File name: Pandora249s1_ChicagoIL_20240731_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T101625.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240731_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240731 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240731T124213.7Z 8978.529325 218 1 54.75 2 69.82 83.49 27.37 111.97 0.00 1 0.00 1 0 17 4.223e-02 6.674e-03 2.137e-02 2.187e-03 3.941989e-01 1.175563e-03 4.684436e-03 -6.000000e+00 2.582529e-02 232.27 -2.00 3.53 -2.00 318.84 0.00e+00 2.924804e-04 2.687752e-04 1.536287e-04 -6.000000e+00 1.149345e-03 288.27 -2.00 20.00 -2.00 318.03 0.00e+00 2.867 0.000 302.00 328.00 3 4.7694e+00 3.2525e-03 3.5222e-02 -6.0000e+00 6.4691e-02 1.7109e-02 3.7418e-03 2.1104e-02 -6.0000e+00 6.9661e-02 -2.9012e-03 2.6172e-03 1.0246e-02 -6.0000e+00 4.1490e-02 -4.8583e-03 1.3609e-03 2.8465e-03 -6.0000e+00 1.7598e-02 1.6580e-04 -4.9209e-04 6.8685e-05 3.4767e-05 -6.0000e+00 1.2966e-03 -1.0273e-02 0.0000e+00 11 8 0 10 0 0 98.81 26.97 0.58 -0.01027 -0.01397 43 4 1 5 0 1273.110 33.50 20.00 26.97 30.79 9.8 1003.80 900000 33744 -3057 4440 338 -9988 6540 -11790 12734 -3882 -1170 3166 -8915 23 458 -6383 -5352 12415 4186 411 2056 -5492 -3888 1423 -5884 -10555 -2259 -5422 1226 -1445 -2213 2515 -1937 941 -6574 -4529 -205 -915 2506 1905 1961 -5701 -882 1672 1476 473 -1173 -2211 -595 704 -985 5285 156 1140 659 84 2172 305 1080 21 1912 1039 1214 673 108 745 367 339 -240 758 359 576 -20 282 -871 478 -433 61 -2503 -532 -634 -1319 -1651 -1098 -203 -212 -175 -218 279 57 425 1122 926 89 1079 80 -172 365 308 -199 -246 -559 -367 -833 -137 -1269 -369 -331 -394 -119 -45 569 15 -295 72 239 314 419 33 107 -410 -673 -109 -29 203 1042 490 1289 462 547 281 -209 -43 873 -177 -174 205 18 -319 -172 -473 -331 -75 900000 720 -102 137 10 -317 180 -430 410 -161 -50 135 -479 1 31 -536 -492 1024 399 43 218 -639 -455 167 -794 -1580 -319 -775 157 -188 -305 367 -328 166 -1253 -828 -37 -192 608 553 589 -2004 -310 588 525 171 -432 -818 -217 259 -387 2110 71 549 336 45 1164 168 585 11 1029 596 759 422 71 479 245 221 -150 519 274 469 -17 230 -676 335 -304 40 -1727 -365 -496 -1168 -1485 -1048 -205 -229 -200 -241 310 68 473 1149 881 82 1018 83 -203 444 408 -273 -324 -688 -451 -1009 -160 -1604 -487 -460 -543 -176 -71 936 25 -470 107 333 457 621 48 166 -660 -1085 -170 -44 293 1522 690 1776 674 807 447 -353 -70 1469 -316 -330 378 33 -612 -326 -919 -616 -135 SS 20240731T124820.3Z 8978.533568 221 1 54.43 2 68.69 84.46 26.35 113.79 0.00 1 0.00 1 0 17 1.086e-01 7.223e-03 2.944e-02 2.453e-03 3.771053e-01 1.313778e-03 4.469493e-03 -6.000000e+00 6.642298e-02 232.27 -2.00 3.53 -2.00 318.75 0.00e+00 -1.990311e-04 2.950242e-04 2.466442e-04 -6.000000e+00 2.954842e-03 288.27 -2.00 20.00 -2.00 317.94 0.00e+00 2.725 0.000 302.00 328.00 3 5.0886e+00 3.6289e-03 3.3559e-02 -6.0000e+00 1.6639e-01 2.4636e-03 4.1649e-03 2.0196e-02 -6.0000e+00 1.7914e-01 2.6972e-02 2.9125e-03 9.7752e-03 -6.0000e+00 1.0670e-01 -1.9252e-02 1.5178e-03 2.6799e-03 -6.0000e+00 4.5282e-02 1.4089e-04 7.2929e-05 7.7185e-05 3.2461e-05 -6.0000e+00 3.3330e-03 -1.3670e-02 0.0000e+00 11 8 0 10 0 0 99.98 26.98 0.42 -0.01367 -0.01312 34 3 1 5 0 1600.620 33.50 20.00 26.98 31.16 9.8 1006.30 900000 81858 11003 26417 -36872 44607 52076 15446 31152 1760 2638 10101 377 9408 1680 -7330 -2352 14430 7216 9513 7852 -595 -6992 3762 -1876 -10152 -861 -3856 1970 5639 -3956 2964 -1112 -2176 -4124 -3735 -200 -4840 2154 2694 -556 -4444 -350 1692 425 -2397 -2149 -1488 -2393 534 636 6189 1381 -1108 -292 967 1000 -713 1069 621 636 572 2031 -530 -38 225 407 427 643 743 -272 308 256 153 -76 398 -606 227 -3704 -348 -225 -649 -1907 -682 -279 31 -28 321 399 3 544 1541 750 618 719 77 50 657 438 -372 -380 -203 -593 -462 -135 -1036 -590 -461 -58 169 29 653 -308 42 38 72 6 318 -103 -286 -698 -676 -139 413 -56 431 312 1281 194 238 -74 7 -97 883 112 -146 201 -149 -18 -163 -374 -355 95 900000 1136 334 689 -1702 864 959 454 887 74 115 428 20 522 119 -650 -219 1215 694 940 819 -69 -881 450 -255 -1588 -126 -569 262 712 -577 446 -193 -408 -789 -697 -38 -1089 541 801 -177 -1592 -126 613 158 -917 -820 -560 -909 200 250 2491 630 -554 -152 517 550 -403 588 339 352 335 1277 -370 -25 160 272 279 434 508 -209 252 213 124 -58 279 -426 149 -2577 -258 -174 -565 -1841 -693 -277 33 -31 375 473 4 597 1548 761 603 722 79 57 835 563 -494 -487 -260 -709 -542 -166 -1370 -760 -623 -82 258 44 1034 -492 64 58 104 9 451 -155 -456 -1081 -1045 -223 639 -82 607 421 1820 271 359 -120 11 -161 1501 201 -261 373 -283 -34 -311 -689 -670 172 SS 20240731T125845.4Z 8978.540803 224 1 53.50 2 66.76 86.14 24.64 117.16 0.00 1 0.00 1 0 17 4.011e-02 7.664e-03 1.535e-02 2.359e-03 3.452203e-01 1.261310e-03 4.115713e-03 -6.000000e+00 2.452922e-02 232.27 -2.00 3.53 -2.00 318.36 0.00e+00 3.122073e-05 2.496016e-04 1.135422e-04 -6.000000e+00 1.091696e-03 288.27 -2.00 20.00 -2.00 317.53 0.00e+00 2.514 0.000 302.00 328.00 3 5.2676e+00 3.4356e-03 3.0843e-02 -6.0000e+00 6.1445e-02 9.9873e-03 3.9033e-03 1.8401e-02 -6.0000e+00 6.6166e-02 1.7247e-04 2.5514e-03 8.9299e-03 -6.0000e+00 3.9408e-02 -5.0690e-03 1.3109e-03 2.4468e-03 -6.0000e+00 1.6714e-02 1.5115e-04 -2.5733e-04 7.4369e-05 2.9420e-05 -6.0000e+00 1.2315e-03 -1.0094e-02 0.0000e+00 11 9 0 11 8 0 99.59 27.03 0.27 -0.01009 -0.01203 24 2 1 5 0 2228.750 33.50 20.00 27.03 31.65 9.7 1008.47 900000 13178 -9078 9757 16837 5243 -881 -6289 19332 -17470 9123 174 -4540 -504 127 -12326 -3514 8862 2170 5781 2991 -4242 -5031 130 -2103 -8318 -6299 -3419 263 2091 -5005 4788 2008 96 -4227 -3579 -1452 -3670 1914 2060 1208 -3326 240 1579 878 -528 -893 -1242 -1331 894 -470 6248 -328 2 1645 1291 1423 175 2210 815 550 910 1415 872 -85 675 1226 -272 -420 1230 -282 183 647 504 -552 451 -851 -795 -3654 -1230 -755 -1157 -2117 -1199 -1166 -16 -82 123 12 189 216 839 581 246 603 174 114 133 607 -678 -11 -702 -229 -109 -298 -762 -603 -228 149 3 113 893 -188 -142 60 182 401 558 171 -245 -464 -556 -23 -6 17 772 400 907 592 469 386 -90 -380 865 -398 41 245 -331 262 -468 -311 -679 224 900000 552 -507 449 674 222 -40 -334 894 -1270 529 11 -345 -43 12 -1554 -443 1048 290 778 428 -662 -805 21 -366 -1624 -1230 -633 45 341 -912 866 410 21 -971 -797 -330 -970 570 726 442 -1375 100 665 375 -229 -387 -535 -570 379 -211 2817 -170 1 933 760 858 108 1319 488 335 582 979 600 -62 471 875 -191 -305 887 -229 158 568 433 -453 335 -634 -557 -2667 -882 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