File name: Pandora249s1_ChicagoIL_20240710_L2Fit_fout2c2d20230104p1-8.txt File generation date: 20240711T060035.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v2d20230104.txt Level 1 file used: Pandora249s1_ChicagoIL_20240710_L1_smca1c2d20230104p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0408 305.1812 305.3216 305.4620 305.6024 305.7427 305.8831 306.0235 306.1638 306.3042 306.4445 306.5848 306.7252 306.8655 307.0058 307.1461 307.2864 307.4267 307.5670 307.7073 307.8475 307.9878 308.1281 308.2683 308.4086 308.5488 308.6891 308.8293 308.9695 309.1097 309.2499 309.3901 309.5303 309.6705 309.8107 309.9509 310.0910 310.2312 310.3713 310.5115 310.6516 310.7917 310.9319 311.0720 311.2121 311.3522 311.4923 311.6324 311.7724 311.9125 312.0526 312.1926 312.3327 312.4727 312.6127 312.7527 312.8928 313.0328 313.1728 313.3127 313.4527 313.5927 313.7327 313.8726 314.0126 314.1525 314.2924 314.4324 314.5723 314.7122 314.8521 314.9920 315.1319 315.2717 315.4116 315.5515 315.6913 315.8311 315.9710 316.1108 316.2506 316.3904 316.5302 316.6700 316.8098 316.9495 317.0893 317.2290 317.3688 317.5085 317.6482 317.7879 317.9276 318.0673 318.2070 318.3467 318.4864 318.6260 318.7657 318.9053 319.0449 319.1846 319.3242 319.4638 319.6033 319.7429 319.8825 320.0221 320.1616 320.3011 320.4407 320.5802 320.7197 320.8592 320.9987 321.1382 321.2776 321.4171 321.5566 321.6960 321.8354 321.9748 322.1142 322.2536 322.3930 322.5324 322.6718 322.8111 322.9505 323.0898 323.2291 323.3684 323.5077 323.6470 323.7863 323.9256 324.0649 324.2041 324.3433 324.4826 324.6218 324.7610 324.9002 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240710T143906.9Z 8957.610497 178 1 54.47 2 45.51 100.02 94.84 74.15 0.00 1 0.00 1 0 17 7.744e-03 5.373e-03 1.868e-03 1.036e-03 2.118740e-01 5.618026e-04 2.548428e-03 -6.000000e+00 4.747336e-03 232.87 -2.00 3.53 -2.00 315.72 0.00e+00 2.580441e-04 5.615930e-05 3.243481e-05 -6.000000e+00 2.095242e-04 287.52 -2.00 20.00 -2.00 315.00 0.00e+00 1.425 0.000 302.00 328.00 3 4.9687e+00 1.4623e-03 1.7989e-02 -6.0000e+00 1.1913e-02 1.2646e-02 1.6171e-03 1.1127e-02 -6.0000e+00 1.2814e-02 1.8595e-03 9.2585e-04 5.3834e-03 -6.0000e+00 7.6301e-03 -2.6380e-03 4.1589e-04 1.4873e-03 -6.0000e+00 3.2201e-03 7.0686e-04 4.7014e-04 3.2266e-05 2.0710e-05 -6.0000e+00 2.3631e-04 -1.7486e-02 2.9470e-04 10 0 0 10 0 0 99.96 26.36 0.29 -0.01749 -0.01395 41 4 1 5 0 1328.370 33.25 20.00 26.36 27.42 9.8 983.47 -390 388 -2560 -1709 -3045 -1485 -1013 320 1601 69 -83 -1351 217 1320 110 -32 -431 914 647 1539 857 768 101 412 870 -524 -470 -1146 -146 804 1217 591 417 -96 -1783 -1135 -721 50 621 330 -343 -1291 -633 -614 -603 -904 -986 -1492 -763 -248 625 1401 958 593 900 921 797 321 342 635 789 1227 1691 962 355 34 -380 -414 123 641 60 184 338 -104 -44 11 -269 -138 -876 -820 -754 -1191 -1618 -1318 -628 -752 -399 -116 252 47 196 375 391 558 747 518 408 324 198 -16 -163 -552 -220 -124 -438 -660 -785 -259 -228 -35 72 212 -5 -12 61 110 409 403 157 -74 -362 -162 104 95 452 433 738 845 420 411 309 3 135 282 -16 -31 -201 -117 -198 -163 -281 -316 -394 -86 94 -656 -419 -691 -309 -212 72 393 18 -22 -370 62 419 36 -11 -166 358 263 637 365 329 44 184 406 -237 -214 -548 -65 338 513 265 199 -48 -882 -539 -354 25 369 213 -249 -939 -472 -465 -457 -684 -735 -1086 -536 -183 468 1025 745 485 760 746 656 267 281 516 650 1057 1556 890 336 32 -340 -351 106 595 58 190 356 -107 -43 10 -233 -118 -747 -704 -719 -1187 -1751 -1420 -712 -865 -486 -146 323 60 233 432 434 580 778 579 474 393 258 -20 -210 -665 -262 -146 -519 -837 -996 -342 -315 -48 104 314 -7 -16 82 143 512 513 212 -102 -523 -224 148 131 593 567 917 1079 523 543 409 4 188 405 -23 -47 -302 -181 -310 -253 -424 -485 -589 SS 20240710T151641.2Z 8957.636588 203 1 20.09 2 38.74 108.19 88.32 80.39 0.00 1 0.00 1 0 17 1.023e-02 6.164e-03 4.513e-03 2.536e-03 1.969325e-01 1.371892e-03 2.389721e-03 -6.000000e+00 6.268262e-03 232.87 -2.00 3.53 -2.00 315.65 0.00e+00 4.005574e-04 1.359864e-04 3.047005e-05 -6.000000e+00 2.767342e-04 287.53 -2.00 20.00 -2.00 314.94 0.00e+00 1.281 0.000 302.00 328.00 3 5.6645e+00 3.5749e-03 1.6437e-02 -6.0000e+00 1.5729e-02 2.5007e-02 3.9554e-03 1.0399e-02 -6.0000e+00 1.6920e-02 1.6985e-03 2.2566e-03 5.0330e-03 -6.0000e+00 1.0075e-02 -4.0548e-03 1.0106e-03 1.4063e-03 -6.0000e+00 4.2509e-03 4.1411e-04 1.2470e-04 7.8968e-05 1.9463e-05 -6.0000e+00 3.1212e-04 -1.7538e-02 2.2225e-04 12 1 1 12 9 1 92.78 26.58 0.15 -0.01754 -0.01660 6 2 1 5 0 2868.760 33.25 20.00 26.58 28.93 9.7 992.36 -1459 1793 -2742 -1824 -5551 -1281 68 536 649 -1501 1350 -2474 -180 832 2024 -708 -1096 1212 -337 1934 2268 537 -323 978 1172 -1207 -1509 908 -37 2099 -424 1587 1542 563 -2500 -1012 -1705 -159 731 99 -357 -994 -981 -44 -198 -129 -1175 -1489 -894 -161 13 1319 824 75 1028 1009 448 299 442 641 73 1276 1420 1194 -47 -117 8 -54 272 863 173 -129 639 157 -264 -24 -431 -363 -1370 -589 -670 -1099 -1557 -1379 -862 -229 -541 -56 298 223 420 60 407 245 370 267 43 614 518 65 -371 -398 -247 -180 161 -832 -875 -592 -95 394 123 584 -347 237 168 -71 739 -167 303 82 -454 -435 -19 211 342 436 627 1436 369 379 296 -243 -148 686 -290 115 -184 -333 -192 -113 -93 -612 -65 -327 426 -701 -444 -1279 -290 15 130 158 -395 349 -667 -50 256 689 -271 -442 492 -143 824 984 237 -145 447 559 -559 -703 433 -16 882 -184 709 730 278 -1243 -479 -842 -80 428 63 -253 -752 -766 -35 -156 -101 -910 -1123 -650 -114 10 989 656 63 821 821 372 250 364 523 61 1103 1313 1172 -48 -112 7 -45 229 788 175 -130 654 158 -273 -23 -369 -309 -1161 -531 -623 -1132 -1623 -1516 -998 -264 -665 -72 384 284 502 71 433 262 396 284 51 738 668 86 -474 -474 -294 -213 188 -1050 -1161 -771 -128 556 182 833 -519 333 230 -90 902 -210 399 109 -636 -617 -27 283 462 559 764 1798 448 487 401 -342 -199 939 -419 175 -275 -512 -299 -175 -140 -949 -97 SS 20240710T152629.6Z 8957.643399 206 1 14.07 2 37.03 110.61 86.59 82.00 0.00 1 0.00 1 0 17 9.915e-03 6.412e-03 4.589e-03 2.699e-03 1.894713e-01 1.463005e-03 2.285335e-03 -6.000000e+00 6.078500e-03 232.87 -2.00 3.53 -2.00 315.50 0.00e+00 2.695894e-04 1.394559e-04 2.645329e-05 -6.000000e+00 2.682899e-04 287.53 -2.00 20.00 -2.00 314.79 0.00e+00 1.252 0.000 302.00 328.00 3 5.4964e+00 3.8042e-03 1.5927e-02 -6.0000e+00 1.5253e-02 1.5238e-02 4.2019e-03 9.9574e-03 -6.0000e+00 1.6407e-02 4.5468e-03 2.4043e-03 4.8230e-03 -6.0000e+00 9.7697e-03 -3.2478e-03 1.0709e-03 1.3311e-03 -6.0000e+00 4.1230e-03 5.1331e-04 4.5207e-04 8.4252e-05 1.8569e-05 -6.0000e+00 3.0259e-04 -1.7932e-02 2.6910e-04 12 9 1 12 9 1 93.23 26.63 0.41 -0.01793 -0.01454 5 2 1 5 0 2344.530 33.25 20.00 26.63 29.49 9.7 995.69 805 2742 -3329 -2066 -1687 -653 -1121 1135 -1283 -2636 451 -1311 1957 554 705 -1294 -24 1124 1110 1427 1053 1121 -296 -94 1349 -802 -1200 -738 31 2186 804 2886 534 -825 -2389 -2079 -1713 -512 430 -333 -68 -1815 -931 189 -332 -555 -1000 -1139 -1181 -142 221 2648 457 1082 544 916 1110 1014 1199 564 663 1456 1533 1084 341 -283 -435 -840 -308 312 650 -393 211 181 -57 -71 -292 -841 -1001 -945 -705 -1264 -1830 -1042 -771 -401 -114 -53 122 293 8 50 158 442 116 227 286 662 409 -16 -308 -735 17 -64 -63 -986 -821 -499 -165 -91 417 543 -155 458 -229 298 345 574 -129 -46 -319 109 15 541 183 684 693 696 387 254 572 -120 -82 188 -35 -82 -156 19 -359 -316 -381 -251 -174 198 721 -956 -563 -417 -149 -258 278 -354 -782 131 -388 594 189 268 -502 -10 459 466 614 464 495 -133 -44 644 -405 -610 -359 14 919 344 1268 254 -411 -1178 -986 -840 -280 252 -230 -48 -1391 -730 149 -262 -436 -776 -857 -861 -101 159 1956 364 896 468 801 983 902 1053 494 590 1259 1418 1066 343 -272 -386 -757 -279 286 654 -398 217 183 -59 -67 -266 -712 -837 -845 -652 -1296 -1908 -1138 -890 -465 -140 -68 158 373 9 58 169 467 123 241 333 793 527 -21 -392 -876 20 -75 -73 -1246 -1088 -651 -224 -129 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