File name: Pandora249s1_ChicagoIL_20240504_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T092656.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240504_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240504T111649.8Z 8890.470021 96 1 53.25 2 84.79 72.87 66.18 121.18 0.00 1 0.00 1 0 17 7.115e-01 1.177e-01 3.176e-01 4.088e-02 1.106182e+00 2.577741e-02 1.400275e-02 -6.000000e+00 4.396682e-01 230.07 -2.00 3.53 -2.00 320.85 0.00e+00 -3.654494e-02 5.046487e-03 2.711135e-03 -6.000000e+00 2.012567e-02 280.78 -2.00 20.00 -2.00 320.02 0.00e+00 9.533 0.016 302.00 328.00 3 7.5152e-01 7.3278e-02 1.1974e-01 -6.0000e+00 1.1009e+00 2.8869e+00 8.4918e-02 9.9055e-02 -6.0000e+00 1.1940e+00 -2.3750e+00 4.7869e-02 2.7753e-02 -6.0000e+00 7.0397e-01 6.8561e-01 2.4745e-02 3.2338e-02 -6.0000e+00 2.9580e-01 4.0110e-06 -2.0802e-03 1.0447e-03 4.8442e-04 -6.0000e+00 2.2407e-02 -4.3700e-03 0.0000e+00 12 8 8 10 0 0 64.65 24.95 1.75 -0.00437 -0.02000 15 2 1 5 0 3549.580 32.25 20.06 24.95 17.64 9.5 920.18 900000 178765 6401 113173 9987 900000 -26740 -37272 186098 173165 178566 2647 108866 900000 206422 75572 92889 900000 165459 900000 97947 36018 -33153 8202 110341 -29992 141093 900000 109825 900000 900000 900000 -23859 6400 -10097 -15149 1082 130553 67582 42123 900000 10111 50433 153845 58031 3764 69837 -60591 82435 -10401 162903 900000 62839 30593 39395 900000 24470 134263 58469 159320 -35144 52804 279899 15770 35972 70050 6 27124 21469 -21714 51044 70239 900000 -7786 24977 173704 -56374 -20567 -89146 -2301 -3619 -5469 37587 47728 119551 57782 43670 31763 46791 15362 -14301 4280 16440 8002 51922 -4288 -914 4351 34010 5721 -3375 -11941 16399 -26893 32128 -5214 1611 8278 -1007 -2312 7683 14417 -1626 -6484 -3283 903 18570 7397 -9195 3832 -7216 -2094 -6480 -2524 1396 15498 15872 1131 -7663 -3395 561 -7662 12658 13529 -4544 -834 -2794 -4406 -2023 3295 -2543 2904 7668 900000 9477 1697 8625 1721 900000 -5936 -10744 7400 8033 8283 728 10461 900000 8208 10267 10465 900000 8971 900000 8851 5598 -10306 1897 10769 -13009 10710 900000 7940 900000 900000 900000 -6209 1249 -2190 -3176 192 7079 8306 8070 900000 3180 10209 10010 8600 843 7321 -22121 7151 -2369 7066 900000 8858 6414 8117 900000 6457 11648 9933 8638 -11814 7062 11129 3477 6891 9622 2 5883 5355 -9340 11624 15081 900000 -2983 6654 8979 -25777 -6379 -58840 -732 -1367 -2436 12255 15182 19489 18150 16148 13261 16372 6963 -8074 1872 6210 3436 16103 -2711 -650 3373 21772 5050 -3140 -10967 10042 -23525 15713 -3877 1172 6024 -889 -2371 8248 16280 -2308 -9874 -4777 1224 20822 9441 -14331 5363 -11076 -2889 -8786 -3151 1620 15159 15146 1290 -10786 -5386 991 -16482 24360 28080 -12250 -2316 -8188 -13279 -5919 8805 -6693 6639 15641 SS 20240504T112837.9Z 8890.478217 99 1 54.70 2 82.69 74.78 64.33 123.60 0.00 1 0.00 1 0 17 6.048e-01 2.452e-02 2.789e-01 6.151e-03 9.719236e-01 3.624058e-03 1.082701e-02 -6.000000e+00 3.678032e-01 230.07 -2.00 3.53 -2.00 322.01 0.00e+00 4.116542e-04 2.053414e-03 4.242125e-03 -6.000000e+00 1.642397e-02 280.78 -2.00 20.00 -2.00 321.57 0.00e+00 7.256 0.007 302.00 328.00 3 1.4827e+00 1.3963e-02 9.3188e-02 -6.0000e+00 9.2069e-01 1.0431e+00 1.8978e-02 6.5234e-02 -6.0000e+00 9.9568e-01 -1.3706e+00 1.7394e-02 3.0243e-02 -6.0000e+00 5.9001e-01 5.5401e-01 7.9957e-03 9.2447e-03 -6.0000e+00 2.4915e-01 3.4798e-05 -2.2515e-03 1.6615e-04 1.3666e-04 -6.0000e+00 1.8630e-02 -6.8229e-03 0.0000e+00 12 8 8 10 0 0 82.09 24.98 0.60 -0.00682 -0.02374 66 7 1 5 0 828.610 32.25 19.98 24.98 18.37 9.6 925.96 900000 -20129 -180622 7760 -125021 -104713 -112069 -149029 -11121 900000 -77384 -121707 20505 900000 -99670 900000 -69576 171844 282 108298 45413 3507 -61604 -29746 26447 -114864 101051 -5937 4015 -37263 363487 203276 -60518 -16777 80271 -19212 80298 54112 2587 11198 94587 -19212 105711 33056 38065 52903 35852 -2526 122755 48430 42813 107296 66957 29212 59410 59631 17715 43497 17351 20923 12352 37206 57622 25387 30189 44481 20606 16859 14961 6929 12562 18202 26328 7347 10341 8188 -5019 4585 -22273 -6965 -2074 -1292 2491 1674 8826 6108 3654 2228 2980 -1299 -2576 -4 -5353 629 161 -6641 -3586 -2900 -661 -1213 -932 -2858 -2053 -4441 -1521 -2244 -2340 -2501 -4017 -1841 -2036 -776 -1071 -490 -942 159 -802 1211 197 1094 665 1104 2158 1326 1129 3588 2425 1333 967 408 441 477 1644 901 -376 255 211 -426 -867 126 -941 -650 -1095 900000 -176 -8169 51 -2725 -1655 -1832 -3654 -73 900000 -1054 -2785 134 900000 -3367 900000 -2351 1030 5 708 544 61 -2014 -729 389 -7135 716 -116 68 -975 2179 1218 -3232 -631 1251 -772 1203 1168 110 517 2154 -1474 2408 1565 1688 1998 1612 -171 2502 2235 2310 3409 3532 2451 3953 4146 1922 3624 1799 1982 1244 3055 4317 2998 3764 5013 2989 2648 2610 1483 2839 4124 5508 1757 2176 1566 -1002 830 -5834 -1862 -636 -463 978 722 3777 2845 1827 1165 1552 -688 -1311 -2 -2577 296 85 -4451 -2526 -2386 -604 -1178 -883 -2537 -1619 -3356 -1137 -1789 -1980 -2289 -4148 -2133 -2729 -1150 -1557 -720 -1492 243 -1226 1868 295 1684 1024 1774 3257 1940 1601 4818 3225 1840 1500 681 844 1016 3760 2063 -938 672 576 -1183 -2412 337 -2368 -1504 -2582 SS 20240504T113930.8Z 8890.485774 102 1 54.30 2 80.72 76.52 62.67 125.90 0.00 1 0.00 1 0 17 6.293e-01 1.018e-02 1.513e-01 2.339e-03 8.253602e-01 1.323196e-03 9.140843e-03 -6.000000e+00 3.815438e-01 230.07 -2.00 3.53 -2.00 321.25 0.00e+00 2.500708e-03 6.549983e-04 8.417453e-04 -6.000000e+00 1.660202e-02 280.78 -2.00 20.00 -2.00 320.76 0.00e+00 5.897 0.004 302.00 328.00 3 1.5960e+00 4.4674e-03 7.3444e-02 -6.0000e+00 9.5303e-01 2.2332e-01 6.4461e-03 4.6698e-02 -6.0000e+00 1.0295e+00 -2.9455e-01 6.8922e-03 2.4916e-02 -6.0000e+00 6.1147e-01 1.1360e-01 3.2331e-03 9.3942e-03 -6.0000e+00 2.5850e-01 1.4461e-04 -6.8726e-04 6.3771e-05 1.0811e-04 -6.0000e+00 1.9307e-02 -7.2154e-03 0.0000e+00 12 8 8 10 0 0 82.53 25.05 0.52 -0.00722 -0.01238 134 14 1 5 0 405.180 32.25 20.02 25.05 19.23 9.5 931.08 900000 -187381 -250105 -196253 -124281 -241662 -245627 -226333 -178071 21449 -205327 -173078 -118425 -52907 -145817 -49215 -96478 -38692 -72373 -80344 -37421 -16898 -96375 -83342 -31862 -100045 -26921 -41934 -46564 -73319 -13700 -14826 -49059 -29448 -23070 -23526 8668 6415 -88 -5126 15573 -10133 11370 14372 -820 341 5102 -4731 4902 5234 7084 20705 8187 5498 6948 8756 4165 8839 1155 3591 -3219 3270 7806 3498 5793 7508 3088 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