File name: Pandora249s1_ChicagoIL_20240628_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T095539.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240628_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240628T175233.1Z 8945.744828 435 1 18.22 2 18.76 178.73 91.90 272.97 0.00 1 0.00 1 0 9 9.181e-03 6.572e-03 4.638e-03 3.100e-03 1.541641e-01 1.685385e-03 1.859598e-03 -6.000000e+00 5.626904e-03 232.85 -2.00 3.53 -2.00 315.05 0.00e+00 3.459527e-04 1.459603e-04 2.038790e-05 -6.000000e+00 2.479534e-04 286.42 -2.00 20.00 -2.00 314.39 0.00e+00 1.056 0.000 302.00 328.00 3 6.3856e+00 4.3631e-03 1.3226e-02 -6.0000e+00 1.4125e-02 2.5043e-02 4.8098e-03 8.0951e-03 -6.0000e+00 1.5208e-02 4.0760e-03 2.7495e-03 3.9102e-03 -6.0000e+00 9.0429e-03 -5.0489e-03 1.2072e-03 1.0933e-03 -6.0000e+00 3.8240e-03 2.7564e-04 1.7680e-07 9.4695e-05 1.5773e-05 -6.0000e+00 2.8193e-04 -1.0701e-02 0.0000e+00 12 9 1 12 9 1 99.82 26.48 0.38 -0.01070 -0.01070 5 2 1 5 0 3035.100 33.25 20.00 26.48 27.33 9.8 983.87 900000 1049 -2591 -296 -1301 1513 -316 -1054 1243 -936 268 -880 146 793 660 -1500 -1259 1033 1559 2206 1691 147 -406 -345 -211 138 -926 -984 308 3126 -335 2317 348 -316 -2282 -1941 -1950 -844 404 -542 -222 -1918 -862 593 484 -169 -1226 -1174 -827 -868 -195 1690 849 674 191 2069 1028 780 947 921 687 1204 1788 661 -80 423 -61 -346 -438 161 198 -60 815 -276 -431 277 -507 -629 -2429 -1622 -508 -725 -1725 -1002 -324 -641 294 -327 383 398 -73 604 126 -465 475 463 -17 345 93 385 -382 -108 -156 -221 177 -690 -235 -274 289 -204 297 403 -189 -28 -115 -120 77 524 -54 148 132 -447 216 -89 92 382 699 939 308 -201 478 -358 -71 579 -93 385 32 -185 -9 -143 -103 -276 -659 900000 331 -874 -94 -381 435 -92 -331 419 -312 89 -293 50 296 273 -688 -602 492 756 1088 855 76 -210 -183 -116 78 -531 -543 156 1455 -160 1117 180 -169 -1212 -986 -1021 -489 248 -391 -177 -1525 -698 479 391 -136 -979 -980 -662 -678 -153 1361 725 554 162 1760 895 682 818 789 599 1095 1726 680 -84 418 -55 -296 -377 149 202 -61 834 -281 -450 264 -438 -541 -2086 -1472 -466 -730 -1889 -1066 -362 -769 347 -405 478 487 -91 684 140 -483 487 504 -19 418 113 473 -486 -128 -175 -247 209 -879 -291 -356 388 -287 434 561 -275 -38 -144 -149 92 635 -69 191 179 -617 292 -117 123 482 833 1084 366 -252 624 -485 -97 752 -127 551 47 -284 -13 -221 -155 -406 -949 SS 20240628T175904.1Z 8945.749353 439 1 53.40 2 18.78 183.38 93.05 274.05 0.00 1 0.00 1 0 17 8.765e-03 6.277e-03 2.618e-03 1.739e-03 1.555539e-01 9.496220e-04 1.900376e-03 -6.000000e+00 5.371060e-03 232.85 -2.00 3.53 -2.00 315.08 0.00e+00 2.013434e-04 8.229968e-05 1.873080e-05 -6.000000e+00 2.367151e-04 286.42 -2.00 20.00 -2.00 314.41 0.00e+00 1.056 0.000 302.00 328.00 3 6.4609e+00 2.4594e-03 1.3307e-02 -6.0000e+00 1.3483e-02 2.6586e-02 2.7090e-03 8.2165e-03 -6.0000e+00 1.4517e-02 2.6671e-03 1.5513e-03 3.9813e-03 -6.0000e+00 8.6321e-03 -3.3856e-03 6.8273e-04 1.0940e-03 -6.0000e+00 3.6496e-03 2.5490e-04 -2.9446e-05 5.4594e-05 1.6221e-05 -6.0000e+00 2.6915e-04 -9.7023e-03 0.0000e+00 10 0 0 10 0 0 99.69 26.51 0.50 -0.00970 -0.00992 19 2 1 5 0 2810.360 33.25 20.00 26.51 27.84 9.8 987.19 900000 538 -3035 -600 -1889 1348 -1244 -1079 936 -214 1979 -414 -1129 1043 470 -1079 -52 1165 1159 2156 479 1182 -363 -174 957 -1124 -609 -109 690 2063 506 1613 -30 -643 -1722 -1353 -2225 -1744 -103 -390 -40 -1828 -859 229 -156 -453 -827 -1044 -672 -143 440 1784 882 447 745 1210 1027 676 987 653 655 813 1370 800 520 402 -453 -205 -283 647 283 -16 946 -37 -279 315 -864 -939 -2136 -1102 -977 -1480 -2025 -1076 -609 -60 -86 406 164 305 45 169 194 99 170 -169 279 713 674 -120 -477 -429 -263 -15 -170 -523 -488 -335 284 166 210 839 -121 59 -338 -83 284 388 -172 88 -264 -123 151 -52 354 276 169 798 166 242 233 -193 196 839 -323 50 91 -142 -44 -270 -325 -460 -158 900000 166 -1001 -186 -595 378 -354 -330 309 -76 692 -147 -382 378 190 -480 -24 540 549 1035 238 585 -183 -90 507 -628 -340 -58 340 945 233 763 -15 -336 -885 -665 -1138 -994 -68 -274 -31 -1534 -735 196 -134 -386 -694 -847 -523 -108 334 1399 733 389 666 1011 871 577 830 593 557 724 1294 801 527 387 -401 -184 -257 582 281 -17 1014 -39 -283 292 -790 -789 -1782 -970 -949 -1466 -2169 -1203 -667 -70 -106 521 214 390 55 187 210 100 171 -181 325 840 849 -155 -592 -498 -310 -17 -196 -648 -634 -455 371 228 299 1208 -172 79 -443 -101 330 459 -217 119 -350 -165 213 -71 458 338 213 967 207 295 296 -254 261 1134 -462 69 132 -212 -67 -408 -479 -659 -220 SS 20240628T180826.6Z 8945.755864 445 1 55.47 2 18.98 190.01 94.70 275.61 0.00 1 0.00 1 0 17 7.017e-03 5.291e-03 1.875e-03 1.299e-03 1.531920e-01 7.087575e-04 1.864124e-03 -6.000000e+00 4.300344e-03 232.85 -2.00 3.53 -2.00 314.89 0.00e+00 1.214704e-04 5.929997e-05 1.815922e-05 -6.000000e+00 1.895132e-04 286.42 -2.00 20.00 -2.00 314.25 0.00e+00 1.057 0.000 302.00 328.00 3 6.0384e+00 1.8329e-03 1.3215e-02 -6.0000e+00 1.0795e-02 1.5145e-02 2.0201e-03 8.0595e-03 -6.0000e+00 1.1623e-02 3.2767e-03 1.1543e-03 3.9092e-03 -6.0000e+00 6.9111e-03 -3.3209e-03 5.0267e-04 1.0722e-03 -6.0000e+00 2.9223e-03 3.9222e-04 -1.8255e-05 4.0546e-05 1.6109e-05 -6.0000e+00 2.1548e-04 -1.0171e-02 0.0000e+00 11 1 0 11 8 0 99.59 26.56 0.20 -0.01017 -0.01031 23 2 1 5 0 2411.270 33.25 20.00 26.56 28.48 9.8 990.86 900000 -403 -1778 -1403 -1526 275 -278 -793 1620 -557 852 -1388 -56 144 308 -293 -506 1096 1104 1773 921 106 68 169 909 -379 -523 -254 418 1467 369 1708 537 -227 -1616 -887 -1496 -1253 4 -266 -513 -1534 -298 -40 -47 -288 -932 -1060 -723 -446 273 1604 598 575 1019 826 734 593 795 380 401 937 1322 801 347 211 -303 -129 -466 467 231 -170 356 91 -276 -23 -324 -452 -1363 -641 -872 -1182 -1428 -1217 -660 -432 -179 163 -41 145 299 94 265 132 616 264 105 633 366 -99 -181 -374 -198 -166 -150 -650 -650 -243 24 72 -17 731 -150 -157 -261 -114 486 348 171 231 -62 -20 46 51 413 547 345 754 391 378 164 -158 94 376 -239 3 19 -223 -8 -205 -217 -341 -451 900000 -143 -661 -501 -497 81 -81 -251 551 -206 313 -517 -21 60 142 -135 -244 531 547 892 477 56 36 91 504 -220 -305 -142 216 706 178 842 281 -123 -865 -453 -792 -742 2 -196 -391 -1253 -248 -33 -39 -239 -764 -839 -591 -355 219 1323 486 487 887 733 660 536 709 337 361 881 1233 791 348 201 -284 -113 -412 445 227 -178 380 96 -277 -23 -288 -398 -1188 -548 -827 -1154 -1502 -1347 -721 -504 -221 197 -50 185 362 104 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