File name: Pandora249s1_ChicagoIL_20240330_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240331T055845.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240330_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240330 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240330T131540.6Z 8855.552554 264 1 54.48 2 72.37 100.67 84.67 226.18 0.00 1 0.00 1 0 25 1.467e-01 5.805e-03 1.085e-02 5.296e-04 6.099916e-01 2.810606e-04 7.135387e-03 -6.000000e+00 8.793288e-02 227.18 -2.00 3.53 -2.00 319.42 0.00e+00 1.293505e-03 7.712694e-05 3.377559e-04 -6.000000e+00 3.797595e-03 276.89 -2.00 20.00 -2.00 318.85 0.00e+00 3.256 0.001 302.00 328.00 3 1.4433e+00 7.8559e-04 4.5237e-02 -6.0000e+00 2.1841e-01 3.7007e-02 9.2438e-04 3.1860e-02 -6.0000e+00 2.3646e-01 -5.4334e-02 7.7608e-04 1.6056e-02 -6.0000e+00 1.4054e-01 1.6525e-02 4.0945e-04 4.9842e-03 -6.0000e+00 5.9303e-02 2.4085e-03 -7.1557e-04 1.5132e-05 5.7375e-05 -6.0000e+00 4.4681e-03 -1.4574e-02 1.0518e-04 10 0 0 10 0 0 99.82 24.95 0.31 -0.01457 -0.01995 742 75 1 5 0 73.410 32.25 20.03 24.95 16.37 9.5 913.61 -57378 -44113 -41362 -55572 -39439 -50270 -56965 -48425 -40493 -36381 -43608 -40594 -28465 -23411 -21796 -10135 -12286 -9888 -7958 -10547 -4691 -6960 -6990 -9877 -7226 -8587 -4123 -9406 -7728 -8670 -2392 -102 -1884 -1448 -2817 -2709 -2296 -977 349 611 185 -724 84 175 -306 678 722 -125 442 611 1573 1620 2000 1816 1732 1335 892 603 165 499 919 1424 2186 1644 1222 724 626 465 801 834 364 225 -105 -184 -345 -492 -406 -501 -687 -703 -970 -1038 -1496 -1447 -1096 -963 -541 -170 -78 110 447 695 640 912 838 509 400 266 -172 -144 -378 -508 -167 84 -616 -938 -923 -599 -415 17 -12 -187 -16 112 315 577 662 426 79 -200 -304 -116 -34 64 407 408 648 1015 692 378 166 96 30 103 -127 -221 -49 -55 -317 -233 -91 -205 -133 -708 -570 -570 -893 -513 -709 -903 -793 -696 -663 -921 -925 -691 -679 -777 -387 -551 -481 -413 -598 -261 -404 -421 -659 -511 -658 -312 -743 -591 -695 -203 -10 -217 -182 -363 -346 -309 -136 58 122 43 -185 21 45 -80 178 193 -35 126 184 510 583 729 722 738 599 416 285 77 228 423 696 1097 926 693 416 353 265 485 531 260 172 -77 -138 -241 -334 -252 -302 -440 -483 -733 -849 -1366 -1346 -1081 -960 -567 -184 -85 117 450 684 596 839 824 538 463 336 -230 -191 -506 -628 -196 99 -726 -1178 -1168 -802 -573 24 -19 -297 -27 177 492 852 995 630 123 -315 -486 -181 -54 96 610 586 934 1459 1030 605 283 170 54 187 -245 -438 -98 -112 -645 -462 -178 -390 -249 SS 20240330T132138.9Z 8855.556701 267 1 54.48 2 71.28 101.74 85.46 227.21 0.00 1 0.00 1 0 25 1.142e-01 5.961e-03 6.124e-03 4.138e-04 5.798909e-01 2.188285e-04 6.817840e-03 -6.000000e+00 6.847016e-02 227.18 -2.00 3.53 -2.00 319.10 0.00e+00 9.629874e-04 5.407597e-05 2.563996e-04 -6.000000e+00 2.956443e-03 276.89 -2.00 20.00 -2.00 318.53 0.00e+00 3.078 0.000 302.00 328.00 3 1.1952e+00 6.0276e-04 4.2811e-02 -6.0000e+00 1.7007e-01 2.7424e-02 6.9698e-04 3.0086e-02 -6.0000e+00 1.8411e-01 -5.1800e-02 5.4628e-04 1.5078e-02 -6.0000e+00 1.0943e-01 1.7366e-02 2.8992e-04 4.5556e-03 -6.0000e+00 4.6185e-02 3.7901e-03 -4.3925e-04 1.1893e-05 5.3661e-05 -6.0000e+00 3.4779e-03 -1.5209e-02 1.4740e-04 10 0 0 10 0 0 94.00 24.97 0.28 -0.01521 -0.01851 823 83 1 5 0 66.190 32.25 20.02 24.97 16.96 9.4 917.78 -46819 -34523 -37844 -33362 -40620 -47109 -42306 -40857 -31403 -27140 -29031 -24462 -20945 -16313 -11284 -8173 -7186 -5214 -3511 -6201 -3006 -3299 -5712 -4666 -3117 -4610 -3702 -4620 -5998 -4850 -1525 324 -421 -1872 -2403 -3008 -1683 -1383 582 -24 93 -413 45 220 46 405 229 -43 525 704 1777 1533 2171 1679 1621 1416 925 749 135 352 828 1297 1819 1667 933 702 522 452 694 865 552 185 -45 -186 -369 -466 -427 -294 -460 -682 -788 -1122 -1706 -1599 -1187 -935 -808 -353 -63 -38 484 728 639 822 777 522 494 223 -186 -273 -386 -508 -129 60 -604 -904 -863 -549 -423 -58 74 -209 115 164 300 539 629 523 127 -227 -300 -33 10 100 453 379 653 1072 721 424 269 51 72 125 -168 -185 -80 -54 -308 -324 -155 -237 -166 -809 -626 -774 -657 -816 -979 -879 -940 -746 -681 -797 -707 -696 -644 -524 -440 -436 -343 -246 -474 -231 -260 -476 -413 -296 -473 -388 -483 -623 -513 -174 39 -58 -285 -372 -464 -271 -256 128 -6 26 -117 13 68 14 128 74 -14 177 249 675 599 927 782 754 691 469 384 69 175 415 689 1001 1021 579 439 319 278 452 595 402 145 -36 -143 -279 -321 -285 -190 -313 -500 -636 -987 -1596 -1533 -1205 -965 -880 -380 -68 -42 505 737 611 811 778 563 562 278 -247 -361 -512 -646 -156 70 -733 -1125 -1132 -732 -585 -85 115 -335 182 260 466 791 933 766 196 -357 -480 -51 16 151 675 541 927 1516 1059 670 438 87 129 226 -314 -356 -155 -106 -611 -629 -295 -439 -302 SS 20240330T132708.5Z 8855.560515 270 1 54.47 2 70.28 102.74 86.20 228.15 0.00 1 0.00 1 0 25 8.818e-02 5.853e-03 4.652e-03 3.698e-04 5.559492e-01 1.953117e-04 6.545890e-03 -6.000000e+00 5.289310e-02 227.18 -2.00 3.53 -2.00 318.90 0.00e+00 1.031090e-03 4.527817e-05 2.389455e-04 -6.000000e+00 2.283322e-03 276.89 -2.00 20.00 -2.00 318.32 0.00e+00 2.932 0.000 302.00 328.00 3 1.1433e+00 5.3375e-04 4.0874e-02 -6.0000e+00 1.3138e-01 2.1482e-02 6.1243e-04 2.8773e-02 -6.0000e+00 1.4221e-01 -4.3758e-02 4.6207e-04 1.4363e-02 -6.0000e+00 8.4526e-02 1.4340e-02 2.4551e-04 4.3747e-03 -6.0000e+00 3.5685e-02 4.7055e-03 -2.3091e-04 1.0697e-05 5.0523e-05 -6.0000e+00 2.6860e-03 -1.5914e-02 1.8393e-04 10 0 0 10 0 0 78.60 25.00 0.29 -0.01591 -0.01765 927 94 1 5 0 58.750 32.25 20.04 25.00 17.70 9.5 922.47 -34705 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