 -97 -212 -308 -498 -363 -828 -395 -498 -783 -522 -147 96 -415 -587 -428 -634 -171 -85 -37 -54 112 -114 -261 -178 -38 -189 86 -9 325 221 540 779 886 736 596 618 526 384 197 291 391 879 1154 799 507 98 -62 253 594 729 302 77 294 -315 -346 -205 -222 -43 -481 -436 -604 -976 -1519 -1279 -1215 -860 -487 -355 -143 -48 349 657 532 945 929 421 364 432 -31 -339 -512 -626 -64 180 -488 -1239 -1262 -776 -589 -12 188 -514 -25 49 407 753 888 640 294 -160 -542 3 102 95 672 645 995 1336 1201 337 311 131 11 11 -228 -406 -29 -7 -535 -405 -236 -510 -362 SS 20240103T202837.0Z 8768.853206 495 1 54.95 2 73.84 216.53 123.50 299.77 0.00 1 0.00 1 0 17 2.923e-01 1.058e-02 1.257e-01 3.884e-03 5.534839e-01 2.047849e-03 6.481260e-03 -6.000000e+00 1.731896e-01 223.16 -2.00 3.53 -2.00 319.95 0.00e+00 3.159546e-04 6.567395e-04 4.222626e-04 -6.000000e+00 7.582273e-03 273.97 -2.00 20.00 -2.00 319.46 0.00e+00 3.534 0.001 302.00 328.00 3 4.6173e+00 5.8599e-03 4.4644e-02 -6.0000e+00 4.2632e-01 1.3532e-01 7.1210e-03 2.8678e-02 -6.0000e+00 4.6321e-01 -7.0148e-02 6.5040e-03 1.4839e-02 -6.0000e+00 2.7519e-01 2.2486e-02 3.3815e-03 4.4858e-03 -6.0000e+00 1.1655e-01 8.1232e-05 -8.7768e-04 1.1740e-04 5.6197e-05 -6.0000e+00 8.9003e-03 -1.2381e-02 6.3587e-05 12 9 8 11 8 0 99.85 24.12 0.53 -0.01238 -0.01898 36 4 1 5 0 1526.270 31.50 20.09 24.12 7.72 9.1 854.52 -100445 -47799 -97539 278 -27963 900000 -83722 -89536 -2875 236671 -38214 -61424 -24089 81385 -16375 -826 -22684 -167 -1587 43757 40298 -10353 -13287 -10624 9469 -35894 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769 -364 715 828 -188 -612 290 -441 1479 390 1126 2851 1027 1120 390 2311 546 1363 866 108 -1013 1736 2788 543 1762 1081 -653 696 640 -274 -207 862 2068 -986 -122 933 -1579 -611 -2951 -679 -1355 -1573 -947 -967 1151 -753 99 7 952 248 -707 -39 -845 332 634 -1432 -848 55 738 -303 -780 -1357 -452 -726 -251 -1352 -1126 -466 -1032 921 -667 -552 345 -580 366 392 1576 932 132 229 -649 682 459 132 951 1573 1751 1787 505 702 143 -889 1950 1379 -751 241 -829 -636 -1533 -199 -924 -151 -374 SS 20240103T205316.6Z 8768.870331 505 1 3.28 2 76.72 221.59 127.30 305.37 0.00 1 0.00 1 0 17 2.753e-01 1.115e-02 1.938e-01 7.098e-03 6.552600e-01 3.790213e-03 7.594027e-03 -6.000000e+00 1.626523e-01 223.17 -2.00 3.53 -2.00 320.09 0.00e+00 2.084063e-03 1.272015e-03 6.921161e-04 -6.000000e+00 7.182707e-03 273.96 -2.00 20.00 -2.00 319.61 0.00e+00 4.248 0.001 302.00 328.00 3 2.5143e+00 1.0918e-02 5.3294e-02 -6.0000e+00 4.0071e-01 1.4973e-01 1.3479e-02 3.3924e-02 -6.0000e+00 4.3545e-01 -1.4652e-01 1.2710e-02 1.8128e-02 -6.0000e+00 2.5910e-01 5.4033e-02 6.5537e-03 6.3107e-03 -6.0000e+00 1.1100e-01 3.1244e-04 -4.4295e-04 2.0296e-04 7.5120e-05 -6.0000e+00 8.4867e-03 -8.4401e-03 3.6037e-04 12 9 9 12 1 1 -195.21 24.20 0.35 -0.00844 -0.01177 4 8 1 5 0 655.450 31.75 19.65 24.20 8.13 9.0 855.60 900000 -41804 -148133 900000 -133649 20414 -52712 -79813 -56566 -100470 -108916 -119007 3466 -34832 -18567 -20068 -29581 -39797 -44091 -2103 1424 19365 -2439 -8536 -16521 -37466 -2705 -1995 -27048 -20047 15944 -6188 -14143 -17526 3891 -5253 -2366 -7999 1112 -8505 8943 -4668 61 5845 4100 -771 -2757 2470 2335 -421 10035 5712 3308 2335 5927 -339 1287 3565 629 -826 519 3675 4217 1936 704 708 1793 2362 4189 -465 -549 949 2279 472 1731 -345 -996 -1997 -1801 -526 -1701 -345 -1596 -961 -629 -1242 -915 1274 189 -403 102 337 -175 1621 706 -1768 266 755 -455 -708 -503 -1178 -447 1195 -2125 -1671 -1474 -107 -174 -530 -549 -354 -523 -25 85 670 -8 1617 790 -467 9 519 916 207 173 1144 676 1651 573 234 -13 77 446 634 -221 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