File name: Pandora249s1_ChicagoIL_20240714_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T100814.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240714_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240714T114300.2Z 8961.488197 79 1 54.96 2 78.23 71.50 150.55 350.23 0.00 1 0.00 1 0 25 2.768e-01 1.783e-02 1.891e-01 5.760e-03 6.141999e-01 3.257983e-03 7.048918e-03 -6.000000e+00 1.714634e-01 232.87 -2.00 3.53 -2.00 320.80 0.00e+00 -3.727760e-04 1.387562e-03 1.085179e-03 -6.000000e+00 8.325223e-03 287.89 -2.00 20.00 -2.00 320.13 0.00e+00 4.746 0.002 302.00 328.00 3 4.1657e+00 1.0576e-02 5.7386e-02 -6.0000e+00 4.3144e-01 2.0867e-01 1.3745e-02 3.4113e-02 -6.0000e+00 4.6594e-01 -2.6470e-01 1.2335e-02 1.6870e-02 -6.0000e+00 2.7645e-01 1.0118e-01 5.9960e-03 4.7041e-03 -6.0000e+00 1.1757e-01 3.9613e-05 -1.0084e-04 1.7988e-04 5.8969e-05 -6.0000e+00 8.6115e-03 -8.6295e-03 0.0000e+00 12 9 8 11 8 0 97.84 26.29 0.42 -0.00863 -0.00939 21 2 1 5 0 2616.730 33.00 20.00 26.29 26.59 9.7 976.38 900000 900000 -145617 900000 -39205 900000 50783 -92594 13229 -87156 900000 -98916 -43858 -44957 69782 -42226 -23525 900000 62613 900000 45708 -8519 -57997 947 5583 -76806 -59191 5760 11401 84266 -13032 17021 -20066 -7788 -14800 -14667 -14586 -7826 23227 20632 33133 -20575 -3211 43878 16706 7737 -1684 -16309 966 5263 3043 48703 1481 -1239 1785 12417 9333 4247 11668 7551 -3221 259 3195 1341 2716 6134 3128 1818 1063 1088 2920 3056 2191 -1235 1389 6325 -1658 -1417 -16121 -4074 1570 -3396 -3407 1369 1228 1697 783 -541 1412 213 -550 1844 743 483 36 -3267 -2931 168 522 -357 -1112 -1814 1080 -2642 1249 -1651 -1732 -407 -945 -35 -208 1482 41 -541 331 -1131 599 1366 76 766 -571 -1279 332 806 -368 1844 1232 2216 -327 180 -184 530 239 2067 -213 -8 -495 -653 -485 486 -1246 -826 681 900000 900000 -3416 900000 -300 900000 285 -1322 74 -1467 900000 -2169 -649 -825 498 -1098 -576 900000 843 900000 795 -258 -2961 29 175 -5860 -3885 194 352 1276 -578 649 -1272 -476 -980 -954 -998 -575 1511 1655 2695 -3128 -432 3791 1912 977 -236 -2690 138 759 487 5464 293 -274 410 2689 2157 1044 2618 1728 -828 68 907 431 922 2023 1041 618 389 447 1317 1469 1078 -608 619 2438 -635 -526 -7343 -1881 799 -2080 -2322 958 918 1226 604 -439 1135 170 -418 1406 543 352 28 -2721 -2797 178 606 -432 -1311 -1990 1057 -2600 1233 -1787 -1983 -489 -1233 -49 -300 2254 65 -841 487 -1751 897 2084 113 1191 -915 -2028 545 1274 -565 2662 1730 3100 -507 284 -320 986 470 4215 -472 -17 -1118 -1505 -1122 1090 -2709 -1833 1426 SS 20240714T115348.9Z 8961.495705 85 1 54.49 2 76.32 73.17 150.83 355.37 0.00 1 0.00 1 0 17 1.525e-01 7.086e-03 1.029e-01 2.364e-03 5.432958e-01 1.298999e-03 6.253481e-03 -6.000000e+00 9.348209e-02 232.87 -2.00 3.53 -2.00 320.12 0.00e+00 6.765794e-04 4.584678e-04 2.792493e-04 -6.000000e+00 4.218313e-03 287.89 -2.00 20.00 -2.00 319.42 0.00e+00 4.127 0.001 302.00 328.00 3 3.5697e+00 3.9140e-03 4.9955e-02 -6.0000e+00 2.3446e-01 1.7448e-02 4.8236e-03 2.9320e-02 -6.0000e+00 2.5241e-01 -4.9128e-02 4.1475e-03 1.4479e-02 -6.0000e+00 1.5019e-01 1.2872e-02 2.1030e-03 4.2758e-03 -6.0000e+00 6.3664e-02 1.4421e-04 -4.1274e-04 7.2212e-05 4.9987e-05 -6.0000e+00 4.7343e-03 -8.6565e-03 0.0000e+00 11 8 0 10 0 0 99.01 26.31 0.50 -0.00866 -0.01176 70 7 1 5 0 778.390 33.00 20.00 26.31 26.83 9.7 978.33 900000 83913 -18771 -31897 900000 -4470 -45576 -106793 -19018 -6571 -40997 -13216 -18548 -25561 -37454 -8862 -21384 27217 6753 -9819 4102 1871 -21389 -9530 -6574 -35871 -6077 -18156 11020 -6684 1981 -3975 -10093 -4837 -10971 -7512 -3397 3415 3326 7057 6612 -7379 -880 1823 -1720 -267 -652 -4769 2787 3134 -604 9732 1660 -618 1126 686 2182 937 970 2184 -447 1260 2198 995 1544 1693 1060 720 1048 1333 441 442 632 981 -421 591 -928 -822 -5016 -1890 -937 -588 -1570 -1080 -348 164 327 -225 372 -77 568 966 722 748 711 -552 -235 344 -177 -384 -285 -671 -566 -184 27 -896 -745 -720 -759 164 98 368 2 -160 169 209 379 541 -21 100 -341 -352 -6 37 186 450 466 1254 420 294 79 108 151 508 -220 -12 -219 -158 -114 -138 -360 -160 7 900000 211 -145 -287 900000 -31 -494 -2387 -202 -68 -642 -171 -295 -536 -1087 -231 -719 621 205 -376 143 68 -1015 -430 -314 -2455 -319 -1067 472 -348 104 -256 -793 -395 -966 -632 -290 313 369 909 986 -1387 -164 343 -341 -53 -132 -1019 567 665 -144 2305 469 -194 337 217 703 310 317 696 -148 438 838 425 700 768 470 321 493 702 262 281 409 615 -251 318 -464 -396 -2642 -1094 -623 -407 -1219 -897 -306 154 299 -215 359 -73 551 870 614 626 630 -555 -249 411 -217 -488 -351 -824 -641 -201 31 -1103 -899 -921 -1043 245 149 594 4 -257 256 323 572 837 -31 161 -563 -574 -9 57 291 674 674 1797 649 470 138 190 279 981 -426 -25 -468 -345 -251 -299 -746 -315 13 SS 20240714T120424.6Z 8961.503062 88 1 12.20 2 74.43 74.80 150.93 0.47 0.00 1 0.00 1 0 17 1.143e-01 7.911e-03 6.141e-02 3.913e-03 4.869711e-01 2.119685e-03 5.700837e-03 -6.000000e+00 7.008793e-02 232.87 -2.00 3.53 -2.00 319.50 0.00e+00 2.310318e-03 6.033261e-04 5.725400e-04 -6.000000e+00 3.107165e-03 287.89 -2.00 20.00 -2.00 318.75 0.00e+00 3.656 0.001 302.00 328.00 3 3.6193e+00 6.0640e-03 4.4438e-02 -6.0000e+00 1.7586e-01 3.4744e-02 7.1644e-03 2.6125e-02 -6.0000e+00 1.8929e-01 -6.4455e-02 5.5449e-03 1.3085e-02 -6.0000e+00 1.1265e-01 2.0884e-02 2.8786e-03 4.2953e-03 -6.0000e+00 4.7707e-02 2.2404e-04 -4.2078e-04 1.1969e-04 4.9894e-05 -6.0000e+00 3.5114e-03 -1.0797e-02 0.0000e+00 12 9 1 12 1 1 -25.37 26.34 0.48 -0.01080 -0.01396 13 6 1 5 0 871.260 33.25 20.00 26.34 27.24 9.7 980.83 900000 -33753 -30168 28414 -9782 -73142 -10414 -61552 -14434 -28634 -30317 -37602 -9512 -6371 -21645 -707 -10037 144 -6676 7260 6069 -11514 -10848 -3420 -80 -22181 -5285 -8249 -6165 -4260 -1688 4990 -5673 1620 -4187 -5644 -5859 -3323 876 -436 -1240 -2800 1056 4529 472 755 2548 -3450 1337 -988 2282 6669 3076 1624 7 2628 784 1461 2259 -913 114 1264 2974 1703 914 1862 -183 637 1710 -320 746 206 1532 171 -35 651 -1766 -330 -1364 -2309 -1795 -1563 -1022 -1521 -413 -700 -33 59 358 444 -390 509 28 1091 708 -694 -141 471 224 -852 -482 -1014 -228 -307 -562 -734 -868 -749 -227 -224 455 195 -317 -433 118 355 956 755 242 399 -88 -87 229 -112 91 643 999 1076 935 186 -229 -46 292 647 -508 218 -314 25 -708 -20 -62 -236 -408 900000 -670 -633 336 -160 -2149 -167 -1808 -297 -743 -844 -1205 -265 -209 -1007 -32 -555 8 -420 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