File name: Pandora249s1_ChicagoIL_20240328_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T091203.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240328_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240328 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240328T122321.2Z 8853.516217 233 1 54.78 2 82.67 92.16 85.25 238.98 0.00 1 0.00 1 0 25 6.363e-01 3.617e-02 2.656e-01 9.868e-03 1.220034e+00 5.996366e-03 1.443424e-02 -6.000000e+00 3.841770e-01 227.03 -2.00 3.53 -2.00 322.28 0.00e+00 -2.203041e-02 2.735326e-03 3.592494e-03 -6.000000e+00 1.777128e-02 276.66 -2.00 20.00 -2.00 321.86 0.00e+00 7.250 0.007 302.00 328.00 3 1.7316e+00 2.1025e-02 9.6356e-02 -6.0000e+00 9.5331e-01 2.0059e+00 2.5451e-02 6.7072e-02 -6.0000e+00 1.0336e+00 -2.5227e+00 1.7810e-02 3.6322e-02 -6.0000e+00 6.1368e-01 9.7865e-01 9.4313e-03 2.2388e-02 -6.0000e+00 2.6194e-01 1.8222e-05 -2.9278e-03 2.4292e-04 4.2602e-04 -6.0000e+00 1.9698e-02 -5.7082e-03 0.0000e+00 12 8 8 10 0 0 85.07 24.00 0.80 -0.00571 -0.02771 45 5 1 5 0 1217.100 31.75 20.45 24.00 6.47 9.1 844.53 900000 26558 -6198 155247 -23714 178214 -38690 -69851 57407 900000 62590 -49895 61525 900000 20197 104637 35122 72627 47381 238980 204339 71029 -9621 1457 75069 -60015 900000 176154 -20290 39373 900000 900000 -53288 10187 156020 5245 37744 113541 76455 -23749 225484 53455 78344 65801 45205 -4056 84979 -15213 900000 -260 78648 132681 104462 51293 56250 74332 26715 147190 27834 40164 -22860 108849 214166 24708 68328 55652 1838 24311 38769 7099 25488 46524 77920 -12191 26869 32983 -41845 15374 -29100 2988 -11198 -46 16639 13367 39151 22152 15455 12303 9737 5868 -2727 4172 -12630 5707 7452 -7652 -3030 -6365 2062 -3933 -2119 -9560 -2201 -10194 2794 -2419 -190 -4340 -6111 -2637 -2363 -379 -176 -173 -62 -1994 1245 401 -1027 1265 43 1675 2724 1375 3306 4217 4728 1164 -1182 -466 -415 -937 4127 558 -790 1104 -90 -742 -849 705 -879 -357 -1620 900000 1624 -482 2035 -1492 1713 -2265 -5981 1505 900000 1695 -4316 1881 900000 1112 2651 1841 2602 2111 2297 1964 1924 -563 81 2230 -7236 900000 1693 -1188 1170 900000 900000 -5307 561 1908 266 1352 2083 2405 -2428 2384 3339 3765 3352 2563 -343 2777 -1330 900000 -22 3250 3570 4116 3746 4217 4929 2953 4810 2782 3165 -3076 3871 2882 2493 4925 4760 276 3084 4695 1337 4434 6886 8312 -2964 3899 3899 -9410 1950 -6404 569 -2970 -13 4557 4150 9971 7004 5392 4493 3603 2166 -1030 1391 -4952 1991 2944 -4214 -1913 -4906 1665 -3583 -1855 -8232 -1553 -7142 1724 -1653 -134 -3470 -5603 -2740 -2636 -477 -242 -248 -89 -2862 1721 573 -1547 1907 65 2317 3486 1706 4292 5285 5803 1537 -1661 -777 -812 -2095 9692 1358 -2113 3082 -261 -2184 -2469 1930 -2246 -895 -3779 SS 20240328T133732.6Z 8853.567738 272 1 54.15 2 69.05 105.13 97.51 250.85 0.00 1 0.00 1 0 17 2.924e-01 2.061e-02 1.115e-01 6.009e-03 5.301837e-01 3.206446e-03 6.383024e-03 -6.000000e+00 1.748638e-01 227.03 -2.00 3.53 -2.00 319.87 0.00e+00 -1.141860e-03 9.584968e-04 9.448577e-04 -6.000000e+00 7.567504e-03 276.67 -2.00 20.00 -2.00 319.32 0.00e+00 2.770 0.000 302.00 328.00 3 6.0253e+00 9.1564e-03 3.9448e-02 -6.0000e+00 4.3419e-01 1.9469e-01 1.0857e-02 2.8996e-02 -6.0000e+00 4.7051e-01 -2.2303e-01 8.6345e-03 1.3983e-02 -6.0000e+00 2.7967e-01 1.0312e-01 4.4276e-03 4.5871e-03 -6.0000e+00 1.1753e-01 4.0814e-05 -2.9805e-03 1.8377e-04 5.7014e-05 -6.0000e+00 8.9111e-03 8.5023e-03 0.0000e+00 12 8 8 10 0 0 99.99 24.17 0.20 0.00850 -0.01389 44 4 1 5 0 1230.590 31.75 20.04 24.17 8.26 9.1 856.68 -108140 -38367 -91324 -9781 -95612 196408 -98901 -105813 -51318 537 -25044 -97434 -776 22917 -27584 -6946 -5999 20657 451 12660 48166 -5774 -16630 -11666 5848 -36009 39422 15073 -5180 -5921 34269 20143 -18258 -14890 19259 -4344 -3957 17536 1819 -4795 16650 -120 6426 14632 1776 3183 5202 -3357 16312 20723 15709 16815 498 2821 3176 6284 -152 5637 -1015 130 -6043 5986 10659 817 4252 1477 -3184 680 2865 -3491 15 637 5288 -2311 2627 985 -6552 -3373 -10681 -3802 -4439 -2532 -2045 682 3474 919 1215 -871 927 -495 -1752 -118 -1932 380 968 -3790 -1188 -495 1046 -458 -756 -2165 104 -3130 314 -1747 -574 711 -830 168 -29 862 698 -55 -314 -344 1073 233 -264 378 -565 1004 356 1389 221 2066 1525 1352 -283 1593 -451 -532 2697 742 -999 78 141 -840 -1134 478 -677 -390 -864 -4493 -920 -3989 -188 -4024 1151 -4109 -5186 -1640 11 -707 -6021 -23 631 -1503 -358 -341 968 27 712 1947 -403 -1316 -930 422 -4178 2195 1042 -419 -479 1988 1523 -2279 -1937 1783 -496 -468 1901 276 -927 2966 -27 1439 3078 426 752 1204 -848 3431 4311 3664 4237 161 957 1139 2276 -60 2127 -402 50 -2457 2273 4235 393 2095 744 -1621 330 1430 -2066 10 428 3439 -1568 1581 547 -3567 -1702 -6027 -2250 -3046 -1935 -1717 597 3137 824 1145 -869 916 -484 -1640 -111 -1735 326 870 -3618 -1255 -586 1336 -612 -978 -2618 113 -3395 342 -2066 -705 913 -1157 253 -47 1487 1221 -94 -508 -526 1576 352 -421 628 -965 1662 574 2133 329 2880 2052 1813 -410 2492 -785 -986 5049 1356 -1960 160 299 -1822 -2477 1005 -1373 -746 -1732 SS 20240328T134714.1Z 8853.574469 275 1 5.40 2 67.31 106.95 99.18 252.32 0.00 1 0.00 1 0 25 4.516e-02 6.089e-03 1.064e-02 1.434e-03 4.963004e-01 7.562879e-04 5.905997e-03 -6.000000e+00 2.706638e-02 227.03 -2.00 3.53 -2.00 318.38 0.00e+00 7.962745e-04 1.484301e-04 1.725041e-04 -6.000000e+00 1.171324e-03 276.67 -2.00 20.00 -2.00 317.79 0.00e+00 2.572 0.000 302.00 328.00 3 2.1423e+00 2.0313e-03 3.6132e-02 -6.0000e+00 6.7213e-02 3.0898e-02 2.3003e-03 2.5557e-02 -6.0000e+00 7.2820e-02 -4.1966e-02 1.5848e-03 1.2731e-02 -6.0000e+00 4.3252e-02 1.5277e-02 8.3367e-04 3.7584e-03 -6.0000e+00 1.8330e-02 2.6073e-03 -3.9371e-04 4.2431e-05 4.4860e-05 -6.0000e+00 1.3841e-03 -6.7823e-03 0.0000e+00 12 1 1 12 1 1 98.75 24.19 0.30 -0.00678 -0.00974 40 42 1 5 0 131.490 31.75 19.69 24.19 8.53 9.0 858.19 900000 -12974 -14166 -20439 -18408 -21542 -15196 -11795 -8179 -9126 -11869 -15332 -6574 -8400 -4313 -4076 -1898 -1170 -2354 -3254 -298 98 -1903 -1500 -1127 -2215 -1920 -2855 -1399 -3295 864 646 -517 -653 -986 -927 -1629 -918 -885 -411 -995 -366 101 626 1133 638 863 -208 572 934 924 1437 1720 1901 1296 982 954 777 529 741 1167 1016 1650 1527 587 366 118 74 568 347 102 -237 -224 -358 212 184 -454 -282 -375 -433 -797 -1296 -1632 -1648 -1300 -1203 -690 -428 -237 -18 386 582 399 598 942 638 705 247 -496 -226 -238 -581 -59 177 -744 -996 -883 -478 -198 57 220 -254 182 -26 263 556 748 578 244 -263 -315 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