File name: Pandora249s1_ChicagoIL_20240707_L2Fit_fwvt1c3d20230501p1-8.txt File generation date: 20240912T100953.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240707_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0600 492.1808 492.3016 492.4224 492.5432 492.6639 492.7847 492.9054 493.0261 493.1468 493.2675 493.3881 493.5088 493.6294 493.7500 493.8706 493.9912 494.1118 494.2323 494.3528 494.4734 494.5939 494.7143 494.8348 494.9552 495.0757 495.1961 495.3165 495.4369 495.5572 495.6776 495.7979 495.9182 496.0385 496.1588 496.2790 496.3993 496.5195 496.6397 496.7599 496.8801 497.0002 497.1204 497.2405 497.3606 497.4807 497.6008 497.7209 497.8409 497.9609 498.0809 498.2009 498.3209 498.4409 498.5608 498.6807 498.8006 498.9205 499.0404 499.1602 499.2801 499.3999 499.5197 499.6395 499.7593 499.8790 499.9988 500.1185 500.2382 500.3579 500.4775 500.5972 500.7168 500.8365 500.9561 501.0756 501.1952 501.3148 501.4343 501.5538 501.6733 501.7928 501.9123 502.0317 502.1511 502.2705 502.3899 502.5093 502.6287 502.7480 502.8673 502.9867 503.1059 503.2252 503.3445 503.4637 503.5829 503.7022 503.8213 503.9405 504.0597 504.1788 504.2979 504.4170 504.5361 504.6552 504.7742 504.8933 505.0123 505.1313 505.2503 505.3692 505.4882 505.6071 505.7260 505.8449 505.9638 506.0826 506.2015 506.3203 506.4391 506.5579 506.6767 506.7954 506.9142 507.0329 507.1516 507.2703 507.3889 507.5076 507.6262 507.7448 507.8634 507.9820 508.1006 508.2191 508.3376 508.4561 508.5746 508.6931 508.8116 508.9300 509.0484 509.1668 509.2852 509.4036 509.5219 509.6402 509.7586 509.8769 509.9951 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240707T103017.3Z 8954.437700 31 1 31.98 2 89.70 59.34 101.16 44.34 0.00 1 0.00 1 0 29 1.600e-02 1.578e-02 7.870e-04 7.816e-04 2.561168e+04 6.138590e+01 1.633385e+03 -6.000000e+00 9.347740e+02 287.23 -2.00 20.00 -2.00 505.47 0.00e+00 8.548634e-03 2.237016e-05 4.917601e-04 -6.000000e+00 4.590802e-04 287.23 -2.00 20.00 -2.00 501.23 0.00e+00 1.099802e-01 1.523836e-02 1.709613e-01 -6.000000e+00 3.218969e-01 232.86 -2.00 3.53 -2.00 502.69 0.00e+00 19.893 0.148 489.00 513.00 1 4.6255e+00 1.1700e-03 3.9431e-02 -6.0000e+00 2.4783e-02 -3.8447e-02 2.8542e-04 4.4102e-03 -6.0000e+00 6.3173e-03 1.0130e-03 4.3950e-03 7.4368e-05 2.3824e-04 -6.0000e+00 1.8086e-03 -8.5713e-03 -9.4034e-05 12 9 9 12 1 1 58.34 26.43 12.13 -0.00857 0.02191 30 5 1 4 0 1031.450 33.25 20.00 26.43 25.97 9.8 973.38 -2329 -1503 -7 1146 2263 3245 3716 3323 2978 2231 1468 542 -224 -879 -1133 -945 -539 171 837 962 1247 1053 1187 1402 1672 1468 1153 492 -608 -1997 -2634 -2499 -1598 -515 504 547 203 -145 -643 -693 -572 -237 333 1057 1198 1438 1164 694 -251 -1061 -2248 -2837 -3214 -2727 -1842 -478 163 627 991 1035 1095 1419 1599 1321 917 471 -137 -675 -1209 -1648 -1665 -1894 -1334 -997 -678 -930 -1431 -2109 -2433 -2245 -2050 -1647 -1687 -1459 -1248 -1249 -1376 -1239 -1213 -818 -216 389 1182 1844 1558 930 233 -999 -1953 -3078 -3755 -3491 -2450 -1261 -445 -269 -650 -960 -1031 -793 -424 266 950 1723 2213 2673 3167 2994 2404 1571 817 632 858 1605 2020 2198 2174 1783 1410 1137 986 107 -503 -773 -923 -705 156 560 846 1371 1123 988 924 1172 871 794 45 -1158 -2322 -2645 -2400 -1994 -1299 -6 1033 2078 2897 3359 3039 2728 2037 1332 489 -201 -787 -1013 -849 -489 158 781 907 1181 1003 1136 1351 1557 1378 1085 462 -565 -1914 -2508 -2390 -1486 -489 486 533 198 -142 -628 -678 -564 -237 324 1040 1194 1443 1171 697 -251 -1050 -2204 -2753 -3119 -2666 -1832 -483 168 653 998 1048 1114 1450 1641 1362 945 483 -139 -682 -1215 -1647 -1721 -1893 -1337 -1006 -686 -939 -1434 -2096 -2488 -2275 -2070 -1661 -1715 -1494 -1240 -1249 -1376 -1229 -1193 -830 -218 396 1201 1846 1524 881 223 -935 -1805 -2842 -3498 -3314 -2306 -1234 -434 -270 -660 -981 -1058 -821 -444 271 970 1758 2263 2752 3300 3179 2587 1695 874 665 890 1651 2084 2286 2280 1887 1500 1212 1046 113 -531 -817 -984 -762 165 598 916 1501 1250 1114 1013 1284 954 864 50 -1299 -2523 -2887 -2643 SQ 20240707T103323.5Z 8954.439855 35 1 54.35 2 89.20 59.85 100.78 44.91 0.00 1 0.00 1 0 29 1.134e-02 1.119e-02 4.565e-04 4.538e-04 2.735567e+04 3.628719e+01 1.734130e+03 -6.000000e+00 6.624968e+02 287.23 -2.00 20.00 -2.00 505.48 0.00e+00 7.655384e-03 1.302046e-05 4.422039e-04 -6.000000e+00 3.253268e-04 287.23 -2.00 20.00 -2.00 501.16 0.00e+00 6.592188e-01 8.887960e-03 1.757227e-01 -6.000000e+00 2.280312e-01 232.86 -2.00 3.53 -2.00 502.63 0.00e+00 18.984 0.129 489.00 513.00 1 4.2533e+00 6.8266e-04 3.6943e-02 -6.0000e+00 1.7558e-02 -5.0270e-02 1.6626e-04 4.5489e-03 -6.0000e+00 4.4729e-03 1.6160e-03 3.0870e-03 4.2378e-05 2.2489e-04 -6.0000e+00 1.2818e-03 -9.4406e-03 -5.3610e-05 12 8 8 10 0 0 7.97 26.42 8.35 -0.00944 0.01197 81 8 1 4 0 670.950 33.25 20.00 26.42 25.98 9.8 974.00 -1516 -958 107 993 1588 2334 2537 2453 2158 1540 1056 455 -32 -490 -771 -736 -404 137 593 642 679 655 827 935 1203 1004 726 336 -492 -1407 -1807 -1789 -1106 -343 251 323 50 -193 -481 -569 -510 -209 227 646 784 975 719 440 -113 -797 -1630 -2150 -2291 -1914 -1174 -487 193 411 620 802 860 1036 1115 928 706 325 -55 -526 -873 -1189 -1267 -1234 -978 -766 -520 -631 -1223 -1445 -1574 -1625 -1453 -1222 -1201 -1069 -807 -751 -1020 -997 -755 -516 -73 332 993 1267 1164 644 180 -635 -1322 -2245 -2759 -2513 -1950 -1012 -345 -228 -340 -689 -770 -639 -349 26 588 1096 1539 1919 2300 2147 1620 1140 555 426 568 1068 1467 1516 1531 1250 998 839 586 -71 -344 -443 -650 -312 74 461 599 1027 874 753 723 794 703 487 53 -791 -1556 -1794 -1627 -1345 -829 95 902 1478 2132 2355 2299 2026 1440 979 418 -29 -445 -700 -672 -373 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