File name: Pandora249s1_ChicagoIL_20240116_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240117T060410.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240116_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240116T135209.3Z 8781.577886 58 1 53.68 2 85.08 124.09 118.42 60.31 0.00 1 0.00 1 0 25 8.790e-01 1.469e-01 3.175e-01 3.925e-02 1.539137e+00 2.665917e-02 2.003360e-02 -6.000000e+00 5.592697e-01 223.61 -2.00 3.53 -2.00 319.65 0.00e+00 -5.038536e-02 3.394041e-03 4.664252e-03 -6.000000e+00 2.623473e-02 273.22 -2.00 20.00 -2.00 318.76 0.00e+00 9.961 0.018 302.00 328.00 3 -7.7351e-01 7.1064e-02 1.4280e-01 -6.0000e+00 1.3719e+00 4.4286e+00 8.3201e-02 1.4131e-01 -6.0000e+00 1.4962e+00 -3.1585e+00 4.4765e-02 3.8033e-02 -6.0000e+00 8.9232e-01 7.0553e-01 2.1348e-02 4.1752e-02 -6.0000e+00 3.7271e-01 4.5471e-06 -2.0352e-03 8.0953e-04 5.9865e-04 -6.0000e+00 2.9132e-02 -9.3146e-03 -8.9727e-05 12 8 8 10 0 0 61.05 22.01 1.75 -0.00931 -0.02461 23 2 1 5 0 2333.640 30.50 18.91 22.01 -15.00 8.1 687.98 34972 5848 -757 124626 -46553 900000 -44289 -33646 49524 900000 133956 82 318602 900000 65901 900000 79993 201716 45574 900000 340498 69764 18945 43999 245482 -4171 900000 900000 -12280 232730 900000 229760 -27734 -1813 900000 -4451 3381 900000 42505 -21093 154611 66819 211482 34480 33767 -9419 168130 -41813 900000 -32487 900000 103631 155024 32835 37986 900000 -24121 900000 6341 45856 -48354 900000 900000 -6766 900000 127686 -18997 109952 208714 3596 50076 114529 900000 -52673 119636 30804 -70936 -7280 -74871 56584 4438 21308 247725 82570 900000 103600 106568 49482 69885 26935 -29274 -10161 -1245 50073 115269 -8625 7462 48721 116945 40937 2249 -16226 17997 -22840 45658 27386 11724 27965 6372 21783 5704 9272 12748 1459 3965 -10851 28670 6075 -4583 5599 -12464 413 -12527 -6867 -10060 9920 32642 -10385 -13201 -3973 -452 -14032 35350 6630 -2525 6091 -7341 -9076 -3172 3062 4055 10470 12440 11556 2304 -267 9899 -16121 900000 -15056 -12828 10070 900000 14896 37 12147 900000 15284 900000 15503 10895 10715 900000 12982 9914 4274 10217 9359 -2111 900000 900000 -3958 8873 900000 8760 -10670 -534 900000 -1111 773 900000 9134 -10454 15004 15980 10995 8963 7256 -2612 6993 -13478 900000 -10359 900000 10416 10209 7966 9479 900000 -12373 900000 2000 7947 -17932 900000 900000 -1782 900000 9736 -6453 11051 8681 1296 12149 14687 900000 -29575 9952 5125 -28765 -1721 -35292 9276 1455 6905 9445 17629 900000 18564 18283 14526 15720 8523 -14732 -3952 -446 11836 16700 -5163 4495 22476 30318 23411 1792 -13672 9126 -15413 15144 11172 5811 12687 4082 14284 5284 9650 14143 1902 5079 -15844 27873 7481 -6377 6981 -17535 462 -14567 -7147 -10470 8245 21405 -11165 -17364 -5892 -781 -32260 56066 15621 -7162 16976 -24096 -30415 -9857 8474 10111 21914 23525 SS 20240116T140447.9Z 8781.586665 61 1 54.76 2 83.16 126.34 116.39 62.85 0.00 1 0.00 1 0 25 6.380e-01 2.683e-02 2.282e-01 5.912e-03 1.362948e+00 3.662770e-03 1.534324e-02 -6.000000e+00 3.854799e-01 223.61 -2.00 3.53 -2.00 322.45 0.00e+00 -1.512247e-02 1.900010e-03 6.545600e-03 -6.000000e+00 1.779347e-02 273.22 -2.00 20.00 -2.00 322.08 0.00e+00 7.686 0.008 302.00 328.00 3 3.7363e-01 1.3674e-02 1.0768e-01 -6.0000e+00 9.5122e-01 2.2135e+00 1.6636e-02 7.5561e-02 -6.0000e+00 1.0363e+00 -2.7450e+00 1.2521e-02 4.2328e-02 -6.0000e+00 6.1320e-01 1.0596e+00 6.5562e-03 1.7264e-02 -6.0000e+00 2.5914e-01 4.0069e-05 -1.9479e-03 1.3843e-04 4.4238e-04 -6.0000e+00 2.0238e-02 -1.3359e-02 1.5995e-04 12 8 8 10 0 0 83.32 22.03 0.60 -0.01336 -0.02800 96 10 1 5 0 570.390 30.50 20.55 22.03 -14.82 8.2 690.52 -22750 -7035 -12386 185232 -36099 900000 -63492 -76319 9292 900000 -23640 -61427 128959 900000 -3994 900000 105764 103371 -676 83464 193780 118003 -5131 -19576 80961 -47445 900000 129483 -48686 -7642 900000 54023 -40507 -18589 900000 -24143 29725 900000 39981 -21782 230183 80911 182377 15971 22096 20275 90638 22076 900000 907 111250 87745 98014 76579 39438 142500 19092 192979 18096 51655 -10444 86803 295034 40019 114414 55998 19719 33618 47458 23253 38269 46753 77577 -639 42116 17609 -16968 14589 -16613 10625 458 3472 15991 9913 31677 10605 13777 10468 11559 2746 -4192 -4253 -5290 1037 2955 -7974 -5274 -2431 -861 -1724 -4203 -4682 -3383 -5697 -2625 -2892 -1991 -3830 -5593 -1998 -3436 -2789 -587 -261 -1359 -984 1350 53 -324 1243 136 2400 2604 969 3207 3562 5388 1084 -330 374 285 -737 3283 273 -407 897 133 -369 -690 -294 -396 -360 -1677 -1381 -364 -616 1066 -1511 900000 -2790 -3953 214 900000 -792 -3214 1147 900000 -178 900000 1826 1839 -33 1616 1115 1297 -185 -860 1398 -3004 900000 1152 -2267 -232 900000 1187 -2586 -992 900000 -1175 824 900000 1276 -1516 1590 2608 2099 910 1081 934 1982 966 900000 56 2561 2878 3215 3394 2724 3691 1736 2999 1479 2676 -920 2898 1698 2718 4148 3867 2043 3270 4479 3172 4956 5785 6876 -113 4218 1936 -2393 1537 -2744 1633 96 843 3958 2858 7766 3339 4306 3410 3659 907 -1392 -1344 -1702 343 1131 -4167 -3275 -1595 -639 -1376 -3358 -3405 -2323 -3616 -1604 -1854 -1340 -2868 -4431 -1825 -3838 -3614 -822 -383 -2042 -1459 1958 80 -466 1787 209 3337 3344 1207 3793 4102 6033 1334 -481 606 552 -1656 7290 686 -1119 2584 396 -1105 -2035 -820 -1006 -817 -3812 SS 20240116T141532.5Z 8781.594127 64 1 54.47 2 81.57 128.30 114.64 64.94 0.00 1 0.00 1 0 17 7.302e-01 2.117e-02 1.528e-01 2.338e-03 1.159239e+00 1.338249e-03 1.262363e-02 -6.000000e+00 4.320355e-01 223.61 -2.00 3.53 -2.00 321.88 0.00e+00 8.749419e-03 6.981644e-04 3.802352e-03 -6.000000e+00 1.863683e-02 273.22 -2.00 20.00 -2.00 321.49 0.00e+00 6.424 0.005 302.00 328.00 3 4.5169e-01 4.6959e-03 9.3142e-02 -6.0000e+00 1.0656e+00 1.0667e+00 7.0453e-03 7.6904e-02 -6.0000e+00 1.1570e+00 -1.3445e+00 7.6091e-03 3.6419e-02 -6.0000e+00 6.8823e-01 5.4036e-01 3.4995e-03 1.6370e-02 -6.0000e+00 2.9227e-01 1.6773e-04 -1.3896e-03 5.4271e-05 2.0344e-04 -6.0000e+00 2.2226e-02 -1.3748e-02 1.4617e-04 12 8 8 10 0 0 76.17 22.07 0.52 -0.01375 -0.02419 214 22 1 5 0 254.490 30.50 18.87 22.07 -14.32 8.2 693.30 -262151 -227781 -200325 -206887 -215606 -76308 -241325 -250007 -221642 210332 -177567 -231111 -118149 -13961 -149105 72996 -61157 -20825 -68465 -74503 -18636 -32611 -65873 -74329 -48386 -134926 62517 -29507 -93584 -79389 900000 -15913 -57097 -31977 57263 -19798 -21628 30119 3211 -57 70081 23208 61980 27409 29774 31008 61170 16854 88677 30134 61501 46151 48390 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