File name: Pandora249s1_ChicagoIL_20240326_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240327T060316.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240326_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240326T143115.4Z 8851.605039 310 1 0.20 2 60.37 116.28 115.50 281.16 0.00 1 0.00 1 0 17 2.009e-02 9.854e-03 1.802e-02 6.779e-03 3.489320e-01 3.569682e-03 4.235472e-03 -6.000000e+00 1.203931e-02 226.88 -2.00 3.53 -2.00 316.78 0.00e+00 1.237271e-03 4.488765e-04 1.013328e-04 -6.000000e+00 5.191966e-04 276.45 -2.00 20.00 -2.00 316.20 0.00e+00 2.014 0.000 302.00 328.00 3 1.8047e+00 9.3017e-03 2.6742e-02 -6.0000e+00 2.9889e-02 3.3470e-02 1.0386e-02 1.7878e-02 -6.0000e+00 3.2357e-02 -1.8807e-02 6.1221e-03 8.8619e-03 -6.0000e+00 1.9231e-02 5.1131e-03 2.9351e-03 2.6723e-03 -6.0000e+00 8.1248e-03 7.5151e-03 -1.1743e-04 2.0661e-04 3.3601e-05 -6.0000e+00 6.1180e-04 -1.8267e-02 2.0803e-04 12 9 9 12 1 1 999.00 25.06 0.30 -0.01827 -0.01915 1 57 1 5 0 97.300 32.25 20.05 25.06 18.39 9.6 927.54 -5115 -3638 274 -3597 -7203 -5418 2410 -1627 -1163 5249 -2044 -2907 -8285 -2386 -1183 2700 1595 -1841 2979 3720 1378 -2572 3263 2064 3541 -135 -1991 -396 2516 -1027 -3921 1822 1052 1103 341 -4914 -5475 -1424 -231 -2002 -3056 605 656 -102 -1719 -77 -2909 926 1064 1750 390 -1113 2627 2843 830 2116 -483 1187 1254 281 2200 393 3271 2471 990 712 -637 -828 575 1116 676 -397 811 -965 209 164 176 -1621 -1874 -522 -1176 -1732 -1548 -2552 -155 -906 -517 -435 -291 908 -1195 -28 -276 865 1580 -976 253 747 -805 -646 -423 -711 -1211 80 149 -414 104 -1251 -73 598 -82 858 114 143 1021 344 524 1175 71 -462 -92 -178 -452 370 578 766 910 1147 183 676 311 413 -788 -116 814 -458 -297 319 -24 107 -500 -1010 -612 -620 -493 38 -505 -972 -739 310 -219 -173 786 -340 -508 -1567 -496 -284 658 428 -542 879 1059 413 -808 981 656 1174 -46 -693 -132 830 -345 -1332 641 409 428 132 -1951 -2280 -610 -110 -1085 -1796 352 398 -64 -1099 -48 -1881 570 650 1073 253 -753 1835 2017 604 1566 -375 911 949 212 1651 305 2679 2123 864 607 -538 -678 478 980 637 -389 776 -947 197 147 148 -1356 -1532 -445 -1103 -1711 -1614 -2770 -169 -1033 -604 -529 -349 1084 -1416 -31 -292 893 1657 -1077 300 926 -1044 -857 -555 -891 -1457 96 181 -527 135 -1684 -100 847 -119 1286 172 210 1424 474 698 1584 100 -673 -136 -261 -649 522 797 1030 1197 1519 248 934 450 612 -1189 -180 1285 -739 -496 530 -41 179 -825 -1642 -980 SS 20240326T154937.6Z 8851.659463 357 1 1.13 2 48.54 135.57 128.99 296.53 0.00 1 0.00 1 0 17 1.457e-02 8.645e-03 1.121e-02 5.939e-03 2.616572e-01 3.149242e-03 3.200577e-03 -6.000000e+00 8.734897e-03 226.88 -2.00 3.53 -2.00 315.83 0.00e+00 6.096943e-04 3.163949e-04 1.056086e-04 -6.000000e+00 3.767093e-04 276.46 -2.00 20.00 -2.00 315.29 0.00e+00 1.508 0.000 302.00 328.00 3 3.8552e+00 8.1137e-03 2.0027e-02 -6.0000e+00 2.1685e-02 4.4545e-02 9.0186e-03 1.3384e-02 -6.0000e+00 2.3476e-02 -4.1563e-03 5.1967e-03 6.6201e-03 -6.0000e+00 1.3953e-02 -2.8591e-03 2.3728e-03 1.9534e-03 -6.0000e+00 5.8948e-03 1.7933e-03 -2.0932e-04 1.8317e-04 2.6701e-05 -6.0000e+00 4.4388e-04 -1.8560e-02 1.9036e-04 12 9 1 12 1 1 999.00 25.22 0.25 -0.01856 -0.02013 1 10 1 5 0 561.800 32.50 19.98 25.22 18.59 9.4 925.45 395 504 -5557 -3065 -5755 -5271 -2860 3761 4126 711 -1395 -1931 890 959 821 870 -371 249 -1635 2431 2419 172 -529 -994 1680 -1194 -704 -583 -856 -751 1876 2088 2946 1218 -2042 -1203 1164 1880 2312 2073 -1972 -922 194 -827 -559 -1356 -581 -2070 -1464 -1450 1371 767 1292 991 1223 1047 -727 171 282 795 537 1169 2327 1446 1170 -301 63 -776 -337 -648 509 -330 -284 -1270 706 -137 880 67 -1099 -1072 -129 -1301 -1926 -1205 -1417 -1096 39 154 -982 -81 509 501 1235 1584 245 740 1208 742 -256 411 -386 192 218 403 -649 -924 -1005 -368 68 -388 335 -429 -671 -68 736 -617 1378 198 355 -450 49 -911 -222 -80 958 1007 195 1924 779 -94 -459 266 596 11 219 -318 211 60 -326 56 -265 -1273 -11 78 110 -1344 -701 -1242 -1058 -567 761 920 175 -358 -507 246 277 270 295 -136 95 -658 970 988 72 -225 -412 712 -542 -320 -256 -381 -322 800 888 1335 587 -998 -565 554 939 1277 1269 -1333 -658 142 -622 -420 -1024 -430 -1521 -1047 -1031 976 583 985 797 973 854 -614 144 234 648 445 1012 2047 1371 1091 -286 56 -689 -303 -611 501 -334 -293 -1296 697 -131 787 56 -927 -976 -125 -1348 -2086 -1317 -1579 -1302 46 193 -1212 -100 595 559 1356 1633 259 802 1385 910 -330 537 -490 234 258 469 -772 -1176 -1297 -494 91 -540 473 -628 -974 -96 990 -808 1770 252 476 -626 68 -1291 -306 -111 1290 1287 248 2438 993 -125 -622 373 852 16 326 -486 323 94 -520 88 -406 -1961 -16 SS 20240326T155355.8Z 8851.662452 360 1 11.28 2 47.99 136.81 129.69 297.50 0.00 1 0.00 1 0 17 8.191e-03 5.266e-03 1.631e-03 9.005e-04 2.555648e-01 4.779804e-04 3.120085e-03 -6.000000e+00 4.910630e-03 226.88 -2.00 3.53 -2.00 315.73 0.00e+00 3.010430e-04 4.720846e-05 4.809100e-05 -6.000000e+00 2.116970e-04 276.46 -2.00 20.00 -2.00 315.19 0.00e+00 1.492 0.000 302.00 328.00 3 3.1213e+00 1.2307e-03 1.9690e-02 -6.0000e+00 1.2191e-02 2.9221e-02 1.3683e-03 1.3046e-02 -6.0000e+00 1.3196e-02 -5.5144e-03 7.8686e-04 6.4605e-03 -6.0000e+00 7.8435e-03 8.3571e-04 3.5602e-04 1.8502e-03 -6.0000e+00 3.3149e-03 3.8688e-03 4.6212e-04 2.7777e-05 2.5486e-05 -6.0000e+00 2.4944e-04 -1.8666e-02 2.8511e-04 12 1 1 12 1 1 100.00 25.22 0.32 -0.01867 -0.01519 83 41 1 5 0 134.270 32.50 20.00 25.22 18.65 9.5 927.58 -119 -1088 -2349 -3606 -3641 -2458 -750 9 1041 138 -1700 -922 84 928 1073 583 196 666 1085 623 1056 664 897 708 529 75 -425 -1111 -366 -9 802 1386 998 -368 -964 -1284 -582 53 730 152 -439 -673 -849 -673 -762 -527 -490 -841 -557 -19 426 722 992 654 521 521 584 538 347 640 1043 1155 1380 836 105 -78 -255 -74 314 653 265 -83 -201 -225 -8 -101 -81 -23 -129 -422 -816 -1111 -1535 -1313 -995 -770 -698 -297 -10 -114 309 321 367 679 1058 719 525 355 2 -67 -202 -343 -127 75 -404 -624 -661 -420 -394 -79 -17 -103 -68 44 133 413 443 501 118 -92 -190 2 -95 160 601 444 707 1024 721 400 345 -62 3 137 -42 -104 0 -78 -353 -399 -165 -303 -416 -26 -265 -556 -907 -840 -524 -159 2 262 34 -442 -242 24 292 355 215 77 253 426 254 438 278 378 310 244 34 -195 -527 -162 -4 345 633 461 -179 -465 -601 -281 29 436 95 -295 -484 -634 -511 -579 -398 -365 -614 -397 -13 308 551 763 531 420 431 491 454 290 527 868 1009 1239 772 100 -72 -227 -66 282 612 264 -85 -210 -230 -8 -97 -73 -19 -109 -384 -765 -1113 -1609 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