File name: Pandora249s1_ChicagoIL_20240530_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240531T055515.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240530_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240530 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240530T105428.7Z 8916.454498 153 1 54.34 2 84.95 64.94 56.66 162.61 0.00 1 0.00 1 0 25 7.711e-01 6.659e-02 3.089e-01 2.436e-02 1.327876e+00 1.610499e-02 1.764302e-02 -6.000000e+00 4.885811e-01 231.91 -2.00 3.53 -2.00 322.29 0.00e+00 -4.707517e-02 5.630695e-03 7.023849e-03 -6.000000e+00 2.380951e-02 283.55 -2.00 20.00 -2.00 321.75 0.00e+00 9.739 0.017 302.00 328.00 3 -1.4556e-01 5.5957e-02 1.1888e-01 -6.0000e+00 1.2246e+00 2.8997e+00 6.5372e-02 7.1198e-02 -6.0000e+00 1.3257e+00 -2.8972e+00 3.5253e-02 3.7511e-02 -6.0000e+00 7.8631e-01 9.5091e-01 2.0385e-02 2.8866e-02 -6.0000e+00 3.3102e-01 7.8653e-06 -1.3382e-03 5.9267e-04 6.9941e-04 -6.0000e+00 2.4908e-02 -1.0328e-02 1.7092e-04 12 8 8 10 0 0 44.56 24.63 1.66 -0.01033 -0.02038 37 4 1 5 0 1468.440 32.00 19.88 24.63 14.42 9.4 898.02 18050 73816 -9430 900000 -15228 900000 -28972 16312 62447 900000 91285 58643 63785 900000 35690 91713 81054 900000 115478 900000 900000 14875 -27092 12803 150760 -40650 900000 399952 76860 900000 900000 900000 -68589 -15457 118124 -51084 -27912 900000 24719 67426 248287 -10449 104155 900000 47488 -10810 62770 -62029 368254 -31638 900000 900000 128125 56090 56971 174708 45129 900000 20966 66247 -47478 16991 900000 34588 44838 221895 14335 -10229 55961 23225 58486 110520 161121 -12845 21584 92106 -23747 7746 -89054 47406 11284 14408 37807 43351 125213 57547 30669 16999 60573 5547 -14212 29603 -10754 17707 24269 -12303 4870 11410 26251 5990 -281 -10456 20341 -11140 11041 -1349 9076 -5058 -8525 -5051 -2978 5348 2154 -4461 1336 -4421 2269 1089 -8647 3812 -2917 -2343 -2095 2847 547 7082 13084 -202 -3987 33 -1270 -2612 3715 4646 -2520 1961 -1129 -1174 -1359 1920 -2239 1081 735 2564 5387 -1339 900000 -1442 900000 -3029 1319 3819 900000 5042 4627 4781 900000 3687 5329 5058 900000 4473 900000 900000 1184 -3381 1267 4542 -9097 900000 9467 3308 900000 900000 900000 -12251 -1630 3050 -6596 -2883 900000 2128 4643 5877 -1866 5603 900000 3372 -1186 2972 -9744 8717 -3949 900000 900000 4411 4345 4781 4887 4856 900000 2572 4419 -8582 1536 900000 3357 4245 5252 1934 -1889 5961 3903 7614 8895 7628 -3162 3270 5887 -4328 1027 -34360 5499 2244 3274 7786 9236 12448 11715 8348 5312 11901 1786 -5181 6587 -3589 4820 7181 -6261 2478 6347 14168 4154 -201 -7499 9437 -6513 5201 -754 4812 -3341 -6578 -4436 -3045 5810 2652 -6135 1746 -6038 2889 1435 -12997 5144 -4088 -3050 -2539 3147 602 7141 12296 -228 -5427 52 -2405 -5738 8548 11690 -6774 5403 -3317 -3478 -3990 5206 -5811 2698 1705 SS 20240530T110607.1Z 8916.462582 156 1 54.34 2 82.97 66.79 56.04 165.86 0.00 1 0.00 1 0 17 5.901e-01 2.266e-02 2.022e-01 4.067e-03 1.128912e+00 2.452297e-03 1.232716e-02 -6.000000e+00 3.610533e-01 231.91 -2.00 3.53 -2.00 322.13 0.00e+00 -6.962728e-04 1.476324e-03 2.459309e-03 -6.000000e+00 1.621107e-02 283.55 -2.00 20.00 -2.00 321.70 0.00e+00 7.502 0.008 302.00 328.00 3 2.3025e-01 9.8231e-03 9.9229e-02 -6.0000e+00 9.0372e-01 1.2769e+00 1.4060e-02 7.0424e-02 -6.0000e+00 9.7401e-01 -1.6283e+00 1.3046e-02 3.5133e-02 -6.0000e+00 5.7932e-01 6.4112e-01 5.8170e-03 1.1644e-02 -6.0000e+00 2.4392e-01 7.8169e-05 -1.1823e-03 1.0000e-04 1.6852e-04 -6.0000e+00 1.8094e-02 -1.1407e-02 1.9951e-04 12 8 8 10 0 0 22.50 24.67 0.61 -0.01141 -0.02029 144 15 1 5 0 377.280 32.00 20.17 24.67 15.07 9.4 903.02 -148082 -104965 -174034 -99955 -143944 -49190 -176592 -162833 -130624 -64858 -191727 -140156 -50152 105448 -121974 26654 -51806 221724 -26744 -68897 89798 -5690 -84316 -32926 17079 -129798 900000 -29597 -15481 -88670 900000 39283 -55458 5651 67172 -23258 12455 31023 9395 70593 137487 38272 66795 67996 22088 45750 50577 19368 65381 49815 60300 101638 51640 48991 63600 68460 37408 61106 28799 33952 18752 37624 49808 27317 38908 41238 24854 26823 26446 15971 18902 27810 25495 11021 9736 6714 -804 10754 -18970 291 272 1717 3658 4504 8986 7378 1499 908 1869 1113 -730 -1049 -4667 503 -1740 -4693 -2216 -2608 -1841 -2704 -1422 -2822 -1613 -3479 -1155 -3927 -2357 -2326 -2948 -2306 -1659 -1719 -299 -510 -388 -229 144 -16 -497 1173 832 1895 1470 1772 2147 2012 2782 1047 624 673 591 472 801 488 147 98 454 -294 -461 -402 -229 -747 -1547 -2776 -1438 -4831 -1225 -2387 -284 -3565 -2994 -1836 -491 -5391 -2627 -470 418 -3737 221 -1064 879 -482 -1888 486 -76 -2432 -593 197 -6644 900000 -512 -223 -2813 900000 561 -2179 143 906 -738 282 652 291 1400 1581 1275 1722 1726 867 1397 1484 806 1841 1797 2200 2781 2601 2778 3354 3610 2759 3513 2170 2275 1420 2476 3278 2600 3687 4023 2947 3318 3639 2780 3560 5051 4701 2194 1757 1102 -131 1591 -4288 66 75 553 1323 1764 3581 3151 707 442 899 523 -331 -452 -2061 224 -912 -2766 -1538 -2157 -1723 -2706 -1371 -2517 -1261 -2571 -844 -3116 -1953 -2093 -3004 -2495 -2090 -2463 -455 -800 -604 -349 219 -26 -820 1959 1373 2930 2148 2478 2897 2646 3574 1425 974 1151 1178 986 1829 1214 370 264 1249 -822 -1281 -1074 -604 -1811 -3517 SS 20240530T111655.3Z 8916.470084 159 1 54.40 2 81.12 68.49 55.56 168.92 0.00 1 0.00 1 0 17 8.559e-01 1.141e-02 8.784e-02 1.551e-03 9.588213e-01 8.882022e-04 1.064796e-02 -6.000000e+00 5.222956e-01 231.91 -2.00 3.53 -2.00 321.42 0.00e+00 2.811660e-03 4.706725e-04 2.443527e-03 -6.000000e+00 2.277863e-02 283.55 -2.00 20.00 -2.00 320.92 0.00e+00 6.126 0.004 302.00 328.00 3 2.7577e-01 3.1414e-03 8.0505e-02 -6.0000e+00 1.3092e+00 3.6452e-01 4.7145e-03 5.5101e-02 -6.0000e+00 1.4108e+00 -4.3927e-01 5.0540e-03 3.1043e-02 -6.0000e+00 8.3870e-01 1.6654e-01 2.3183e-03 1.0982e-02 -6.0000e+00 3.5272e-01 3.6260e-04 -2.4823e-04 3.9064e-05 1.5741e-04 -6.0000e+00 2.6113e-02 -1.1716e-02 2.0397e-04 12 8 8 10 0 0 19.01 24.74 0.46 -0.01172 -0.01358 340 34 1 5 0 159.970 32.00 19.90 24.74 15.99 9.4 908.39 -282214 -251662 -260244 -235979 -237750 -282820 -270194 -274907 -214757 -201565 -246795 -134471 -215022 -176321 -188655 -122144 -147867 -93549 -81340 -146533 -39430 -114293 -98174 -106269 -82679 -105663 -49127 -91894 -76057 -104460 -40367 -33619 -54993 -34420 -21737 -30972 -22075 -8409 10262 10831 7775 -6950 8068 10764 -4378 1131 6207 4429 10789 12904 9622 16039 12711 10354 12381 10400 9510 9873 3904 4565 1520 6643 9866 6486 8509 7191 4629 4150 4968 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