File name: Pandora249s1_ChicagoIL_20240830_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20240912T102546.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20240830_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20240830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240830T134133.3Z 9008.570524 219 1 54.23 2 63.83 102.46 26.57 121.86 0.00 1 0.00 1 0 17 1.577e-02 5.393e-03 6.743e-03 1.708e-03 2.972866e-01 9.065356e-04 3.585427e-03 -6.000000e+00 9.578244e-03 230.40 -2.00 3.53 -2.00 317.64 0.00e+00 -2.104601e-04 1.451352e-04 7.674108e-05 -6.000000e+00 4.275667e-04 287.32 -2.00 20.00 -2.00 316.83 0.00e+00 2.254 0.000 302.00 328.00 3 5.0779e+00 2.4212e-03 2.7105e-02 -6.0000e+00 2.3890e-02 -2.9279e-03 2.7203e-03 1.5680e-02 -6.0000e+00 2.5767e-02 -1.1514e-03 1.6653e-03 7.6367e-03 -6.0000e+00 1.5362e-02 -1.2035e-03 8.3256e-04 2.1101e-03 -6.0000e+00 6.5340e-03 2.5489e-04 -2.3873e-04 5.3913e-05 2.6883e-05 -6.0000e+00 4.8399e-04 -9.2125e-03 0.0000e+00 10 0 0 10 0 0 99.99 26.90 0.50 -0.00921 -0.01101 88 9 1 5 0 616.130 33.50 20.00 26.90 30.51 9.8 1001.98 900000 8123 -545 112 2179 -9617 -4682 259 3589 -1435 470 1918 602 -361 -1789 -2330 -3669 1632 1985 -643 3449 696 -788 -1049 -1355 -3430 414 -1900 2302 20 990 2123 -462 110 -2790 -1231 -669 -2314 583 623 118 -1336 -1089 674 -209 -49 -198 -893 -1143 -117 -42 3156 713 484 448 150 1431 -466 657 513 503 255 872 1009 -110 716 281 330 73 682 187 276 -67 155 -204 93 217 -339 -2229 -731 -862 -1279 -1666 -832 -512 -260 92 540 323 197 493 615 110 658 529 350 205 374 179 -218 -460 -680 -788 -177 -400 -739 -384 -313 -531 260 121 81 -99 100 27 354 -132 409 -104 -168 -68 -307 -165 -48 367 416 349 991 885 444 287 -7 -70 589 -3 114 122 -195 -17 -212 -225 -465 -415 900000 615 -48 10 169 -788 -370 21 320 -145 48 199 69 -48 -274 -404 -696 308 391 -135 718 151 -176 -245 -337 -914 108 -492 541 5 234 537 -130 32 -839 -354 -199 -722 210 265 57 -702 -594 368 -116 -27 -109 -486 -614 -62 -23 1804 409 295 286 99 953 -318 440 340 338 181 666 827 -87 587 216 244 55 568 160 252 -62 141 -177 74 169 -248 -1669 -588 -722 -1198 -1706 -833 -542 -295 111 671 381 245 577 664 118 667 548 365 238 450 234 -291 -593 -818 -952 -210 -502 -927 -505 -432 -773 374 185 129 -156 150 39 489 -178 559 -150 -243 -103 -465 -244 -68 532 575 461 1276 1187 640 442 -11 -109 939 -5 191 212 -348 -30 -379 -390 -778 -716 SS 20240830T135815.1Z 9008.582119 235 1 21.13 2 60.83 105.65 24.11 128.32 0.00 1 0.00 1 0 17 3.009e-02 1.000e-02 1.808e-02 5.269e-03 2.722933e-01 2.797041e-03 3.282825e-03 -6.000000e+00 1.827555e-02 230.40 -2.00 3.53 -2.00 317.55 0.00e+00 6.388518e-04 4.339718e-04 6.569064e-05 -6.000000e+00 8.158461e-04 287.32 -2.00 20.00 -2.00 316.74 0.00e+00 2.042 0.000 302.00 328.00 3 6.1805e+00 7.4268e-03 2.4630e-02 -6.0000e+00 4.5582e-02 6.1937e-02 8.3399e-03 1.4323e-02 -6.0000e+00 4.9164e-02 -2.0135e-02 5.0351e-03 6.9815e-03 -6.0000e+00 2.9312e-02 4.5764e-03 2.4849e-03 1.9931e-03 -6.0000e+00 1.2467e-02 1.0470e-04 -5.0587e-04 1.6692e-04 2.4834e-05 -6.0000e+00 9.2352e-04 -8.9047e-03 0.0000e+00 12 9 9 12 1 1 100.00 27.02 0.35 -0.00890 -0.01271 7 2 1 5 0 2639.860 33.75 20.00 27.02 31.23 9.7 1004.33 900000 6783 1297 12742 -4230 -4288 2030 -9237 7015 -4997 9304 -2498 -703 -2881 -6071 2297 -8440 10488 2277 10066 4177 -4837 -4836 -1712 980 -6958 -933 -1098 -1207 5215 -1257 2295 1011 -1299 -5995 -5175 1227 -3656 2213 1693 1677 -4422 194 1899 1545 639 829 -2174 286 -2183 -770 2920 494 272 1627 2731 -241 -429 812 998 1189 2060 2055 -173 236 699 -813 -130 -937 -237 228 779 1718 -943 -437 1824 -1816 -288 -4680 -1282 -962 -1414 -2308 -432 -219 -395 332 478 537 23 566 1496 459 324 328 -408 -283 161 1135 323 -352 -1604 -104 -1288 -612 -1138 -782 -512 -84 77 397 1163 306 -248 -510 -936 496 641 -327 -73 224 -471 324 -387 195 735 1057 598 -149 636 318 167 330 1630 -438 -71 377 -323 -62 -559 -339 -417 -337 900000 652 139 1191 -432 -408 181 -1001 717 -619 1023 -314 -94 -444 -1104 430 -1886 2026 497 2105 951 -1213 -1223 -435 255 -2041 -261 -298 -309 1208 -317 599 288 -398 -1897 -1571 362 -1275 860 776 785 -2355 103 1004 823 343 439 -1162 146 -1140 -409 1586 293 170 1046 1782 -165 -296 547 663 800 1445 1555 -143 200 568 -624 -95 -703 -194 205 741 1651 -911 -398 1486 -1388 -202 -3425 -984 -825 -1354 -2218 -432 -232 -447 396 593 676 29 660 1591 493 330 338 -419 -322 202 1517 444 -469 -2015 -121 -1492 -742 -1482 -1067 -731 -115 112 609 1827 480 -370 -707 -1316 666 874 -475 -104 332 -707 473 -550 285 1013 1385 771 -200 904 482 243 492 2471 -711 -121 665 -587 -114 -1022 -599 -712 -557 SS 20240830T140303.1Z 9008.585453 238 1 41.08 2 59.97 106.59 23.44 130.37 0.00 1 0.00 1 0 17 6.466e-03 4.940e-03 1.213e-03 5.888e-04 2.633257e-01 3.150777e-04 3.208518e-03 -6.000000e+00 3.926788e-03 230.40 -2.00 3.53 -2.00 316.28 0.00e+00 1.831536e-04 3.592638e-05 4.173111e-05 -6.000000e+00 1.752798e-04 287.32 -2.00 20.00 -2.00 315.51 0.00e+00 1.990 0.000 302.00 328.00 3 3.2953e+00 8.2130e-04 2.3914e-02 -6.0000e+00 9.7940e-03 -1.8388e-02 9.1337e-04 1.3797e-02 -6.0000e+00 1.0563e-02 -2.3950e-03 5.2758e-04 6.7203e-03 -6.0000e+00 6.2979e-03 -9.8394e-05 2.4480e-04 1.8610e-03 -6.0000e+00 2.6788e-03 2.0709e-03 -2.3357e-04 1.8322e-05 2.5561e-05 -6.0000e+00 1.9841e-04 -9.5739e-03 0.0000e+00 12 1 1 12 1 1 99.79 27.05 0.27 -0.00957 -0.01133 143 19 1 5 0 285.220 33.75 20.00 27.05 31.24 9.7 1005.04 900000 -906 -1776 -1492 -1515 -2041 -678 -368 486 -84 -696 -26 -545 -352 -159 150 -362 601 1100 364 652 657 481 844 541 33 365 -297 401 462 1064 908 733 -68 -1140 -1123 -1153 -1178 -359 -579 -763 -916 -575 -492 -637 -275 -606 -808 -518 -53 155 708 780 586 662 615 617 385 350 529 828 1031 1218 1076 409 266 149 23 590 746 289 142 7 71 -175 -163 -148 -175 -448 -380 -791 -1084 -1438 -1301 -960 -601 -380 -102 -66 28 301 485 421 662 957 687 438 447 75 -225 -441 -672 -421 -21 -372 -662 -754 -426 -406 48 99 -33 -62 -54 29 276 438 462 229 -56 -233 -159 -141 1 347 499 571 922 853 528 380 126 -14 245 -16 -57 61 -36 -282 -336 -221 -373 -442 900000 -165 -344 -283 -289 -365 -120 -71 95 -18 -152 -6 -130 -95 -45 47 -123 196 371 128 236 239 178 323 219 13 146 -124 157 175 407 373 304 -30 -498 -475 -507 -548 -196 -351 -492 -600 -390 -340 -443 -190 -416 -544 -341 -35 105 503 561 445 500 477 488 307 277 414 656 858 1042 944 371 232 127 20 489 677 279 140 7 70 -165 -146 -126 -146 -374 -328 -736 -1077 -1495 -1378 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